TECHNICAL PAPERS
Mar 1, 2008

Influence of Composition of uPVC on Mechanical Properties of Window Profiles Exposed to Weathering

Publication: Journal of Materials in Civil Engineering
Volume 20, Issue 3

Abstract

The durability of unplasticized poly(vinyl chloride) (uPVC) components used in the building industry is a function of the interaction of several factors. Types and quantities of additives incorporated to the PVC resin and defining the formulation of the PVC compound used in the production of these components are among the most important such factors. White uPVC window profiles with different formulations have been exposed to five years of natural weathering under Brazilian climatic conditions. Results of Charpy impact tests were used to assess the influence of three factors on the durability of the profiles: additivation levels of titanium dioxide, nature of the impact modifier, and nature of the thermal stabilizer. Statistical analysis of the results made it possible to rank these factors according to their influence in component durability. The influence of composition of uPVC on mechanical properties of window profiles is demonstrated by means of the study of the modulus of elasticity. Results presented in this paper indicated the need for several additional experiments in order to check changes in molecular mass and color. Comparison of all these data with results from profiles subjected to accelerated weathering led to straightforward criteria for prediction of the potential behavior of uPVC, to be described in a future paper.

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Acknowledgments

The writers wish to thank the help received from Braskem S/A, Instituto de Pesquisas Tecnologicas de Sao Paulo, and TESIS—Tecnologia de Sistemas em Engenharia.

References

ASTM. (1984). “Standard test methods for determining the pendulum impact resistance of notched specimens of plastic.” ASTM D256, Philadelphia.
ASTM. (1992). “Standard test methods for flexural properties of unreinforced and reinforced plastics and electrical insulating materials—Method I.” ASTM D790, Philadelphia.
ASTM. (1994). “Standard practice for outdoor weathering of plastics.” ASTM D1435, Philadelphia.
British Standard Institution (BSI). (1994). “Specification for white PVC-U extruded hollow profiles with heat welded corner joints for plastic windows: Materials type A.” BS 7413, London.
Hachich, V. C. F. (1999). “Minimum criteria for evaluation of rigid poly (vinyl chloride) (PVC) products for exterior use in buildings.” Ph.D. thesis, Polytechnic School, Univ. of São Paulo, São Paulo, Brazil.
Lee, C. H., Shim, D. S., and Kim, S. W. (1995). “Effect of pigment on weatherability of PVC.” Kongop Hwahak, 6(1), 22–8.
Lemaire, J. (1996). “Predicting polymer durability.” CHEMTECH, 26(10), 42–47.
Rabinovitch, E. B. (1993). “Use of titanium dioxide in vinyl building products.” European Polymers Paint Color Journal, 183(4339), 521–524.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 20Issue 3March 2008
Pages: 199 - 204

History

Received: Jun 29, 2004
Accepted: Mar 26, 2007
Published online: Mar 1, 2008
Published in print: Mar 2008

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Notes

Note. Associate Editor: Carl Liu

Authors

Affiliations

Vera Fernandes-Hachich, Ph.D.
Technical Manager, TESIS—Tecnologia de Sistemas em Engenharia Ltda., Av. Queirós Filho, 87, 05319-000 São Paulo, SP, Brazil. E-mail: [email protected]
Vahan Agopyan, Ph.D.
President, Institute for Technologycal Research of São Paulo—IPT. E-mail: [email protected]

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