Technical Papers
Sep 4, 2015

Using Focused Pulsed Technology to Remove Siloxane from Municipal Sewage Sludge

Publication: Journal of Environmental Engineering
Volume 142, Issue 1

Abstract

Siloxanes, impurities in the biogas produced from anaerobic digestion of wastewater sludges, are transformed to silica dioxide sand during combustion of the biogas, which damages the heat exchanger and engine. Decamethylcyclopenta-siloxane (D5) and octamethylcyclotetra-siloxane (D4) were added to return activated sludge (RAS) and treated using a pulsed-electric field method [focused pulsed (FP)] that makes the sludge solids more readily converted to methane. With an FP treatment intensity (TI) of 36kWh/m3-RAS, the D4, and D5 removal efficiencies were 32±4.0 and 11±0.2%, respectively. Removals of D4 and D5 increased proportionally with TI whether TI was affected by sludge conductivity or FP pulse frequency. FP treatment of activated sludge before methanogenic batch tests lowered the amount of both siloxanes in the produced biogas, and evidence suggests that the siloxanes were biotransformed during the batch tests.

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Acknowledgments

The authors would like to thank OpenCEL LLC for their financial support of this research and Rod Caldwell for operation of the FP unit.

References

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 142Issue 1January 2016

History

Received: Dec 4, 2012
Accepted: Apr 6, 2015
Published online: Sep 4, 2015
Published in print: Jan 1, 2016
Discussion open until: Feb 4, 2016

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Authors

Affiliations

Environmental Engineer, Freeport-McMoRan Inc., 1600 E. Hanley Blvd., Oro Valley, AZ 85737; formerly, Postdoctoral Researcher, Swette Center for Environmental Biotechnology, Biodesign Institute at Arizona State Univ., 1001 South McAllister Ave., Tempe, AZ 85287-5701 (corresponding author). E-mail: [email protected]
Bruce E. Rittmann, Dist.M.ASCE [email protected]
Director, Swette Center for Environmental Biotechnology, Biodesign Institute at Arizona State Univ., 1001 South McAllister Ave., Tempe, AZ 85287-5701. E-mail: [email protected]

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