TECHNICAL PAPERS
Aug 14, 2009

Statistical Analysis of BTEX Surface Soil Regulatory Guidance Values

Publication: Journal of Environmental Engineering
Volume 135, Issue 9

Abstract

Residential surface soil regulatory guidance values (RGVs) specify the threshold at which soil contamination requires action. Usually, these are risk-based values based on child ingestion, inhalation, and dermal exposure. Benzene, toluene, ethylbenzene, and xylenes (BTEX) are among the five most commonly regulated soil contaminants in the United States and worldwide. More than 100 regulatory jurisdictions have established surface soil RGVs for BTEX compounds. Analysis of these values indicates that they vary by several orders of magnitude and appear to fit a lognormal random variable model with values well dispersed across the number spans. The RGVs applied to benzene are statistically distinct from those applied to TEX contamination, but the TEX values appear to be statistically indistinguishable. The magnitude of difference between TEX RGVs of different jurisdictions appears to be more significant than differences in the T, E, and X values specified by any one jurisdiction. Although value distributions are dominated by randomness, some contain clusters of points that are unlikely to be random and may represent consensus on appropriate values. Where “consensus clusters” exist, they should be identified and explored. The mechanistic explanations for cluster values may yield methods of reducing RGV variability.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

This research was conducted with the support of National Science Foundation Grant Nos. NSFCMS 99-01108 and NSFCBET-0650675. The writer also acknowledges the contributions of Dr. Jun Ma, Mr. Elijah Petersen, and Ms. Amy Hanna in helping to identify, acquire, and analyze soil guidance values.

