SPECIAL SECTION: Pesticides
Jan 1, 1990

Aldicarb in Vadose Zone: Review

Publication: Journal of Irrigation and Drainage Engineering
Volume 116, Issue 1

Abstract

The literature was reviewed regarding the sorption and transport of a nonionic organic pesticide aldicarb, an extremely toxic and relatively water soluble carbamate insecticide that has been detected in ground water across the United States. Leaching of organic compounds poses a serious threat to ground water. Sorption is a critical factor in determining how rapidly a pesticide will leach through the vadose zone. Aldicarb behaves as a nonionic organic compound being adsorbed primarily by soil organic matter and to a lesser extent by clay minerals. The assumption of a local equilibrium between the soil particles and the pore fluid is not always correct. Aldicarb transport may be controlled by nonequilibrium effects. Certain agricultural management practices may reduce the threat of ground‐water contamination by aldicarb residues.

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References

1.
Bilkert, J. N., and Rao, P. S. C. (1985). “Sorption and leaching of three nonfu‐migant nematicides in soils.” J. Envir. Sci. Health, B20(l), 1–26.
2.
Bouwer, H. (1987). “Effect of irrigated agriculture on groundwater.” J. Irrig. and Drain. Eng., 113(1), 4–15.
3.
Cohen, S. Z., et al. (1984). “Potential for pesticide contamination of ground water resulting from agricultural uses.” Treatment and Disposal of Pesticide Wastes. R. F. Krueger and J. N. Seiber, eds., ACS Symposium Ser. 259. ACS, Washington, D.C., 297–325.
4.
Cohen, S. Z., Eiden, C., and Lorber, M. N. (1986). “Monitoring groundwater for pesticides.” Evaluation of Pesticides in Groundwater. W. Y. Garner, R. C. Honeycutt, and H. N. Nigg, eds., ACS Symposium Ser. 315. ACS, Washington, D.C., 170–196.
5.
de Marsily, G. (1986). Quantitative hydrogeology: Groundwater hydrology for engineers. Academic Press, Inc., Orlando, Fla.
6.
Donigian, A. S., Jr., and Rao, P. S. C. (1986). “Overview of terrestrial processes and modeling.” Vadose zone modeling of organic pollutants. S. C. Hern and S. M. Melancon, eds., Lewis Publishers Inc., Chelsea, Mich., 3–36.
7.
Felsot, A., and Dahm, P. A. (1979). “Sorption of organophosphorus and carbamate insecticides by soil.” J. Agric. Food Chem., 27(3), 557–563.
8.
Freeze, R. A., and Cherry, J. A. (1979). Groundwater. Prentice‐Hall Inc., Englewood Cliffs, N.J.
9.
Gerstl, Z., and Mingelgrin, U. (1979). “A note on the adsorption of organic molecules on clays.” Clays and Clay Minerals, 27(4), 285–290.
10.
Giddings, C. (1963). “Kinetic origin of tailing in chromatography.” Analytical Chem., 35(13), 1999–2002.
11.
Glass, R. J., and Steenhuis, T. S. (1984). “Factors influencing infiltration flow instability and movement of toxics in layered sandy soils.” ASAE Technical Paper No. 84‐2508, St. Joseph, Mich.
12.
Goltz, M. N., and Roberts, P. V. (1987). “Using the method of moments to analyze three‐dimensional diffusion‐limited solute transport from temporal and spatial perspectives.” Water Resour. Res., 23(8), 1575–1585.
13.
Guerrera, A. A. (1981). “Chemical contamination of aquifers on Long Island, New York.” J. AWWA, 190–199.
14.
Hamaker, J. W. (1975). “The interpretation of soil leaching experiments.” Environmental Dynamics of Pesticides, R. J. Hance, ed., Plenum Press, New York, N.Y., 115–133.
15.
Hornsby, A. G., et al. (1983). “Fate of aldicarb in Floridan citrus soils: 1. Field studies and laboratory studies.” Proc. of NWWA Characterization and Monitoring of the Vadose (Unsaturated) Zone Conf., December 8‐10, 1983, 936–958.
16.
Jones, R. L. (1986). “Field, laboratory, and modeling studies on the degradation and transport of aldicarb residues in soil and groundwater.” Evaluation of Pesticides in Groundwater. W. Y. Garner, R. C. Honeycutt, and H. N. Nigg, eds., ACS Symposium Ser. 315. ACS, Washington, D.C., 197–218.
17.
Jury, W. A. (1986). “Adsorption of organic chemicals onto soil.” Vadose zone modeling of organic pollutants. S. C. Hern and S. M. Melancon, eds., Lewis Publishers, Inc., Chelsea, Mich., 177–189.
18.
Jury, W. A., and Valentine, R. L. (1986). “Transport mechanisms and loss pathways for chemicals in soil.” Vadose zone modeling of organic pollutants. S. C. Hern and S. M. Melancon, eds. Lewis Publishers Inc., Chelsea, Mich., 37–60.
19.
Jury, W. A., et al. (1987). “Transport and transformations of organic chemicals in the soil‐air‐water ecosystem.” Rev. Envir. Contamination and Toxicology, Vol. 99, Springer‐Verlag Inc., New York, N.Y., 119–164.
20.
Karickhoff, S. W. (1981). “Semi‐empirical estimation of sorption of hydrophobic pollutants on natural sediments and soils.” Chemosphere, 10(8), 833–846.
21.
Karickhoff, S. W. (1984). “Organic pollutant sorption in aquatic systems.” J. of Hydr. Engrg., ASCE, 110(6), 707–735.
22.
