Technical Papers
Jun 30, 2015

General Model of Chlorine Decay in Blends of Surface Waters, Desalinated Water, and Groundwaters

Publication: Journal of Environmental Engineering
Volume 141, Issue 12

Abstract

Management goals for many distribution systems include maintaining a minimum level of free chlorine and limiting disinfection by-products. As water resources become scarce and quality deteriorates, blends are often required, so achieving these goals becomes increasingly difficult. The augmented two-reactant (2RA) model describes chlorine decay in a single water, for various dosing levels and water temperatures. However, it is not known whether there is any effect on chlorine decay (either synergistic or antagonistic) arising from blending waters of distinctly different quality. Linked 2RA models of source waters were used to determine whether bulk decay in blends of various source waters could be accurately and generally modeled. Results showed that chlorine decay in blends of various waters could be described accurately without synergistic or antagonistic effects, implying that each water’s reactants reduced chlorine independently. This held for pairs of surface waters, groundwaters, and raw or treated surface water blended with desalinated water, for various initial chlorine doses and temperatures. Linked models can be incorporated immediately into system models, to predict bulk chlorine decay and trihalomethane (THM) formation in distribution systems supplied from several water sources.

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Acknowledgments

Decay tests for the two surface waters and their blends were funded by the Sydney Catchment Authority and conducted at the University of Western Sydney, Australia. Experimental work involving desalinated water and its blends was funded by SA Water and completed at the Australian Water Quality Centre. Experimental work on groundwater/artesian water was carried out by Water Corporation, Western Australia, as part of the research program of the Australian Cooperative Research Centre for Water Quality and Treatment.

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Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 141Issue 12December 2015

History

Received: Jul 18, 2014
Accepted: Apr 28, 2015
Published online: Jun 30, 2015
Discussion open until: Nov 30, 2015
Published in print: Dec 1, 2015

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Authors

Affiliations

Ian Fisher, Ph.D. [email protected]
Director, Watervale Systems, P.O. Box 318, Potts Point, NSW 1335, Australia (corresponding author). E-mail: [email protected]
George Kastl
Research Student, School of Computing, Engineering and Mathematics, Univ. of Western Sydney, Locked Bag 1797, Penrith, NSW 2751, Australia.
Arumugam Sathasivan, Ph.D.
Associate Professor, School of Computing, Engineering and Mathematics, Univ. of Western Sydney, Locked Bag 1797, Penrith, NSW 2751, Australia.
David Cook
Senior Scientist, Australian Water Quality Centre, GPO Box 1751, Adelaide, SA 5001, Australia.
Lalantha Seneverathne, Ph.D.
Research Associate, School of Computing, Engineering and Mathematics, Univ. of Western Sydney, Locked Bag 1797, Penrith, NSW 2751, Australia.

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