References

Agency for Toxic Substances and Disease Registry (ASTDR). (2001). “Toluene CAS # 108-88-3.” U.S. Dept. of Health and Human Services Public Health Service, ⟨http://www.atsdr.cdc.gov/tfacts56.pdf⟩ (Dec. 18, 2007).
Agency for Toxic Substances and Disease Registry (ASTDR). (2007a). “Benzene CAS # 71-43-2.” U.S. Dept. of Health and Human Services Public Health Service, ⟨http://www.atsdr.cdc.gov/tfacts3.pdf⟩ (Dec. 18, 2007).
Agency for Toxic Substances and Disease Registry (ASTDR). (2007b). “Ethylbenzene CAS # 100-41-4.” U.S. Dept. of Health and Human Services Public Health Service, ⟨http://www.atsdr.cdc.gov/tfacts110.pdf⟩ (Dec. 18, 2007).
Agency for Toxic Substances and Disease Registry (ASTDR). (2007c). “Xylene CAS # 1330-20-7.” U.S. Dept. of Health and Human Services Public Health Service, ⟨http://www.atsdr.cdc.gov/tfacts71.pdf⟩ (Dec. 18, 2007).
Alaska Dept. of Environmental Conservation (ADEC). (2004). Oil and other hazardous substances pollution control, ⟨http://www.mxak.org/regulations/nintank/nontankfinal/75mas.pdf⟩ (Jan. 1, 2008).
Association of Environmental Health and Science (AEHS). (2002). “State summary of cleanup standards.” ⟨http://www.aehs.com/surveys.htm⟩ (Dec. 28, 2007).
Association of Environmental Health and Science (AEHS). (2003). “State summary of cleanup standards.” ⟨http://www.aehs.com/surveys.htm⟩ (Dec. 28, 2007).
Atlantic Partnership in RBCA Implementation (APRI). (2003). “Atlantic RBCA (risk-based corrective action), version 2.0 for petroleum impacted sites in Atlantic Canada.” ⟨http://www.atlanticrbca.com/data_eng/arbca_user_guide_v2_update_03-07_full.pdf⟩ (Sept. 26, 2007).
Bartsch, C., and Dorfman, B. (2000a). “Brownfields, VCPs and housing: State-of-the-art information and data.” ⟨http://nemw.org/NAHBresults.pdf⟩ (Jan. 2, 2008).
Bartsch, C., and Dorfman, B. (2000b). “Brownfields, VCPs and housing: How are state VCPs encouraging residential development?” ⟨http://nemw.org/NAHBresults.pdf⟩ (Jan. 2, 2008).
California Leaking Underground Fuel Tank Task Force (CLUFT). (1989). “Leaking underground fuel tank field manual: Guidelines for site assessment, cleanup, and underground storage tank closure.” ⟨http://www.waterboards.ca.gov/general/publications/index.html⟩ (Jan. 2, 2008).
Canadian Council of Ministers of the Environment (CCME). (1999). “Canadian environmental quality guidelines.” Winnipeg, Canada.
Canadian Council of Ministers of the Environment (CCME). (2007) “Canadian soil quality guidelines for the protection of environmental and human health.” ⟨http://www.ccme.ca/assets/pdf/rev_soil_summary_tbl_7.0_e.pdf⟩ (Nov. 30, 2007).
Carlon, C., ed. (2007). “Derivation methods of soil screening values in Europe: A review and evaluation of national procedures towards harmonization.” Rep. No. EUR 22805, European Commission, Joint Research Centre, Ispra, Italy.
Colorado Dept. of Labor and Employment (CDLE). (2005). “Petroleum storage tank owner/operator guidance document.” ⟨http://ops.cdle.state.co.us/OIL/StatuesRegulations/Current%20Regs%20J03an%2029%2007⟩ (Jan. 2, 2008).
Contaminated Sites Management Working Group (CSMWG). (2007). “Compilation and review of Canadian remediation guidelines, standards and regulations.” ⟨http://www.ec.gc.ca/etad/csmwg/pub_rev/en/chap3_e.htm⟩ (Dec. 18, 2007).
Delaware Dept. of Natural Resources and Environmental Control (DNREC). (2000). “Delaware risk-based corrective action program (DERBCAP) guide for underground storage tank (UST) sites.” ⟨http://www.dnrec.state.de.us/dnrec2000/divisions/awm/ust/Download/pdf/DERBCAP.pdf⟩ (Jan. 3, 2008).
Environment Agency, United Kingdom (EA). (2005). “Soil guideline values for ethylbenzene contamination” Dept. for Environment, Food and Rural Affairs, Science Rep. SGV16, ⟨http://www.environment-agency.gov.uk/commondata/acrobat/sgv16_932499.pdf⟩ (Sept. 21, 2007).
Florida Dept. of Environmental Protection (FDEP). (2006). “Alternative SCTL calculation spreadsheet.” ⟨http://www.dep.state.fl.us/waste/categories/pcp/pates/pg_documents.htm⟩ (Jan. 2, 2008).