Lemley, A. T., and Zhong, W. Z. (1984). “Hydrolysis of aldicarb, aldicarb sulfoxide, and aldicarb sulfone at parts per billion levels in aqueous mediums.” J. Agric. Food Chem., 32(4), 714–719.
23.
Lemley, A. T., et al. (1988). “Sorption and degradation of aldicarb and its oxidation products in a soil‐water flow system as a function of pH and temperature.” J. Environ. Qual., 17(3), 408–414.
24.
McCarty, P. L., Reinhard, M., and Rittmann, B. E. (1981). “Trace organics in groundwater.” Environ. Sci. Technol., 15(1), 40–49.
25.
Miles, C. J., and Delfino, J. J. (1985). “Fate of aldicarb, aldicarb sulfoxide, and aldicarb sulfone in Floridan groundwater.” J. Agric. Food Chem., 33(3), 455–460.
26.
Mingelgrin, U., and Gerstl, Z. (1983). “Reevaluation of partitioning as a mechanism of nonionic chemicals adsorption in soils.” J. Environ. Qual., 12(1), 1–11.
27.
Nielsen, D. R., van Genuchten, M. Th., and Biggar, J. W. (1986). “Water flow and solute transport processes in the unsaturated zone.” Water Resour. Res., 22(9), 89S‐108S.
28.
Rao, P. S. C., and Davidson, J. M. (1980). “Estimation of pesticide retention and transformation parameters required in nonpoint source pollution models.” Environmental Impact of Nonpoint Pollution. M. R. Overcash and J. M. Davidson, eds., Ann Arbor Sci. Publ. Inc., Ann Arbor, Mich., 23–67.
29.
Rao, P. S. C., and Jessup, R. E. (1983). “Sorption and movement of pesticides and other toxic organic substances in soils.” Chemical Mobility and Reactivity in Soil Systems. D. W. Nelson, D. E. Elrick, and K. K. Tanji, eds., Soil Sci. of America, Madison, Wis., 183–201.
30.
Rao, P. S. C., Nkedi‐Kizza, P., Davidson, J. M., and Ou, L. T. (1983). “Retention and transformation of pesticides in relation to nonpoint source pollution from croplands.” Agriculture management and water quality, F. W. Schaller and G. W. Bailey, eds., Iowa State Univ. Press, Ames, Iowa, 126–140.
31.
Roberts, P. V., et al. (1980). “Organic contaminant behavior during groundwater recharge.” J. Water Poll. Control Fed., 52(1), 161–172.
32.
Rothschild, E. R., Manser, R. J., and Anderson, M. P. (1982). “Investigation of aldicarb in ground water in selected areas of the central sand plain of Wisconsin.” Ground Water., 20(4), 437–445.
33.
Roy, W. R., and Griffin, R. A. (1985). “Mobility of organic solvents in water‐saturated soil materials.” Environ. Geol. Water Sci., 7(4), 241–247.
34.
Schwarzenbach, R. P., and Westall, J. (1985). “Sorption of hydrophobic trace organic compounds in groundwater systems.” Water Sci. Tech., 17, 39–55.
35.
Supak, J. R. (1972). “The volatilization, degradation, adsorption, and desorption characteristics of aldicarb [2‐methyl‐2‐(methylthio) propionaldehyde 0‐(methyl‐carbamoyl) oxime] in soils and clays.” Thesis presented to Texas A&M Univ., at College Station, Tex., in partial fulfillment of the requirements for the degree of Doctor of Philosophy.
36.
Union Carbide Agricultural Products Co. (1983). “Aldicarb: A perspective.” Union Carbide Agricultural Products Co. (1985). “The environment fate of TEMIK brand aldicarb pesticide.”
37.
Valocchi, A. J. (1985). “Validity of the local equilibrium assumption for modeling sorbing solute transport through homogeneous soils.” Water Resour. Res., 21(6), 808–820.
38.
Van Genuchten, M. Th., and Jury, W. A. (1987). “Progress in unsaturated flow and transport modeling.” Reviews of Geophysics, 25(2), 135–140.
39.
Van Genuchten, M. Th., and Wierenga, P. J. (1976). “Mass transfer studies in sorbing porous media, I. Analytical solutions.” Soil Sci. Soc. Am. J., 40(4), 473–480.
40.
Wagenet, R. J., and Rao, P. S. C. (1985). “Basic concepts of modeling pesticide fate in the crop root zone.” Weed Sci., 33(Suppl. 2), 25–32.
41.
Wartenberg, D. (1988). “Groundwater contamination by Temik aldicarb pesticide: The first 8 months.” Water Resour. Res., 24(2), 185–194.
42.
Water Quality Committee of the Irrigation and Drainage Division. (1985). “Report of task committee on water quality problems resulting from increasing irrigation efficiency.” J. of Irrigation and Drainage Engrg., 111(3), 191–198.
43.
Wyman, J. A., et al. (1985). “Effects of application procedures and irrigation on degradation and movement of aldicarb residues in soil.” Environ. Toxic. Chem., 4, 641–651.

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Published In

Go to Journal of Irrigation and Drainage Engineering
Journal of Irrigation and Drainage Engineering
Volume 116Issue 1January 1990
Pages: 36 - 49

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Published online: Jan 1, 1990
Published in print: Jan 1990

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J. A. Stover
Hydro., Resour. Suitability Branch, Denver Ofc., U.S. Bureau of Reclamation, P.O. Box 25007, Lakewood, CO 80225
J. C. Guitjens, Member, ASCE
Prof. of Irrig. Engrg., Range, Wildlife and Forestry Dept., Univ. of Nevada‐Reno, Reno, NV 89557

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