Adsorption of Acid Extractable Oil Sands Tailings Organics onto Raw and Activated Oil Sands Coke
Publication: Journal of Environmental Engineering
Volume 138, Issue 8
Abstract
The accumulation of organic contaminants in process-affected (PA) water represents an environmental liability for oil sands operators. Oil sands coke is a promising adsorbent for removing dissolved organic carbon (DOC), which includes toxic acid-extractable oil sands tailings organics (AEOSTO) found in PA water. The ability of raw and activated delayed and fluid coke to remove DOC and AEOSTO from PA water was assessed. Treatment with of activated delayed and fluid coke removed 91% of DOC and 92% of AEOSTO at levels of and , respectively. Heavy metal leaching of vanadium at was observed for a application of activated delayed coke, representing a challenge to the approach. Microtox testing indicated that higher carbon doses of activated cokes were effective in reducing toxic the biological response caused by organic compounds; however, exposure to heavy metals increased the toxic effect with time. The proposed methodology should be coupled with an inorganic treatment technique for complete oil sands tailings water treatment.
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Acknowledgments
The authors would like to acknowledge financial support from the Natural Science and Engineering Research Council (NSERC) of Canada. We would also like to thank Suncor Energy Inc. and Syncrude Canada Ltd. for providing delayed and fluid coke samples.
References
Allen, E. W. (2008a). “Process water treatment in Canada’s oil sands industry: I. Target pollutants and treatment objectives.” J. Environ. Eng. Sci.JEESAX, 7(2), 123–138.
Allen, E. W. (2008b). “Process water treatment in Canada’s oil sands industry: II. A review of emerging technologies.” J. Environ. Eng. Sci.JEESAX, 7(5), 499–524.
ASTM. (2006). “Standard test method for determination of iodine number of activated carbon.” D4607-94, West Conshohocken, PA.
ASTM. (2007). “Standard practice for general techniques for obtaining infrared spectra for qualitative analysis.” E1252-98, West Conshohocken, PA.
ASTM. (2008). “Standard test method for 24-h batch-type measurement of contaminated sorption by soils and sediments.” D4646-03, West Conshohocken, PA.
ASTM. (2009). “Standard test method for assessing the microbial detoxification of chemically contaminated water and soil using a toxicity test with a luminescent marine bacterium.” D5660-96, West Conshohocken, PA.
Barrow, M. P., Witt, M., Headley, J. V., and Peru, K. M. (2010). “Athabasca oil sands process water: Characterization by atmospheric pressure photoionization and electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry.” Anal. Chem.ANCHAM, 82(9), 3727–3735.
Brethor, P. (2008). “Suncor’s coke solution? Ahoy, Port Alberta (near Prince Rupert).” 〈http://oilsandstruth.org/suncor039s-coke-solution-ahoy-port-alberta-near-prince-rupert〉 (Nov. 16, 2009).
Canadian Council of Ministers of the Environment (CCME). (1999). “Canadian water quality guidelines for the protection of aquatic life: Molybdenum.” Winnipeg, Canada.
Canadian Council of Ministers of the Environment (CCME). (2006). “Canadian environmental quality guidelines.” Winnipeg, Canada.
Chen, H. (2010). “Microwave heating for adsorbents regeneration and oil sands coke activation.” M.S. thesis, Univ. of Alberta, Edmonton, Canada.
Chen, L., Kost, D., and Dick, W. A. (2010). “Petroleum coke circulating fluidized bed combustion product effects on soil and water quality.” Soil Sci.SOSCAK, 175(6), 270–277.
Clemente, J. S., and Fedorak, P. M. (2005). “A review of the occurrence, analyses, toxicity, and biodegradation of naphthenic acids.” ChemosphereCMSHAF, 60(5), 585–600.
Clesceri, L. S., Greenberg, A. E., and Eaton, A. D. (1999). Standard methods for the examination of water and wastewater, 20th Ed., American Public Health Association, Washington, DC, 5–32.
Dąbrowski, A., Podkościelny, P., Hubicki, Z., and Barczak, M. (2005). “Adsorption of phenolic compounds by activated carbon—A critical review.” ChemosphereCMSHAF, 58(8), 1049–1070.
Del Rio, L. F., Hadwin, A. K. M., Pinto, L. J., MacKinnon, M. D., and Moore, M. M. (2006). “Degradation of naphthenic acids by sediment micro-organisms.” J. Appl. Microbiol.JAMIFK, 101(5), 1049–1061.
Fedorak, P. M., and Coy, D. L. (2006). “Oil sands cokes affect microbial activities.” FuelFUELAC, 85(12–13), 1642–1651.
Grewer, D. M., Young, R. F., Whittal, R. M., and Fedorak, P. M. (2010). “Naphthenic acids and other acid-extractables in water samples from Alberta: What is being measured?” Sci. Total Environ.STENDL, 408(23), 5997–6010.
Hao, C., Headley, J. V., Peru, K. M., Frank, R., Yang, P., and Solomon, K. R. (2005). “Characterization and pattern recognition of oil-sand naphthenic acids using comphrehensive two-dimensional gas chromatography/time-of-flight mass spectrometry.” J. Chromatogr., AJCRAEY, 1067(1–2), 277–284.
Holowenko, F. M., MacKinnon, M. D., and Fedorak, P. M. (2001). “Naphthenic acids and surrogate naphthenic acids in methanogenic microcosms.” Water Res., 35(11), 2595–2606.
