Removal of Lithium Antimonide from Radioactive Glove Box
Authors: L. Leibowitz, S. M. McDeavitt, D. G. Graczyk, and F. P. SmithAuthor Affiliations
Publication: Practice Periodical of Hazardous, Toxic, and Radioactive Waste Management
Volume 4, Issue 4
Abstract
A sample of lithium antimonide (Li3Sb) was prepared in a radioactive helium-atmosphere glove box, some of which spread throughout the box. Because of the potential for stibine generation should the Li3Sb contact water, some effort was devoted to assessing the extent of possible stibine formation and methods for removing the Li3Sb from the box. This note summarizes our findings and the waste disposal procedures used.
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References
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Holland, R. ( 1962). “The determination of stibine.” Analyst, 87, 385.
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Lewis, R. J. ( 1996). Sax's dangerous properties of industrial materials, 9th Ed., Van Nostrand Reinhold, New York, 3016.
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Melor, J. W. ( 1964). A comprehensive treatise on inorganic and theoretical chemistry, Vol. IX, Wiley, New York, 401.
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History
Received: Jun 8, 2000
Published online: Oct 1, 2000
Published in print: Oct 2000
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Authors
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L. Leibowitz
S. M. McDeavitt
D. G. Graczyk
F. P. Smith
Sr. Chemist, Chem. Technol. Div., Argonne Nat. Lab., 9700 S. Cass Ave., Argonne, IL 60439. E-mail: [email protected]
Nuclear Engr., Chem. Technol. Div., Argonne Nat. Lab., 9700 S. Cass Ave., Argonne, IL.
Group Leader, Anal. Chem. Lab., Chem. Technol. Div., Argonne Nat. Lab., 9700 S. Cass Ave., Argonne, IL.
Chemist, Anal. Chem. Lab., Chem. Technol. Div., Argonne Nat. Lab., 9700 S. Cass Ave., Argonne, IL.
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