Optimization of Phenol Removal Using Anode with Response Surface Methodology
This article has a reply.
VIEW THE REPLYPublication: Journal of Environmental Engineering
Volume 142, Issue 4
Abstract
Scale-up of a lead dioxide () anode system is significant to the practical application of electrochemical oxidation (EO) in biorefractory wastewater treatment. In this study, response surface methodology (RSM) was employed to investigate the effects of different operating conditions on phenol removal by electro-oxidation with a anode. A central composite design (CCD) was used to optimize the electro-oxidation process and to evaluate the individual and interactions effects of current intensity, electrolysis time, and recirculation flow rate on phenol removal. Synthetic wastewater (or distillate water) with phenol concentration of was used in this study. Optimal conditions for phenol removal were established at 1.12 A current intensity, 40 min electrolysis time, and recirculation flow rate, in which a removal of was achieved. The decay kinetics of phenol removal was fitted a first-order reaction.
Get full access to this article
View all available purchase options and get full access to this article.
References
Ahmad, S. A., Shamaan, N. A., Arif, N. M., Koon, G. B., Shukor, M. Y., Syed, M. A. (2012). “Enhanced phenol degradation by immobilized Acinetobacter sp. strain AQ5NOL 1.” World J. Microbiol. Biotechnol., 28(1), 347–352.
Alves, S., Ferreira, T., Migliorini, F., Baldan, M., Ferreira, N., and Lanzaa, M. (2013). “Electrochemical degradation of the insecticide methyl parathion using a boron-doped diamond film anode.” J. Electroanal. Chem., 702, 1–7.
Buscaa, G., Berardinelli, S., Resini, C., and Arrighi, L. (2008). “Technologies for the removal of phenol from fluid streams: A short review of recent developments.” J. Hazard. Mater., 160(2–3), 265–288.
Chatzisymeon, E., Fierro, S., Karafyllis, I., Mantzavinos, D., Kalogerakis, N., and Katsaounis, A. (2010). “Anodic oxidation of phenol on Ti/IrO2 electrode: Experimental studies.” Catal. Today, 151(1–2), 185–189.
Design Expert version 7 [Computer software]. Stat-Ease, Minneapolis.
Eaton, A. D., Clescerl, L. S., Rice, E. W., and Greenberg, A. E. (2005). Standard methods for examination of water and wastewater, 21st Ed., American Public Health Association, Washington, DC.
Fenga, L., Van Hullebuscha, E., Rodrigo, M., Esposito, G., and Oturan, M. (2013). “Removal of residual anti-inflammatory and analgesic pharmaceuticals from aqueous systems by electrochemical advanced oxidation processes: A review.” Chem. Eng. J., 228, 944–964.
Feng, Y., and Li, X. (2003). “Electro-catalytic oxidation of phenol on several metal-oxide electrodes in aqueous solution.” Water Res., 37(10), 399–407.
Hu, F., Cui, X., and Chen, W. (2010). “Pulse electro-codeposition of electrode for phenol oxidation.” Electrochem. Solid State Lett., 13(9), F20–F23.
Joglekar, A. M., and May, A. T. (1987). “Product excellence through design of experiments.” Cereal Foods World, 32, 857–868.
Joshi, M., and Shambaugh, R. (1982). “The kinetics of ozone-phenol reaction in aqueous solution.” Water Res., 16(6), 933–938.
Keith, L., and Telliand, W. (1979). “ES&T special report: Priority pollutants: I. A perspective view.” Environ. Sci. Technol., 13(4), 416–423.
Lefevre, S., Boutin, O., Ferrasse, J., Malleret, L., Faucherand, R., and Viand, A. (2011). “Thermo dynamic and kinetic study of phenol degradation by a non-catalytic wet air oxidation process.” Chemosphere, 84(9), 1208–1215.
Li, X., Cui, Y., Feng, Y., Xie, Z. M., and Gu, J. D. (2005). “Reaction pathways and mechanisms of the electrochemical degradation of phenol on different electrodes.” Water Res., 39(10), 72–81.
