Technical Papers
May 6, 2016

Electrochemical Degradation of Acid Yellow 23 by Anodic Oxidation—Optimization of Operating Parameters

Publication: Journal of Environmental Engineering
Volume 142, Issue 11

Abstract

In this study, the electrochemical oxidation (EO) process was implemented and optimized to effectively decolorize and degrade wastewater containing Acid Yellow 23 (Y23). The experiments were carried out in a laboratory-scale batch cell reactor, with monopolar configuration of electrodes, made of graphite (anode) and titanium (cathode). The response surface methodology (RSM), coupled with Box-Behnken experimental design (BBD), was used to evaluate the single and interactive effects of different variables of the EO process on (1) degradation percentages of both chemical oxygen demand (%DCOD) and color (%DC) and (2) energy consumption (EC). Thus, the following experimental factors were considered: initial dye concentration (40100mg/L), current density (1020mA/cm2), and conductivity (1,0004,000μS/cm). Thus, the subsequent conditions were found to be optimal for decolorization and degradation of Y23: initial dye concentration = 100mg/L; current density = 20mA/cm2; and conductivity = 4,000μS/cm. At these conditions, the EO process allowed to reach approximately 99% of color degradation and 76% of COD degradation. Because NaCl was used as an electrolyte, chorine formation was monitored, and its effect on %DC and %DCOD was also evaluated.

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Acknowledgments

The authors thank the Dirección de Investigación de la Universidad EAFIT, Medellin, Colombia, for its financial support of this research. The staff of the Laboratorio de Ingeniería de Procesos is also recognized for its participation.

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 142Issue 11November 2016

History

Received: Sep 28, 2015
Accepted: Feb 10, 2016
Published online: May 6, 2016
Discussion open until: Oct 6, 2016
Published in print: Nov 1, 2016

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Authors

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Edison GilPavas [email protected]
Professor, Departamento de Ingeniería de Procesos, Universidad EAFIT, Grupo de Investigación en Procesos Ambientales (GIPAB), Cr 49 #7 sur 50, Medellín, Colombia (corresponding author). E-mail: [email protected]
Izabela Dobrosz-Gómez [email protected]
Associate Professor, Departamento de Física y Química, Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Colombia, Sede Manizales, Grupo de Investigación en Procesos Reactivos Intensificados con Separación y Materiales Avanzados (PRISMA), Campus La Nubia, vía al Aeropuerto, A.A 127, Manizales, Caldas, Colombia. E-mail: [email protected]
Miguel Ángel Gómez-García [email protected]
Professor, Departamento de Ingeniería Química, Facultad de Ingeniería y Arquitectura, Universidad Nacional de Colombia, Sede Manizales, Grupo de Investigación en Procesos Reactivos Intensificados con Separación y Materiales Avanzados (PRISMA), Campus La Nubia, vía al Aeropuerto, A.A 127, Manizales, Caldas, Colombia. E-mail: [email protected]

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