TECHNICAL PAPERS
Apr 1, 2002

Multimedia Environmental Models

Publication: Practice Periodical of Hazardous, Toxic, and Radioactive Waste Management
Volume 6, Issue 2

Abstract

In this introductory paper it is suggested that multimedia mass balance models can play a valuable role in improving our understanding of the behavior of chemicals in the environment. They can provide a rational basis for chemical management by linking emission rates to prevailing environmental concentrations and identifying such issues of concern as tendency to bioaccumulate, persistence for excessive times, and the potential to undertake intermedia transport. Four principles are outlined: the need for iterative modeling starting with simple models and progressing toward more complexity with fidelity to real conditions; the value of evaluative models as a means of focusing attention on how the chemicals’ properties translate into fate; the need for more validation of these models by comparing observations with simulations; and finally, the value of the fugacity concept as a means of expressing multimedia partitioning, transport, and transformation more simply. These principles are demonstrated by a case study in which a variety of models is applied to assess the fate and transport of hexachlorobenzene in evaluative, regional, and aquatic environments. This example demonstrates that multimedia models can provide a comprehensive, quantitative picture of how specific chemicals behave in the environment, thus contributing to conditions engineered such that the beneficial uses of chemicals can be enjoyed sustainably and without risk of adverse effects on humans or the ecosystem.

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References

Colborn, T., Dumanoski, D., and Meyers, J. P. (1996). Our stolen future, McClelland & Stewart, New York.
Mackay, D., Shiu, W. Y., and Ma, K. C. (2000). Physical chemical properties and environmental fate and degradation handbook, CRCnetBASE 2000, Chapman & Hall CRCnetBASE, CRC Press LLC, Boca Raton, Fla.
Mackay, D.(1979). “Finding fugacity feasible.” Environ. Sci. Technol., 13, 1218.
Mackay, D. (2001). Multimedia Environmental Models: The fugacity approach, 2nd Ed., CRC, Boca Raton, Fla.
Mackay, D., Paterson, S., DiGuardo, A., and Cowan, C. E.(1996). “Evaluating the environmental fate of a variety of types of chemicals using the EQC model.” Environ. Toxicol. Chem.,15(9), 1627–1637.
MacLeod, M., and Mackay, D.(1999). “An assessment of the environmental fate and exposure of benzene and the chlorobenzenes in Canada.” Chemosphere, 38, 1777–1796.
Mackay, D., Sang, S., Vlahos, P., Diamond, M., Gobas, F., and Dolan, D.(1994). “A rate constant model of chemical dynamics in a lake ecosystem: PCBs in Lake Ontario.” J. Great Lakes Res., 20(4), 625–642.
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Go to Practice Periodical of Hazardous, Toxic, and Radioactive Waste Management
Practice Periodical of Hazardous, Toxic, and Radioactive Waste Management
Volume 6Issue 2April 2002
Pages: 63 - 69

History

Received: Dec 28, 2001
Accepted: Dec 28, 2001
Published online: Apr 1, 2002
Published in print: Apr 2002

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Authors

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Donald Mackay
Canadian Environmental Modelling Centre, Trent Univ., Peterborough, Ontario, Canada K9J 7B8.
Matthew MacLeod
Canadian Environmental Modelling Centre, Trent Univ., Peterborough, Ontario, Canada K9J 7B8.

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