TECHNICAL PAPERS
Jan 1, 2007

Micropore Structure of Aggregates in Treated Soils

Publication: Journal of Materials in Civil Engineering
Volume 19, Issue 1

Abstract

For the purpose of understanding the influence of stabilizing agents on the internal structure of aggregates in treated soils, seven soil samples were prepared for tests according to type and quantity of stabilization agents, as well as sampling location. In nitrogen adsorption and desorption tests, HK and BJH methods are, respectively, adopted to analyze the diameter distributions of micropores and mesopores within aggregates in samples with diverse treatment. The results indicate that: (1) micropores with the diameter of approximately 8.4Å in aggregates are prominent in both untreated and treated expansive soil samples; (2) mesopores with the diameter of greater than 30Å are mainly distributed in four ranges of 30–40, 70–75, 90–95, and 450500Å , and the stabilization agent has significant effect on the structure of mesopores with the diameter of greater than 200Å ; and (3) both lime and cement are able to decrease the volumes of micropores while increasing those of mesopores and macropores in expansive soils. The scanning electron microscope images of the samples were presented to interpret the difference in micropore structure between lime-treated soils and cement-treated soils and further validate the results from adsorption tests. In addition, energy-dispersive X-ray spectrometer (EDX) analysis was employed to determine the composition of some points on the individual aggregate and migration of calcium ions in the aggregates in lime treated soils. Through the EDX analysis, it is shown that lime usually concentrates in pores or on the surface of aggregates and has few effects on the inner of aggregates with size ranging from 5to10mm .

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Acknowledgments

This work was financially supported by Natural Science Foundation of China (Grant No. NSFC40172089) and also funded by National Science Fund for Distinguished Young Scholars (Grant No. UNSPECIFIED40225006). Their support is gratefully acknowledged.

References

Barret, E. P., Joyner, L. G., and Hallenda, P. P. (1951). “The determination of pore volume and area distributions in porous substances. Computations from nitrogen isotherms.” J. Am. Chem. Soc., 73, 373–380.
Brunauer, S., Emmett, P. H., and Teller, E. (1938). “Adsorption of gas in multimolecular layers.” J. Am. Chem. Soc., 60, 309–319.
Carrott, P. J. M., Roberts, R. A., and Sing, K. S. (1987). “Adsorption of nitrogen by porous and non-porous carbons.” Carbon, 25(1), 59–68.
Hillel, D. (1998). “Soil structure and aggregation.” Environmental soil physics, Academic, San Diego, 106–108.
Horn, R., Baumgartl, T., Kayser, R., and Baasch, S. (1995). “Effect of aggregate strength on strength and stress distribution in structured soils.” Soil structure—Its development and function, K. H. Hartge and B. A. Stewart, eds., Lewis, Boca Raton, Fla., 31–52.
Horvath, G., and Kawazoe, K. (1983). “Method for the calculation of effective pore size distribution in molecular sieve carbon.” J. Chem. Eng. Jpn., 16(6), 470–475.
Juszczak, L., Fortuna, T., and Wodnicka, K. (2002). “Characteristics of cereal starch granules surface using nitrogen adsorption.” J. Food. Eng., 54, 103–110.
Langmuir, I. (1918). “The adsorption of gas on plane surfaces of glass, mica and platinum.” J. Am. Chem. Soc., 40, 1361–1403.
Lei, X. Y. (1985). “Pore distribution characteristics of Longdong loess in Northern Shanxi of China.” Chin. Sci. Bull., Beijing, 30(3), 206–209.
Munkholm, L. J., Schjønning, P., and Kay, B. D. (2002). “Tensile strength of soil cores in relation to aggregate strength, soil fragmentation and pore characteristics.” Soil and Tillage Research, 64(1–2), 125–135.
Reddi, L. N., and Inyang, H. I. (2000). “Soil formation and composition.” Geoenvironmental engineering, Marcel Dekker, New York, 25–28.
Seaton, N. A., Walton, J. P. R. B., and Quirke, N. (1989). “A new analysis method for the determination of the pore size distribution of porous carbons from nitrogen adsorption measurements.” Carbon, 27, 853–861.
Shi, B., Murakami, Y., and Wu, Z. S. (1998). “Orientation of aggregates of fine-grained soil: Quantification and application.” Eng. Geol. (Amsterdam), 50(1–2), 59–70.
Sing, K. S. W., Everett, D. H., Haul, R. A., Mosou, L., Pierotti, R. A., Rouquerol, J., and Siemieniewska, T. (1985). “Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity.” Pure Appl. Chem., 57(4), 603–619.
Wang, M., Bai, X. H., Liang, R. W., and Chen, P. A. (2001). “Microstudy on soft foundations reinforcement with lime-fly ash piles.” Rock and Soil Mechanics, 22(1), 67–70.
Wang, Q., and Wang, J. P. (2000). “A study on fractal of porosity in the soils.” Chinese J. Geotech. Eng., 22(4), 496–498.
Zhang, L. X., and Wang, J. C. (2002). “Experimental study on frost heaving behaviors of lime soil.” Chinese J. Geotech. Eng., 24(3), 336–339.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 19Issue 1January 2007
Pages: 99 - 104

History

Received: Mar 21, 2005
Accepted: Jul 29, 2005
Published online: Jan 1, 2007
Published in print: Jan 2007

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Notes

Note. Associate Editor: Hilary I. Inyang

Authors

Affiliations

Professor, ACEI, Dept. of Earth Sciences, Nanjing Univ., Nanjing 210093, China (corresponding author). E-mail: [email protected]
Liu Zhibin
Graduate Student, ACEI, Dept. of Earth Sciences, Nanjing Univ., Nanjing 210093, China.
Cai Yi
Graduate Student, ACEI, Dept. of Earth Sciences, Nanjing Univ., Nanjing 210093, China.
Zhang Xiaoping
Associate Professor, Dept. of Civil Engineering, Nanjing Univ. of Aeronautics and Astronautics, Nanjing 210016, China.

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