TECHNICAL PAPERS
Mar 15, 2010

Practical Method to Extract and Dechlorinate PCBs in Soils

Publication: Practice Periodical of Hazardous, Toxic, and Radioactive Waste Management
Volume 14, Issue 2

Abstract

In this paper some of the practical issues involved in the development and application of an extraction-photodegradation remediation technology for polychlorinated biphenyl (PCB) impacted weathered soils are addressed. The extraction of PCBs from weathered soils was investigated using the conventional Soxhlet extraction and by shake extraction using different solvents. The shake extraction has the potential for up-scaling to a field technology. The photodegradation of the extracted PCBs was investigated under direct ultraviolet light at 254 nm wavelength as well as under photosensitized light at 350 nm. The production of biphenyl, a by-product of the dechlorination of PCBs was investigated and it was found to degrade in the same ultraviolet system.

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Acknowledgments

The writers thank TransCanada Pipelines and NSERC for their financial support and additionally TransCanada for supplying the soil samples.NSERC

References

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Go to Practice Periodical of Hazardous, Toxic, and Radioactive Waste Management
Practice Periodical of Hazardous, Toxic, and Radioactive Waste Management
Volume 14Issue 2April 2010
Pages: 98 - 103

History

Received: Jul 27, 2007
Accepted: Oct 2, 2009
Published online: Mar 15, 2010
Published in print: Apr 2010

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Authors

Affiliations

Gopal Achari
Professor, Dept. of Civil Engineering, Univ. of Calgary, Calgary, Alberta, Canada T2N 1N4 (corresponding author).
Aarti Jakher
Postdoctoral fellow, Dept. of Chemical and Petroleum Engineering, Univ. of Calgary, Calgary, Alberta, Canada T2N 1N4.
Chetna Gupta
Laboratory Technologist, Dept. of Chemical and Petroleum Engineering, Univ. of Calgary, Calgary, Alberta, Canada T2N 1N4.
Arvinder Dhol
Former Graduate Student, Dept. of Civil Engineering, Univ. of Calgary, Calgary, Alberta, Canada T2N 1N4.
Cooper H. Langford
Faculty Professor, Dept. of Chemistry, Univ. of Calgary, Calgary, Alberta, Canada T2N 1N4.

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