Phase Separation of SBS Polymer Modified Bitumens
Publication: Journal of Materials in Civil Engineering
Volume 11, Issue 1
Abstract
Styrene-butadiene-styrene (SBS) polymer modified binders consist of two-phase (polymer-rich and asphaltene-rich) mixtures. This type of system is thermodynamically unstable, and a phase separation may occur under the influence of gravitational fields. In this study, the phase separation was determined by a hot storage test and characterized using the softening point, dynamic mechanical analysis (DMA), and Fourier transform infrared (FTIR) spectroscopy. Based on DMA and FTIR, influences of the type of base bitumen and the characteristics and concentrations of SBS polymers were studied. In addition, the rheological properties of the separate phases were investigated, and the mechanism of phase separation was discussed.
Get full access to this article
View all available purchase options and get full access to this article.
References
1.
Bahia, H. U., and Davies, R. ( 1994). “Effect of crumb rubber modifiers (CRM) on performance-related properties of asphalt binders.” J. Assoc. of Asphalt Paving Technologists, 63, 414–449.
2.
Bonemazzi, F., Braga, V., Corrieri, R., Giavarini, C., and Sartori, F. ( 1996). “Characteristics of polymers and polymer-modified binders.” Transp. Res. Rec. 1535, National Research Council, Washington, D.C., 36–47.
3.
Brûlé, B. ( 1996). “Polymer-modified asphalt cements used in the road construction industry: basic principles.” Transp. Res. Rec. 1535, National Research Council, Washington, D.C., 48–53.
4.
Bull, A. L., and Vonk, W. C. ( 1987). “Thermoplastic rubber/bitumen blends for roof and road.” Thermoplastic Rubbers Tech. Manual TR 8.15, Shell Elastomers, London.
5.
Collins, J. H., Bouldin, M. G., Gelles, R., and Berker, A. ( 1991). “Improved performance of paving asphalts by polymer modification.” J. Assoc. of Asphalt Paving Technologists, 60, 43–79.
6.
Isacsson, U., and Lu, X. ( 1995). “Testing and appraisal of polymer modified road bitumens—state of the art.” Mat. and Struct., Paris, 28, 139–159.
7.
Lu, X. ( 1996). “Fundamental studies on styrene-butadiene-styrene polymer modified road bitumens,” Licentiate thesis, Royal Institute of Technology, Stockholm.
8.
Lu, X., and Isacsson, U. ( 1997). “Rheological characterization of styrene-butadiene-styrene copolymer modified bitumens.” Constr. and Build. Mat., 11, 23–32.
9.
Muncy, H. W., King, G. N., and Prudhomme, J. B. ( 1987). “Improved rheological properties of polymer-modified asphalts.” Asphalt rheology: relationship to mixture. American Society for Testing and Materials, Philadelphia, 146–165.
10.
Petersen, J. C. ( 1984). “Chemical composition of asphalt as related to asphalt durability: state of the art.” Transp. Res. Rec. 999, National Research Council, Washington, D.C., 13–30.
11.
Sybilski, D. ( 1993). “Non-Newtonian viscosity of polymer-modified bitumens.” Mat. and Struct., Paris, 26, 15–23.
12.
Valkering, C. P., Vonk, W. C., and Whiteoak, C. D. ( 1992). “Improved asphalt properties using SBS modified modified bitumens.” Shell Bitumen Rev. 66, Shell Bitumen, Chertsey, U.K., 9–11.
13.
Whiteoak, D. ( 1991). The Shell Bitumen handbook. Shell Bitumen, Chertsey, U.K.
14.
Yen, T. F. ( 1990). “A macrostructure of petroleum asphalt.” Preprints of the Symp.: Chemistry and Characterization of Asphalts, Vol. 35, Div. of Petroleum Chemistry, American Chemistry Society, Washington, D.C., 314–319.
Information & Authors
Information
Published In
History
Published online: Feb 1, 1999
Published in print: Feb 1999
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.