TECHNICAL NOTES
Apr 8, 2010

Photoreduction of Reactive Brilliant Red X-3B by Ultraviolet Irradiation/Potassium Borohydride/Sodium Bisulfite

Publication: Journal of Environmental Engineering
Volume 136, Issue 11

Abstract

Photoreduction of Reactive Brilliant Red X-3B in aqueous solution by ultraviolet irradiation/potassium borohydride/sodium bisulfite (UV/KBH4/NaHSO3) was investigated. The effects of operational parameters including KBH4 dosage, NaHSO3 dosage, pH value, and temperature were studied. The reaction mechanism was also discussed. The preliminary results showed that UV and KBH4/NaHSO3 had a significant synergy for the decolorization. At the conditions of 6-mg KBH4 , 250-mg NaHSO3 , pH 6.0, and room temperature, highest color removal percentage was achieved. From the mechanism discussion, we could conjecture that the mechanism of photoreduction was mainly caused by the production of sulfur dioxide anion radicals, and UV irradiation played a vital role during the process.

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Acknowledgments

The writers are very grateful to the editor and anonymous reviewers for their valuable comments and suggestions. This work was supported by the National Basic Research Program (973) of China (Grant No. UNSPECIFIED2008CB418004) and the Major Projects on Control and Rectification of Water Body Pollution (Water Special Project) (Grant No. UNSPECIFIED2008ZX07526-002).

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Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 136Issue 11November 2010
Pages: 1314 - 1319

History

Received: Aug 12, 2009
Accepted: Apr 2, 2010
Published online: Apr 8, 2010
Published in print: Nov 2010

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Authors

Affiliations

Jie Fu
Ph.D. Student, State Key Laboratory of Pharmaceutical Biotechnology, School of Life Sciences, Nanjing Univ., Nanjing 210093, People’s Republic of China.
Zhi-Ming Zhang
Graduate Student, State Key Laboratory of Pharmaceutical Biotechnology, School of Life Sciences, Nanjing Univ., Nanjing 210093, People’s Republic of China.
Jia-Yu Tang
Graduate Student, State Key Laboratory of Pharmaceutical Biotechnology, School of Life Sciences, Nanjing Univ., Nanjing 210093, People’s Republic of China.
Qing-Fu Zeng
Professor, Engineering Research Center for Clean Production of Textile Dyeing and Printing of Ministry of Education, Wuhan Univ. of Science and Engineering, Wuhan 430073, People’s Republic of China (corresponding author).
Shu-Qing An
Professor, State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing Univ., Nanjing 210093, People’s Republic of China.
Hai-Liang Zhu [email protected]
Professor, State Key Laboratory of Pharmaceutical Biotechnology, School of Life Sciences, Nanjing Univ., Nanjing 210093, People’s Republic of China. E-mail: [email protected]

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