General Accounting Office (GAO). (1996). “Superfund: How states establish and apply environmental standards when cleaning up sites.” GAO/RCED-96-70FS, General Accounting Office, Washington D.C., March 1996.
Government of the District of Columbia (DC). (2007). “District of Columbia remedial action strategy statement of basis.” ⟨http://www.epa.gov/reg3wcmd/pdf/DC_Remedial_Plan%20_response_to_EPA_Statement_of_Basis%20Final_Septemger2007.pdf⟩ (Jan. 3, 2008).
Interstate Technology Regulatory Council (ITRC). (2005). “Examination of risk-based screening values and approaches of selected states.” ITRC White Paper, Interstate Technology & Regulatory Council, Washington, D.C.
Iowa Dept. of Natural Resources (IDNR). (1996). “Tier 1 guidance, site assessment of leaking underground storage tanks (LUST) using risk-based corrective action (RBCA), version 1.0.” ⟨http://www.iowadnr.com/land/ust/technicalresources/lustsiteassessment/documents/tier1guide.pdf⟩ (Jan. 3, 2008).
Jennings, A. A. (2005). “The need to rationalize North American regulatory guidance for soil contamination.” J. Resid. Sci. & Tech., 2(4), 195–201.
Jennings, A. A. (2008). “Analysis of worldwide regulatory guidance for surface soil contamination.” J. Environ. Eng. & Sci., 7(6), 597–615.
Jennings, A. A., Cox, A. N., Hise, S. J., and Petersen, E. J. (2002). “Heavy metal contamination in the brownfield soils of Cleveland.” Soil Sediment Contam., 11(5), 719–750.
Jennings, A. A., and Hanna, A. (2007). “Dataabase analysis of state surface soil regulatory guidance values.” 23rd Annual Int. Conf. on Soils, Sediments and Water, Univ. of Massachusetts, Amherst.
Jennings, A. A., and Ma, J. (2007). “Variability in North American regulatory guidance for heavy metal surface soil contamination at commercial and industrial sites.” J. Environ. Eng. Sci., 6(5), 587–609.
Jennings, A. A., and Petersen, E. J. (2006). “Variability of North American regulatory guidance for heavy metal contamination of residential soil.” J. Environ. Eng. Sci., 5(6), 485–508.
Kentucky Div. of Waste Management (KDWM). (2006). “410 KAR 42:080 Classification outline, UST.” ⟨http://www.waste.ky.gov/NR/rdonlyres/CD37FAFD-5006-4495-B82B-4F45FAA2280E/O/Classification_Outline_42_080_10506.pdf⟩ (Jan. 2, 2008).
McBean, E. A., and Rovers, F. S. (1998). Statistical procedures for analysis of environmental monitoring data and risk assessment, Prentice- Hall, Upper Saddle River, N.J.
Miller, R. N., Haas, P., Faile, M., and Taffinder, S. (2001). “Risk-based approach to petroleum hydrocarbon remediation.” ⟨http://www.afcee.brooks.af.mil/products/techtrans/download/Nafo7.pdf⟩ (Dec. 20, 2007).
Missouri Dept. of Natural Resources (MDNR). (2006). “Missouri risk-based corrective action (MRBCA).” ⟨http://www.dnr.mo.gov/env/hwp/mrbca/mrbca.htm⟩ (Jan. 2, 2008).
Montana Dept. of Environmental Quality (MDEQ). (2007). “Tier 1 surface soil (0–2 ft) RSBL table.” ⟨http://www.deq.mt.gov/LUST/rbsls/dnldrbsls.asp⟩ (Jan. 2, 2008).
New Mexico Environmental Dept. (NMED). (2000). “Risk-based screening levels for residential scenario (lowest of the target levels for child and adult).” ⟨http://www.nmenv.dtate.nm.us/ust/lustrem.html⟩ (Jan. 3, 2008).
NIST. (2005a). “Benzene.” ⟨http://webbook.nist.gov/cgi/cbook.cgi?ID=71-43-2&Units=SI⟩ (Dec. 18, 2007).
NIST. (2005b). “Toluene.” ⟨http://webbook.nist.gov/cgi/cbook.cgi?ID=108-88-3&Units=SI⟩ (Dec. 18, 2007).
NIST. (2005c). “Ethylbenzene.” ⟨http://webbook.nist.gov/cgi/cbook.cgi?ID=100-41-4&Units=SI⟩ (Dec. 18, 2007).
NIST. (2005d). “Dimethylbenzene.” ⟨http://webbook.nist.gov/cgi/cbook.cgi?ID=1330-20-7&Units=SI⟩ (Dec. 18, 2007).
NIST. (2005e). “Benzene, 1,2-dimethyl-.” ⟨http://webbook.nist.gov/cgi/cbook.cgi?ID=95-47-6&Units=SI⟩ (Jan. 17, 2008).
NIST. (2005f). “Benzene, 1,4-dimethyl-.” ⟨http://webbook.nist.gov/cgi/cbook.cgi?ID=108-38-3&Units=SI⟩ (Jan. 17, 2008).
NIST. (2005g). “p-Xylene.” ⟨http://webbook.nist.gov/cgi/cbook.cgi?ID=106-42-3&Units=SI⟩ (Dec. 18, 2007).
