Technical Papers
May 27, 2016

Effect of H2O2 on UV Photo-Oxidation of Pharmaceuticals and Personal Care Products in Wastewater

Publication: Journal of Environmental Engineering
Volume 142, Issue 11

Abstract

This study investigates the effect of low levels of hydrogen peroxide (H2O2) on photo-oxidation of pharmaceuticals and personal care products (PPCPs) present in secondary effluent of a municipal wastewater treatment plant (WWTP). Experiments were conducted using two types of flow-through reactor systems: (1) three ultraviolet light (UV) reactors connected in series without a H2O2 addition, and (2) a UV reactor with a H2O2 addition. In the first part of this study, 38 PPCPs detected in secondary effluent were examined based on their degradability by UV in the presence and absence of H2O2. For the PPCPs that were not degraded to or below their detection level, the pseudo first-order photo-oxidation rate constants, k (s1), were determined using a mathematical model developed for three continuously stirred tank reactors in series. The second part of the study investigated the kinetics of the selected PPCPs in the UV/H2O2 reactor. The effect of low concentrations of H2O2 on the photo-oxidation rate of PPCPs was quantified by the power function expression.

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Acknowledgments

The draft version of the manuscript was prepared during the visiting scholar program under the auspices of Kyoto University.

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 142Issue 11November 2016

History

Received: Oct 27, 2015
Accepted: Feb 23, 2016
Published online: May 27, 2016
Discussion open until: Oct 27, 2016
Published in print: Nov 1, 2016

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Chikashi Sato, A.M.ASCE [email protected]
Professor, Dept. of Civil and Environmental Engineering, Idaho State Univ., 921 S. 8th Ave., Stop 8060, Pocatello, ID 83209 (corresponding author). E-mail: [email protected]
Associate Professor, Dept. of Construction Environment Engineering, Univ. of Science and Technology, (Daehwa-Dong 2311) 283, Goyangdae-ro Ilsanseo-gu, Goyang-si, Kyonggi-do 411-712, Republic of Korea; Senior Researcher, Environmental and Plant Engineering Institute, Korea Institute of Civil Engineering and Building Technology, (Daehwa-Dong 2311) 283, Goyangdae-ro Ilsanseo-gu, Goyang-si, Kyonggi-do 411-712, Republic of Korea. E-mail: [email protected]
Hiroaki Tanaka [email protected]
Professor, Graduate School of Engineering, Research Center for Environmental Quality Management, Kyoto Univ., 1-2 Yumihama, Otsu, Shiga 520-0811, Japan. E-mail: [email protected]

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