Ityokumbul, M. T. (1994). “Experimental evaluation of molten caustic leaching of an oil sand coke residue.” Can. J. Chem. Eng.CJCEA7, 72(2), 370–374.
Karanfil, T., and Kilduff, J. E. (1999). “Role of granular activated carbon surface chemistry on the adsorption of organic compounds. 1. Priority pollutants.” Environ. Sci. Technol.ESTHAG, 33(18), 3217–3224.
Kavanagh, R. J., Burnison, B. K., Frank, R. A., Solomon, K. R., and Van DerFraak, G. (2009). “Detecting oil sands process-affected waters in the Alberta oil sands region using synchronous fluorescence spectroscopy.” ChemosphereCMSHAF, 76(1), 120–126.
LeGendre, G. R., and Runnells, D. D. (1975). “Removal of dissolved molybdenum from waste waters by precipitates of ferric iron.” Environ. Sci. Technol.ESTHAG, 9(8), 744–749.
Lo, C. C., Brownlee, B. G., and Bunce, N. J. (2006). “Mass spectrometric and toxicological assays of Athabasca oil sands naphthenic acids.” Water Res.WATRAG, 40(4), 655–664.
Pavoni, B., Drusian, D., Giacometti, A., and Zanette, M. (2006). “Assessment of organic chlorinated compound removal from aqueous matrices by adsorption on activated carbon.” Water Res.WATRAG, 40(19), 3571–3579.
Petala, M., Tsiridis, V., Kyriazis, S., Samaras, P., Kungolos, A., and Sakellaropoulos, G. P. (2005). “Evaluation of toxic response of heavy metals and organic pollutants using Microtox acute toxicity test.” Proc., 9th Int. Conf. on Environmental Science and Technology, Global NEST, Athens, Greece, 1–6.
Poleo, A. B. S. (1995). “Aluminum polymerization- a mechanism of acute toxicity of aqueous aluminum to fish.” Aquat. Toxicol.AQTODG, 31(4), 347–356.
Qi, S., and Schideman, L. C. (2008). “An overall isotherm for activated carbon adsorption of dissolved natural organic matter in water.” Water Res.WATRAG, 42(13), 3353–3360.
Quagraine, E. K., Peterson, H. G., and Headley, J. V. (2005). “In situ bioremediation of naphthenic acids contaminated tailing pond waters in the Athabasca oil sands region–Demonstrated field studies and plausible options: A review.” J. Environ. Sci. Health Part A: Toxic/Hazard. Subst. Environ. Eng.JATEF9, 40(3), 685–722.
Quinlivan, P. A., Li, L., and Knappe, R. U. (2005). “Effects of activated carbon characteristics on the simultaneous adsorption of aqueous organic micropollutants and natural organic matter.” Water Res.WATRAG, 39(8), 1663–1673.
Randall, D. J., and Tsui, T. K. N. (2002). “Ammonia toxicity in fish.” Mar. Pollut. Bull.MPNBAZ, 45(1–12), 17–23.
Rowland, S. J., West, C. E., Scarlett, A. G., Jones, D., and Frank, R. A. (2011). “Identification of individual tetra- and pentacyclic naphthenic acids in oil sands process water by comprehensive two-dimensional gas chromatography/mass spectrometry.” Rapid Commun. Mass Spectrom.RCMSEF, 25(9), 1198–1204.
Scott, A. C., Young, R. F., and Fedorak, P. M. (2008). “Comparison of GC-MS and FTIR methods for quantifying naphthenic acids in water samples.” ChemosphereCMSHAF, 73(8), 1258–1264.
Shawwa, A. R., Smith, D. W., and Sego, D. C. (2001). “Color and chlorinated organics removal from pulp mills wastewater using activated petroleum coke.” Water Res.WATRAG, 35(3), 745–749.
Sing, K. S. W., et al. (1985). “Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity.” Pure Appl. Chem.PACHAS, 57(4), 603–619.
Small, C. C., Hashisho, Z., and Ulrich, A. C. (2012). “Preparation and characterization of activated carbon from oil sands coke.” FuelFUELAC, 92(1), 69–76.
Smith, E. H. (1991). “Evaluation of multicomponent adsorption equilibria for organic mixtures onto activated carbon.” Water Res.WATRAG, 25(2), 125–134.
Stavropoulos, G. G., and Zabaniotou, A. A. (2009). “Minimizing activated carbons production cost.” Fuel Process. Technol.FPTEDY, 90(7–8), 952–957.
Synek, V. (2008). “Evaluation of the standard deviation from duplicate results.” Accred. Qual. Assur., 13(6), 335–337.
U.S. Army Corps of Engineers. (2001). “Engineering and design: Adsorption design guide.” Design Guide No. 1110-1-2, Dept. of the Army, Washington, DC, 1–99.
Whitby, C. (2010). “Microbial naphthenic acid degradation.” Adv. Appl. Microbiol., 70ADAMAP, 93–125.
Yang, R. T. (2003). “Adsorbents: fundamentals and applications.” Wiley, New York, 70–130.
Yen, T., Marsh, W. P., MacKinnon, M. D., and Fedorak, P. M. (2004). “Measuring naphthenic acids in aqueous environmental samples by liquid chromatography.” J. Chromatogr. AJCRAEY, 1033(1), 83–90.
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© 2012. American Society of Civil Engineers.
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Received: May 30, 2011
Accepted: Jan 31, 2012
Published online: Feb 2, 2012
Published in print: Aug 1, 2012
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