TECHNICAL PAPERS
Dec 18, 2009

Feasibility of Using Coal Fly Ash for Mine Waste Containment

Publication: Journal of Environmental Engineering
Volume 136, Issue 7

Abstract

This study investigates the feasibility of using coal fly ash and fly ash-bentonite mixtures as a barrier material for mine waste. The hydraulic conductivity of the coal fly ash was measured to be in the order of 2×109m/s when it was permeated with deionized water, and this value decreased significantly when the permeant was switched to acid mine drainage (AMD). The addition of bentonite to coal fly ash lowered the hydraulic conductivity during water permeation but no further significant change was observed upon switching the permeant to AMD. Chemical analyses on the effluent from the hydraulic conductivity tests indicated that heavy metals present in AMD were attenuated and were well below the leachate criteria set by the Ontario Government. X-ray diffraction and scanning electron microscopy analyses results of postpermeation samples showed significant structural differences and formation of secondary minerals after AMD permeation. The results of this study suggest that the addition of 10% bentonite to coal fly ash reduced the hydraulic conductivity of the coal fly ash to less than 1×109m/s and improved the chemical compatibility for mine waste containment.

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Acknowledgments

The work described in this paper was funded by the Natural Sciences and Engineering Research Council of Canada (NSERC) Corporate Research and Development Project (Grant No. UNSPECIFIEDCRDPJ 319808-04), Goldcorp Musselwhite Mine, Ontario Power Generation-Atikokan Generating Station, and Golder Associates Ltd.

References

Allison, J. D., Brown, D. S., and Novo-Gradac, K. J. (1991). MINTEQA2/PRODEFA2: A geochemical assessment model for environmental systems—Version 3.0 user’s manual, U.S. EPA, Athens, Ga.
Barone, F. S., Yanful, E. K., Quigley, R. M., and Rowe, R. K. (1989). “Effect of multiple contaminant migration on diffusion and adsorption of some domestic waste contaminants in a natural clayey soil.” Can. Geotech. J., 26, 189–198.
Bowders, J. J., Daniel, D. E., Broderick, G. P., and Liljestrand, H. M. (1986). “Methods for testing the compatibility of clay liners with landfill leachate.” ASTM STP886—Hazardous and Industrial Solid Waste Testing: 4th Symp., J. K. Petros, Jr., W. J. Lacy, and R. A. Conway, eds., ASTM, West Conshoken, Pa., 233–250.
Bowders, J. J., Usmen, M. A., and Gidley, J. S. (1987). “Stabilized fly ash for use as low permeability barriers.” Geotechical Practice for Waste Disposal ’87, R. D. Woods, ed., ASCE, New York, 320–333.
Chhabra, R., Pleysier, J., and Cremers, A. (1975).” The measurement of the cation exchange capacity and exchangeable cations in soils: A new method.” Proc., Int. Clay Conf., Applied Publishing Ltd., Wilmette, Ill., 439–449.
Cokca, E., and Yilmaz, Z. (2004). “Use of rubber and bentonite added fly ash as a liner material.” Waste Manage., 24(2), 153–164.
Damidot, D., and Glasser, F. P. (1993). “Thermodynamic investigation of the CaOAl2O3CaSO4K2OH2O system at 25°C and the influence of Na2O .” Cem. Concr. Res., 23, 221–238.
Daniel, D. E. (1993). “Clay liners.” Geotechnical practice for waste disposal, D. E. Daniel, ed., Chapman & Hall, London, 137–163.
Daniel, D. E., Anderson, D. C., and Boynton, S. S. (1985). “Fixed-wall versus flexible-wall permeameters.” Hydraulic barriers in soil and rock: ASTM STP874, A. I. Johnson, R. K. Frobel, N. J. Cavalli, and C. B. Pettersson, eds., ASTM, West Conshohocken, Pa., 107–126.
Edil, T. B., Sandstrom, L. K., and Berthouex, P. M. (1992). “Interaction of inorganic leachate with compacted pozzolanic fly ash.” J. Geotech. Eng., 118(9), 1410–1430.
Fernandez, F., and Quigley, R. M. (1985). “Hydraulic conductivity of natural clays permeated with simple liquid hydrocarbons.” Can. Geotech. J., 22(2), 205–214.
Gustavsson, J. P. (2006). “Visual MINTEQ version 2.50: Department of Land and Water Resources Engineering.” Royal Institute of Technology, Stockholm, Sweden, ⟨http://www.lwr.kth.se/English/OurSoftware/vminteq/index.htm⟩ (Jan. 1, 2009).
Hunter, R. J. (1993). Introduction to modern colloid science, Oxford University Press, New York.
Kashir, M., and Yanful, E. K. (2001). “Hydraulic conductivity of bentonite permeated with acid mine drainage.” Can. Geotech. J., 38, 1034–1048.
Ministry of the Environment (MOE). (2000). “Ontario Regulation 558/00 (Environmental Protection Act—Schedule 4)—Leachate Quality Criteria.” Ministry of the Environment, Toronto, Ontario, Canada.
Mitchell, J. K. (1993). Fundamentals of soil behaviour, Wiley, New York.
Mitchell, J. K., and Madsen, F. T. (1987). “Chemical effects on clay hydraulic conductivity.” Geotechnical practice for waste disposal ‘87, R. D. Woods, ed., ASCE, New York, 87–116.
Myneni, S. C. B., Traina, S. J., and Logan, T. J. (1998). “Ettringite solubility and geochemistry of the Ca(OH)2Al2(SO4)3H2O system at 1 atm pressure and 298 K.” Chem. Geol., 148, 1–19.
Nhan, C. T., Graydon, J. W., and Kirk, D. W. (1996). “Utilizing coal fly ash as a landfill barrier material.” Waste Manage., 16, 587–595.
Usmen, M. A., Bowders, J. J., and Gidley, J. S. (1988). “Low permeability liners incorporating fly ash.” Disposal and utilization of electric utility wastes, M. A. Usmen, ed., ASCE National Convention, ASCE, New York, 50–65.
Yeheyis, M. B., Shang, J. Q., and Yanful, E. K. (2008). “Characterization and environmental evaluation of Atikokan coal fly ash for environmental applications.” J. Environ. Eng. Sci., 7(5), 481–498.

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Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 136Issue 7July 2010
Pages: 682 - 690

History

Received: Jan 16, 2009
Accepted: Aug 27, 2009
Published online: Dec 18, 2009
Published in print: Jul 2010

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Authors

Affiliations

Muluken B. Yeheyis [email protected]
Research Assistant, Dept. of Civil and Environmental Engineering, Univ. of Western Ontario, London, ON, Canada N6A 5B9 (corresponding author). E-mail: [email protected]
Julie Q. Shang [email protected]
Professor, Dept. of Civil and Environmental Engineering, Univ. of Western Ontario, London, ON, Canada N6A 5B9. E-mail: [email protected]
Ernest K. Yanful, M.ASCE [email protected]
Professor, Dept. of Civil and Environmental Engineering, Univ. of Western Ontario, London, ON, Canada N6A 5B9. E-mail: [email protected]

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