Technical Papers
Jul 25, 2017

Modification of Shannon Entropy to Quantify Mixing in UV Reactors

Publication: Journal of Environmental Engineering
Volume 143, Issue 10

Abstract

Mixing or mixedness in ultraviolet (UV) wastewater reactors has been identified by many as a key factor in reactor performance. However, the current methods for determining mixing are either qualitative, and cannot be correlated directly with reactor performance, or use ideal mixing states that are not practical. In this paper, a modified Shannon entropy mixedness metric was used to quantify mixing in UV reactors. Contrary to the current literature which has shown that the mixedness only decreases when the number of regions into which the system is divided is increased, it is shown here numerically that mixedness can increase or decrease when the number of regions are increased. As well, it was proven numerically and theoretically that the mixedness will converge to a finite value with a sufficiently high number of regions. Furthermore, a highly simulated system that achieved perfect mixing under the modified mixedness equation produced a reduction equivalent dose (RED) almost 50% higher than the perfect mixing state under the original mixedness. The modification made to the mixedness equation suits the need of a UV reactor, but can also be applied to other process flow systems where mixing and reactor performance are linked. Finally, a very strong correlation between mixedness and UV reactor performance was found for two idealized single-lamp UV reactors. This means that the mixedness calculated here can be used as a proxy for reactor performance, allowing modelers to significantly reduce the computational cost required when comparing the performance of different reactors.

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References

ANSYS FLUENT 14.5 [Computer software]. ANSYS, Canonsburg, PA.
Brandani, G. B., Schor, M., MacPhee, C. E., Grubmüller, H., Zachariae, U., and Marenduzzo, D. (2013). “Quantifying disorder though conditional entropy: An application to fluid mixing.” PLoS One, 8(6), e65617.
Camesasca, M., Manas-Zloczower, I., and Kaufman, M. (2005). “Entropic characterization of mixing in microchannels.” J. Micromech. Microeng., 15(11), 2038–2044.
Cortelyou, J. R., et al. (1954). “Effects of ultraviolet irradiation on large populations of certain waterborne bacteria in motion.” Appl. Microbiol., 2, 227.
Danckwerts, P. V. (1953). “Continuous flow systems; distribution of residence times.” Chem. Eng. Sci., 2(1), 1–13.
Gandhi, V., Roberts, P. J. W., Stoesser, T., Wright, H., and Kim, J. H. (2011). “UV reactor flow visualization and mixing quantification using three-dimensional laser-induced fluorescence.” Water Res., 45(13), 3855–3862.
Haas, C. N., and Sakellaropoulos, G. P. (1979). “Rational analysis of UV disinfection reactors.” Proc., ASCE National Conf. on Environmental Engineers, ASCE, New York, 540–547.
Kattan, A., and Adler, R. J. (1972). “A conceptual framework for mixing in continuous chemical reactors.” Chem. Eng. Sci., 27(5), 1013–1028.
Khakhar, D. V., McCarthy, J. J., Shinbrot, T., and Ottino, J. M. (1997). “Transverse flow and mixing of granular materials in a rotating cylinder.” Phys. Fluids, 9(1), 31–43.
Lawryshyn, Y. A., and Cairns, B. (2003). “UV disinfection of water: The need for UV reactor validation.” Water Sci. Technol.: Water Supply, 3(4), 293–300.
Levenspiel, O (1999). Chemical reaction engineering, 3rd Ed., Wiley, New York.
Liu, D., Ducoste, J., Jin, S., and Linden, K. (2004). “Evaluation of alternative fluence rate distribution models.” J. Water Supply Res. Technol., 53(6), 319–408.
Masiuk, S., and Rakoczy, R. (2006). “The entropy criterion for the homogenisation process in a multi-ribbon blender.” Chem. Eng. Process, 45(6), 500–506.
Masiuk, S., Rakoczy, R., and Kordas, M. (2008). “Entropy criterion of random states for granular material in mixing process.” Chem. Papers, 62(3), 247–264.
MATLAB [Computer software]. MathWorks, Natick, MA.
Mohr, W. D., Saxton, R. L., and Jepson, C. H. (1957). “Mixing in laminar-flow systems.” Ind. Eng. Chem., 49(11), 1855–1856.
Ogawa, K., and Ito, S. (1973). “A definition of quality of mixedness.” J. Chem. Eng. Jpn., 8(2), 148–151.
Perugini, D., De Campos, C. P., Petrelli, M., Morgavi, D., Vetere, F. P., and Dingwell, D. B. (2015). “Quantifying magma mixing with Shannon entropy: Application to simulations and experiments.” Lithos, 236-236, 299–310.
Qualls, R. G., and Johnson, J. D. (1985). “Modelling and efficiency of ultraviolet disinfection systems.” Wat. Res., 19(8), 1039–1046.
Severin, B. F., Suidan, M. T., and Engelbrecht, R. S. (1984). “Mixing effects in UV disinfection.” J. Water Pollut. Control Fed., 56(7), 881–888.
Shannon, C. E. (1948). “A mathematical theory of communication.” Bell Syst. Tech. J., 27(3), 379–423.
Thampi, M. V., and Sorber, C. A. (1987). “A method for evaluating the mixing characteristics of UV reactors with short retention times.” Water Res., 21(7), 765–771.
USEPA (U.S. Environmental Protection Agency). (1986). “Design manual: Municipal wastewater disinfection.” EPA/625/1-86/021, Cincinnati.
White, S. C., Jernigan, E. B., and Venosa, A. D. (1986). “A study of operational ultraviolet disinfection equipment at secondary treatment plants.” J. Water Pollut. Control Fed., 58, 181–192.
Wilcox, D. C. (1998). Turbulence modeling for CFD, 2nd Ed., DCW Industries, Anaheim, CA.
Wright, H., and Lawryshyn, Y. (2000). “An assessment of the bioassay concept for UV reactor validation.” Proc. Water Environ. Fed., 2000(2), 378–400.
Zhao, Z. F., Mehrvar, M., and Ein-Mozaffari, F. (2008). “Mixing time in an agitated multi-lamp cylindrical photoreactor using electrical resistance tomography.” J. Chem. Technol. Biotechnol., 83(12), 1676–1688.
Zweitering, T. H. (1959). “The degree of mixing in continuous flow systems.” Chem. Eng. Sci., 11(1), 1–15.

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 143Issue 10October 2017

History

Received: May 4, 2016
Accepted: Oct 31, 2016
Published online: Jul 25, 2017
Published in print: Oct 1, 2017
Discussion open until: Dec 25, 2017

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Authors

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Colin Powell [email protected]
Ph.D. Student, Dept. of Chemical Engineering and Applied Chemistry, Univ. of Toronto, 200 College St., Toronto, ON, Canada M5S 3E1 (corresponding author). E-mail: [email protected]
Yuri Lawryshyn, Ph.D. [email protected]
P.Eng.
Associate Professor, Dept. of Chemical Engineering and Applied Chemistry, Univ. of Toronto, 200 College St., Toronto, ON, Canada M5S 3E1. E-mail: [email protected]

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