North Carolina Dept. of Environment and Natural Resources (NCDENR). (2001). “Guidelines for assessment and corrective action, North Carolina underground storage tank section.” ⟨http://www.wastenotnc.org/ust/docs/2001Guidelines.pdf⟩ (Jan. 2, 2008).
Ohio Dept. of Commerce (ODC). (2005). “Bureau of underground storage tank regulations, technical guidance manual for closure, corrective action and petroleum contaminated soil rules.” ⟨https://www.com.state.oh.us/sfm/bustr/PDFs/bust_tgm.pdf⟩ (Jan. 2, 2008).
Ohio Environmental Protection Agency (OEPA). (2002). “Support document for the development of generic numerical standards and risk assessment procedures.” ⟨http://www.epa.state.oh.us/derr/pdf_doc_wpd/fvapspportDoc.pdf⟩ (Dec. 20, 2004).
Oklahoma Corporation Commission (OCC). (2002). “Guardian guidance for the assessment and cleanup of complex crude oil, condensate, and other hydrocarbon release sites, including historically impacted sites.” ⟨http://www.occeweb.com/Divisions/OG/ogtaxapp/og-garidan/abatement.htm⟩ (Jan. 2, 2008).
Oregon Dept. of Human Services (ODHS). (1994). “Health effects information, BTEX.” ⟨http://www.orgon.gov/DHS/ph/dwp/docs/fact/btex.pdf⟩ (Dec. 18, 2007).
Petersen, E. J. (2003). “Legacy heavy-metal contamination in Cleveland area public commons.” MS thesis, Case Western Reserve Univ., Cleveland, Ohio.
Petersen, E. J., Jennings, A. A., and Ma, J. (2006). “Screening level risk assessment of heavy metal contamination in Cleveland area commons.” J. Environ. Eng., 132(3), 392–404.
Pollution Control Dept., Thailand (PCD). (2004). “Soil quality standards.” ⟨http://www.pcd.go.th/info_serv/en_reg_std_soil01.html⟩ (Dec. 27, 2007).
Proctor, D. M., Shay, E. C., and Scott, P. K. (1997). “Health-based soil action levels for trivalent and hexavalent chromium: A comparison with state and federal standards.” J. Soil Contaminant, 6(6), 595–648.
Provoost, J., Cornelis, C., and Swartjes, F. (2006). “Comparison of soil clean-up standards for trace elements between countries: Why do they differ?” J. Soils and Sed., 6(3), 173–181.
Schäfer, K. W. (1997). “International experience and expertise in registration investigation, assessment, and clean-up of contaminated military sites, R&D Project 103 40 102/01.” Dames & Moore GmbH & Co. KG, Berlin, ⟨http://www.umweltbundesamt.de/boden-und-altlasten/altlast/web1/berichte/mooreeng/dmeng08.htm⟩ (Sept. 27, 2007).
Tennessee Dept. of Conservation (TDEC). (2007). “See Ref. 3: Risk-based clean-up levels, Tennessee Division of Underground Storage Tanks.” ⟨http://www.state.tn.us/environment/ust/guidance/index.shtml⟩ (Jan. 3, 2008).
U.S. Environmental Protection Agency (USEPA). (1989). “Risk assessment guidance for superfund, Vol. I: Human health evaluation manual (Part A)—Interim final.” Rep. No. EPA/540/1–89/002, U.S. Environmental Protection Agency, Washington, D.C.
U.S. Environmental Protection Agency (USEPA). (2001). “40 CFR Part 745. Lead: Identification of dangerous levels of lead (final rule).” Fed. Regist., 4(66), 1206–1240.
U.S. EPA Region III (USEPAIII). (2004). “Human health risk assessment, risk-based concentration table.” ⟨http://www.epa.gov/reg3hwmd/risk/human/rbc/rbc1004.pdf⟩ (Dec. 15, 2004).
U.S. EPA Region IX (USEPAIX). (2004). “Region 9 PRG Table.” ⟨http://www.epa.gov/region09/waste/sfund/prg/files/04prgtable.pdf⟩ (Dec. 22, 2004).
U.S. EPA Region VI (USEPAVI). (2004). “Region 6 human health medium specific screening levels (2004-2005).” ⟨http://www.epa.gov/earth1r6/6pd/rcra_c/pd-n/screenvalues.pdf⟩ (Dec. 21, 2004).

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 135Issue 9September 2009
Pages: 723 - 736

History

Received: Feb 5, 2008
Accepted: Dec 18, 2008
Published online: Aug 14, 2009
Published in print: Sep 2009

Permissions

Request permissions for this article.

Authors

Affiliations

Aaron A. Jennings, Ph.D., M.ASCE [email protected]
P.E.
Professor, Civil Engineering, Dept. of Civil Engineering, Case Western Reserve Univ., 10900 Euclid Ave., Cleveland, OH 44106. E-mail: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share