Technical Papers
May 24, 2016

Photocatalytic Degradation of Polycyclic Aromatic Hydrocarbons in Offshore Produced Water: Effects of Water Matrix

Publication: Journal of Environmental Engineering
Volume 142, Issue 11

Abstract

To demonstrate the feasibility of photocatalysis for the removal of polycyclic aromatic hydrocarbons (PAHs) from offshore-produced water (OPW), the effects of water matrix were studied by comparing the performance of TiO2-induced photocatalysis in distilled water and OPW media. The effects of salinity, insoluble particulate matter, and organic composition were evaluated. The results showed the strong improvements with the addition of catalysts but the enhancement of photocatalysis was restricted by OPW media. The photocatalytic degradation of PAHs with high molecular weights was more sensitive to the variations of salinity and insoluble matter due to their lower solubility. The overall degradation of PAHs was strongly restricted by the organic composition in OPW particularly the aromatic compounds. The aromatic compounds played an important role as ultraviolet-photon absorbents and competed with the photodegradation of PAHs. Because of their abundance in OPW, these species had the most significant effect on the photocatalytic degradation of PAHs.

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Acknowledgments

This research was funded by Natural Sciences and Engineering Research Council of Canada (NSERC), Research and Development Corporation of Newfoundland and Labrador (RDC NL), and Canadian Foundation of Innovation (CFI). Thanks go to the Fisheries and Oceans Canada (DFO) and local industrial partners for their support and technical advice.

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 142Issue 11November 2016

History

Received: Nov 11, 2015
Accepted: Feb 29, 2016
Published online: May 24, 2016
Discussion open until: Oct 24, 2016
Published in print: Nov 1, 2016

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Graduate Student, Faculty of Engineering and Applied Science, Memorial Univ. of Newfoundland, St. John’s, NL, Canada A1B 3X5. E-mail: [email protected]
Bing Chen, M.ASCE [email protected]
Associate Professor, Faculty of Engineering and Applied Science, Memorial Univ. of Newfoundland, St. John’s, NL, Canada A1B 3X5 (corresponding author). E-mail: [email protected]
Bai Yu Zhang, M.ASCE [email protected]
Associate Professor, Faculty of Engineering and Applied Science, Memorial Univ. of Newfoundland, St. John’s, NL, Canada A1B 3X5. E-mail: [email protected]
Postdoctoral Fellow, Faculty of Engineering and Applied Science, Memorial Univ. of Newfoundland, St. John’s, NL, Canada A1B 3X5. E-mail: [email protected]
Graduate Student, Faculty of Engineering and Applied Science, Memorial Univ. of Newfoundland, St. John’s, NL, Canada A1B 3X5. E-mail: [email protected]
Kenneth Lee [email protected]
Director of the Oceans and Atmosphere Flagship, Common wealth Scientific and Industrial Research Organisation, Kensington, WA 6102, Australia. E-mail: [email protected]

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