Field-Scale Observations of Arsenic and Boron in Soil Irrigated with Drainwater
Publication: Journal of Irrigation and Drainage Engineering
Volume 126, Issue 3
Abstract
Addition of a strong acid to irrigation water could enhance sorption of boron and arsenic in a Lahontan Valley field. Approximately 90 soil samples, taken from a field irrigated with mildly brackish drainage water (TDS ≈ 1,250 mg L−1), were analyzed for soluble constituents. When the pH of the saturated soil paste was between 7.2 and 8.8, dissolved arsenic and boron concentrations increased, possibly indicating decreased sorption on oxyhydroxide precipitates of manganese and aluminum, and goethite, inferred from equilibrium aqueous speciation modeling. In the pH range of 7.2–8.8, linear regression models indicate a unit decrease in pH may result in a log[B] reduction of 1.18 and a log[total As] reduction of 1.58, when the concentrations are expressed in mg L−1. Geochemical modeling indicates that a reduction in pH in the observed range should not solubilize carbonates that could counteract acidity increase. Addition of HCl or H2SO4 to reduce soil water pH may be an effective way to minimize deep percolation of boron and arsenic.
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References
1.
Ayars, J. E., and Meek, D. W. (1994). “Drainage load-flow relationships in arid irrigated areas.” Trans. ASAE, 37(2), 431–437.
2.
Chambers, E. P., and Guitjens, J. C. (1995). “Shallow ground-water influence on salt budgets for Newlands Project.”J. Irrig. and Drain. Engrg., ASCE, 121(6), 436–441.
3.
Dollarhide, W. E. (1975). Soil survey of Fallon-Fernley area, Nevada, parts of Churchill, Lyon, Storey, and Washoe counties, U.S. Department of Agriculture, Washington, D.C.
4.
Goldberg, S., Forster, H. S., and Heick, E. L. (1993). “Boron adsorption mechanisms on oxides inferred from ionic strength effects.” Soil Sci. Soc. Am. J., 57, 704–708.
5.
Goldberg, S., and Glaubig, R. A. (1985). “Boron adsorption on aluminum and iron oxide minerals.” Soil Sci. Soc. Am. J., 49, 1374–1379.
6.
Gould, J. C. ( 1992). “Influence of irrigation on subsurface drainage.” MS thesis, University of Nevada, Reno, Nev.
7.
Guitjens, J. C. (1987). “Modeling of drainage for water quality evaluation.” Proc., 5th Nat. Drain. Symp., American Society of Agricultural Engineers, St. Joseph, Mich., 178–188.
8.
Guitjens, J. C. (1992). “Interpreting spatial yield variability of irrigated spring wheat.” Trans. ASAE, 35(1), 91–95.
9.
Hoffman, R. J., Hallock, R. J., Rowe, T. G., Lico, M. S., Burge, H. L., and Thompson, S. P. (1990). “Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in and near Stillwater Wildlife Management Area, Churchill County, Nevada, 1986–1987.” Water Resour. Investigations Rep. 89-4105, U.S. Geological Survey, Carson City, Nev.
10.
Lico, M. S., and Seiler, R. L. (1994). “Ground-water quality and geochemistry, Carson Desert, western Nevada.” Open-File Rep. 86-250, U.S. Geological Survey, Carson City, Nev.
11.
Livesey, N. T., and Huang, P. M. (1981). “Adsorption of arsenate by soils and its relation to selected chemical properties and anions.” Soil Sci., 131(2), 88–94.
12.
McGeehan, S. L., and Naylor, D. V. (1994). “Sorption and redox transformation of arsenite and arsenate in two flooded soils.” Soil Sci. Soc. Am. J., 58, 337–342.
13.
Neter, J., Wasserman, W., and Kutner, M. H. (1989). Applied linear regression models. 2nd Ed., Richard D. Irwin, Inc., Homewood, Ill.
14.
Papke, K. G. (1976). “Evaporites and brines in Nevada playas.” Nevada Bureau of Mines and Geol., Bulletin 87, Mackay School of Mines, University of Nevada, Reno, Nev.
15.
Plummer, L. N., Jones, B. F., and Truesdell, A. H. (1984). “WATEQF-a FORTRAN IV version of WATEQ, a computer program for calculating chemical equilibrium of natural waters.” Water-Resour. Investigations 76-13. U.S. Geological Survey, Reston, Va.
16.
Rhoades, J. D. ( 1982). “Soluble salts.” Methods of soil analysis. Part 2: Chemical and microbiological properties. A. Klute, ed., American Society of Agronomy–Soil Science Society of America, Wisc., 167–179.
17.
Welch, A. H., Lico, M. S., and Hughes, J. L. (1988). “Arsenic in ground water of the western United States.” Ground Water, 26(3), 333–347.
18.
Whitney, R. (1994). “Data on ground-water quality in the Carson River Basin, Western Nevada and Eastern California, 1987–90.” Open-File Rep. 94-39. U.S. Geological Survey, Carson City, Nev.
19.
Wolery, T. J. (1992). EQ3NR, a computer program for geochemical aqueous speciation-solubility calculations: theoretical manual, user's guide, and related documentation (version 7.0). Lawrence Livermore National Laboratory, Livermore, Calif.
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Received: Aug 5, 1996
Published online: May 1, 2000
Published in print: May 2000
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