Luoa, Y., et al. (2014). “A review on the occurrence of micropollutants in the aquatic environment and their fate and removal during wastewater treatment.” Sci. Total Environ., 473–474, 619–641.
Manojlovic, D., Ostojic, D., Obradovic, B., Kuraica, M., Krsmanovic, V., and Puric, J. (2007). “Removal of phenol and chlorophenols from water by new ozone generator.” Desalination, 213(1–3), 116–122.
Martınez, C., Battisti, A., Ferro, S., Reyna, S., Cerro, M., and Quiro, M. (2008). “Removal of the pesticide methamidophos from aqueous solutions by electrooxidation using , , and electrodes.” Environ. Sci. Technol., 42(18), 29–35.
Myers, R., and Montgomery, D. (2002). Response surface methodology: Process and product optimization using designed experiments, 2nd Ed., Wiley, New York.
Panizza, M., and Cerisola, G. (2003). “Influence of anode material on the electrochemical oxidation of 2-naphthol: Part 1. Cyclic voltammetry and potential step experiments.” Electrochim. Acta, 48(23), 3491–3497.
Samet, Y., Agengui, L., and Abdelhédi, R. (2010). “Anodic oxidation of chlorpyrifos in aqueous solution at lead dioxide electrodes.” J. Electroanal. Chem., 650(1), 152–158.
Su, J., Lin, H., Wang, Q., Xie, Z., and Chen, Z. (2011). “Adsorption of phenol from aqueous solutions by organomontmorillonite.” Desalination, 269(1–3), 163–169.
Suryanarayanan, V., Nakazawa, I., Yoshihara, S., and Shirakashi, T. (2006). “The influence of electrolyte media on the deposition/dissolution of lead dioxide on boron-doped diamond electrode—A surface morphologic study.” J. Electroanal. Chem., 592(2), 175–182.
Szpyrkowicz, L., Kaul, S., Neti, R., and Satyanaray, S. (2005). “Influence of anode material on electrochemical oxidation for the treatment of tannery wastewater.” Water Res., 39(8), 1601–1613.
Tran, L., Drogui, P., Mercier, G., and Blais, J. (2009). “Electrochemical degradation of polycyclic aromatic hydrocarbons in creosote solution using ruthenium oxide on titanium expanded mesh anode.” J. Hazard. Mater., 164(1), 18–25.
Urtiaga, A., Fernandez, P., Gómez, P., and Ortiz, I. (2014). “Remediation of wastewaters containing tetrahydrofuran. Study of the electrochemical mineralization on BDD electrodes.” Chem. Eng. J., 239, 341–350.
Wei, J., Feng, Y., Sun, X., Liu, J., and Zhu, L. (2011). “Effectiveness and pathways of electrochemical degradation of pretilachlor herbicides.” J. Hazard. Mater., 189(1–2), 84–91.
Xu, X., et al. (2011). “Evaluation of photocatalytic production of active oxygen and decomposition of phenol in ZnO suspensions.” Rare Metals, 30, 188–191.
Zhu, X., Ni, J., and Lai, P. (2009). “Advanced treatment of biologically pretreated coking wastewater by electrochemical oxidation using boron-doped diamond electrodes.” Water Res., 43(17), 4347–4355.
Zhuo, Q., Deng, S., Yang, B., Huang, J., and Yu, G. (2011). “Efficient electrochemical oxidation of perfluorooctanoate using a anode.” Environ. Sci. Technol., 45(7), 2973–2979.
Zhu, X., Tong, M., Shi, S., Zhao, H., and Ni, J. (2008). “Essential explanation of the strong mineralization performance of boron-doped diamond electrodes.” Environ. Sci. Technol., 42(13), 4914–4920.
Information & Authors
Information
Published In
Copyright
© 2016 American Society of Civil Engineers.
History
Received: Jun 9, 2015
Accepted: Sep 23, 2015
Published online: Jan 7, 2016
Published in print: Apr 1, 2016
Discussion open until: Jun 7, 2016
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.