Technical Papers
May 10, 2017

Effect of Desorption Methods on Electrode Regeneration Performance of Capacitive Deionization

Publication: Journal of Environmental Engineering
Volume 143, Issue 9

Abstract

Long regeneration time and substantial water usage in desorption cycles impose potential barriers for practical applications of capacitive deionization (CDI). In this research, a single-pass continuous-flow CDI cell was used to explore the effect of desorption methods on electrode regeneration performance. The results demonstrated effective nature of polarity reversal during electrode regeneration compared to the conventional short-circuit method. A reversed polarity with optimized duration and magnitude of cell voltage while purging with a proper flow scheme exhibited substantial reductions on regeneration time and flush-water usage during the desorption processes of CDI. The beneficial aspects of preferred desorption methods were attributable to minimization of a readsorption effect by limiting the rate of ion transport to the oppositely charged electrode. The results of this research are beneficial for improving the operational efficiency and cost-effectiveness of CDI systems for engineering applications.

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Acknowledgments

This research was supported by Minn Water (Minneapolis, Minnesota, United States) under Project No. 1390501914. The authors acknowledge Ningbo Chuanming Electrosorption Equipment Co. Ltd. (Ningbo, China) for assistance on acquiring materials for the bench work and providing accommodation for Q. Yao’s stay in Ningbo. H. Tang acknowledges Min Wan and Yanting Li for testing the durability of electrodes.

References

Bian, Y., et al. (2016). “Using activated carbon fiber separators to enhance the desalination rate of membrane capacitive deionization.” Desalination, 381, 95–99.
Biesheuvel, P. M., and Bazant, M. Z. (2010). “Nonlinear dynamics of capacitive charging and desalination by porous electrodes.” Phys. Rev. E, 81(3), 031502.
Biesheuvel, P. M., Porada, S., Levi, M., and Bazant, M. Z. (2014). “Attractive forces in microporous carbon electrodes for capacitive deionization.” J. Solid State Electrochem., 18(5), 1365–1376.
Biesheuvel, P. M., van Limpt, B., and van der Wal, A. (2009). “Dynamic adsorption/desorption process model for capacitive deionization.” J. Phys. Chem. C, 113(14), 5636–5640.
Biesheuvel, P. M., Zhao, R., Porada, S., and van der Wal, A. (2011). “Theory of membrane capacitive deionization including the effect of the electrode pore space.” J. Colloid Interface Sci., 360(1), 239–248.
Cohen, I., Avraham, E., Bouhadana, Y., Soffer, A., and Aurbach, D. (2013). “Long term stability of capacitive de-ionization processes for water desalination: The challenge of positive electrodes corrosion.” Electrochim. Acta, 106, 91–100.
Cohen, I., Avraham, E., Noked, M., Soffer, A., and Aurbach, D. (2011). “Enhanced charge efficiency in capacitive deionization achieved by surface-treated electrodes and by means of a third electrode.” J. Phys. Chem. C, 115(40), 19856–19863.
Dɫugoɫȩcki, P., and van der Wal, A. (2012). “Energy recovery in membrane capacitive deionization.” Environ. Sci. Technol., 47(9), 4904–4910.
Gabelich, C. J., Tran, T. D., and Suffet, I. H. (2002). “Electrosorption of inorganic salts from aqueous solution using carbon aerogels.” Environ. Sci. Technol., 36(13), 3010–3019.
Gao, X., Omosebi, A., Landon, J., and Liu, K. (2015). “Surface charge enhanced carbon electrodes for stable and efficient capacitive deionization using inverted adsorption-desorption behavior.” Energy Environ. Sci., 8(3), 897–909.
Huang, Z., Lu, L., Cai, Z., and Ren, Z. J. (2016). “Individual and competitive removal of heavy metals using capacitive deionization.” J. Hazard. Mater., 302, 323–331.
Jande, Y. A. C., and Kim, W. S. (2013). “Predicting the lowest effluent concentration in capacitive deionization.” Sep. Purif. Technol., 115, 224–230.
Jande, Y. A. C., and Kim, W. S. (2014). “Modeling the capacitive deionization batch mode operation for desalination.” J. Ind. Eng. Chem., 20(5), 3356–3360.
Kim, T., et al. (2015). “Enhanced charge efficiency and reduced energy use in capacitive deionization by increasing the discharge voltage.” J. Colloid Interface Sci., 446, 317–326.
Kim, Y.-J., Kim, J.-H., and Choi, J.-H. (2013). “Selective removal of nitrate ions by controlling the applied current in membrane capacitive deionization (MCDI).” J. Membr. Sci., 429, 52–57.
Leonard, K. C., Genthe, J. R., Sanfilippo, J. L., Zeltner, W. A., and Anderson, M. A. (2009). “Synthesis and characterization of asymmetric electrochemical capacitive deionization materials using nanoporous silicon dioxide and magnesium doped aluminum oxide.” Electrochim. Acta, 54(22), 5286–5291.
Li, H., and Zou, L. (2011). “Ion-exchange membrane capacitive deionization: A new strategy for brackish water desalination.” Desalination, 275(1), 62–66.
Liang, P., Yuan, L., Yang, X., Zhou, S., and Huang, X. (2013). “Coupling ion-exchangers with inexpensive activated carbon fiber electrodes to enhance the performance of capacitive deionization cells for domestic wastewater desalination.” Water Res., 47(7), 2523–2530.
Liu, D., Huang, K., Xie, L., and Tang, H. L. (2015). “Relation between operating parameters and desalination performance of capacitive deionization with activated carbon electrodes.” Environ. Sci. Water Res. Technol., 1(4), 516–522.
Mossad, M., and Zou, L. (2012). “A study of the capacitive deionization performance under various operational conditions.” J. Hazard. Mater., 213–214, 491–497.
Porada, S., et al. (2014). “Carbon flow electrodes for continuous operation of capacitive deionization and capacitive mixing energy generation.” J. Mater. Chem. A, 2(24), 9313–9321.
Ratajczak, P., Jurewicz, K., and Béguin, F. (2014). “Factors contributing to ageing of high voltage carbon/carbon supercapacitors in salt aqueous electrolyte.” J. Appl. Electrochem., 44(4), 475–480.
Suss, M., et al. (2015). “Water desalination via capacitive deionization: What is it and what can we expect from it?” Energy Environ. Sci., 8(8), 2296–2319.
Xu, P., Drewes, J. E., Heil, D., and Wang, G. (2008). “Treatment of brackish produced water using carbon aerogel-based capacitive deionization technology.” Water Res., 42(10), 2605–2617.
Yao, Q., and Tang, H. L. (2016). “Occurrence of re-adsorption in desorption cycles of capacitive deionization.” J. Ind. Eng. Chem., 34, 180–185.
Zhao, R., Biesheuvel, P. M., Miedema, H., Bruning, H., and van der Wal, A. (2010). “Charge efficiency: A functional tool to probe the double-layer structure inside of porous electrodes and application in the modeling of capacitive deionization.” J. Phys. Chem. Lett., 1(1), 205–210.

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Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 143Issue 9September 2017

History

Received: Feb 2, 2016
Accepted: Feb 21, 2017
Published online: May 10, 2017
Published in print: Sep 1, 2017
Discussion open until: Oct 10, 2017

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Authors

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Research Assistant, Dept. of Water Engineering and Science, Hunan Univ., Changsha, Hunan 410082, China. E-mail: [email protected]
Hao L. Tang [email protected]
Assistant Professor, Dept. of Chemistry, Indiana Univ. of Pennsylvania, Indiana, PA 15705 (corresponding author). E-mail: [email protected]

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