TECHNICAL PAPERS
Jun 1, 1993

Soil‐Fabric Measurement using Phase Transition Porosimetry

Publication: Journal of Geotechnical Engineering
Volume 119, Issue 6

Abstract

A new method for the study of soil fabric has been developed. This method has been referred to as conductometric phase transition porosimetry (CPTP). With CPTP, changes in electrical conductance and temperature of saturated soil samples are measured during a cycle of capillary freezing and melting. These measurements are used to calculate the sample's pore size distribution. The paper includes an introduction to CPTP, an investigation of the variability of test results, a comparison of results with mercury intrusion porosimetry (MIP), and a discussion of the advantages and disadvantages of CPTP. Experimental results show that the new methodology can provide a useful and valuable tool for quantitative studies of soil fabric and is capable of measuring pore sizes between 2.5 nm and 5,000 nm diameter. Pore sizes measured by CPTP are smaller than MIP‐measured pore sizes. Due to the lesser disturbance of pore structure and much larger sample size, CPTP provides a more accurate and representative measure of the pore structure of recompacted fine‐grained soils than MIP.

Get full access to this article

View all available purchase options and get full access to this article.

References

1.
Atkins, P. W. (1982). Physical chemistry. 2nd ed., Freeman, New York, N.Y., 204, 923.
2.
Benjamin, J. R., and Cornell, C. A. (1970). Probability, statistics, and decision for civil engineers, McGraw‐Hill, New York, N.Y., 12.
3.
Brun, M. A., Lallamond, A., Quinso, J. F., and Eyraud, C. (1977). “A method for the simultaneous determination of the size and shape of pores: The thermoporometry.” Thermochemia Acta, 21(1), 59–88.
4.
Day, P. R. (1965). “Particle fractionation and particle‐size analysis.” Methods of soil analysis, Part 1. Agronomy, 9(1), 545–567.
5.
Eckrich, J., Enüstün, B. V., and Demirel, T. (1986). “Phase transition porosimeter.” American Lab., 18(3), 80–92.
6.
Enüstün, B. V., Eckrich, J., and Demirel, T. (1985). “Phase transition porosimetry.” Proc. Int. Symp. Workshop on Particulate and Multi‐Phase Processes and 16th Annual Meeting of the Fine Particle Society, Fine Particle Society, Tulsa, Okla., 68‐1–68‐7.
7.
Enüstün, B. V., Gunnink, B. W., and Demirel, T. (1990). “Phase transition porosimetry and surface area determination.” J. Colloid Interface Sci., 134(1), 264–273.
8.
Enüstün, B. V., Sentürk, H. S., and Kösal, K. (1965). “Freezing‐melting behaviour of capillary water in porous materials.” RILEM/CIB Symp., Moisture Problems in Bldgs., Helsinki, Report 2013, Int. Union of Testing and Res. Lab. and Struct. (RILEM), Paris, France, 1–10.
9.
Enüstün, B. V., Sentürk, H. S., and Yordakul, O. (1978). “Capillary freezing and melting.” J. Colloid Interfacial Sci., 65(3), 509–516.
10.
Everett, D. H. (1961). “The thermodynamics of frost damage to porous solids.” Trans. Faraday Soc., 57(9), 1541–1551.
11.
Everett, D. H., and Haynes, J. M. (1965). “Capillary properties of some model pore systems with special reference to frost damage.” RILEM Bulletin No. 27, Int. Union of Testing and Res. Lab. and Struct. (RILEM), Paris, France, 31–38.
12.
Gunnink, B. W. (1987). “Determination of the pore structure of porous materials using electrical conductance,” PhD thesis, Iowa State University, Ames, Iowa.
13.
Gunnink, B. W. (1989a). “Critical analysis of conductometric phase transition porosimetry I. Capillary freezing and melting.” Particulate Sci. Tech., 7(2), 229–239.
14.
Gunnink, B. W. (1989b). “Critical analysis of conductometric phase transition porosimetry II. Pore geometry factors.” Particulate Sci. Tech., 7(2), 241–251.
15.
Gunnink, B. W. (1991). “A new method for measuring pore size distributions in concrete.” J. Materials in Civ. Engrg., ASCE, 3(4), 307–319.
16.
Gunnink, B. W., Demirel, T., and Enüstün, B. V. (1990). “Environmental degradation of concrete pore structure.” Serviceability and Durability of Construction Materials, Proc. 1st Materials Engrg. Congress, ASCE, New York, N.Y., 1103–1112.
17.
Gunnink, B. W., Enüstün, B. V., and Demirel, T. (1988). “Determination of the pore structure of porous materials using electrical conductance.” Particulate Sci. Tech., 6(1), 105–117.
18.
Hesstvedt, E. (1964). “The interfacial energy ice/water.” Publication No. 56, Norwegian Geotechnical Inst., Oslo, Norway, 7–10.
19.
Horton, R., Thompson, M. L., and McBride, J. F. (1987). “Method of estimating the travel time of noninteracting solutes through compacted soil material.” Soil Soc. America J., 51(1), 48–53.
20.
Klute, A. (1986). Methods of soil analysis, American Soc. Agronomy: Soil Sci. Soc. of America, Madison, Wis.
21.
McBride, J. F., Horton, R., and Thompson, M. L. (1987). “Evaluation of three Iowa soil materials as liners for hazardous‐waste landfills.” Proc. Iowa Acad. Sci., 94(3), 73–77.
22.
“Standard test method for determination of pore volume and pore volume distribution of soil and rock by mercury intrusion porosimetry.” (1990). Annual Book of ASTM Standards, 12.01, 656–660.
23.
Thompson, M. L., McBride, J. F., and Horton, R. (1985). “Effects of drying treatments on porosity of soil materials.” Soil Sci. Soc. of America J., 49(6), 1360–1364.
24.
Vinegar, H. J. (1986). “X‐ray CT and NMR Imaging of Rocks.” J. Pet. Tech., 38(3), 257–259.
25.
Völkl, J. J., Beddoe, R. E., and Setzer, M. J. (1987). “The specific surface of hardened cement paste by small‐angle X‐ray scattering effect of moisture content and chlorides.” Cem. Conc. Res., 17(1), 81–88.

Information & Authors

Information

Published In

Go to Journal of Geotechnical Engineering
Journal of Geotechnical Engineering
Volume 119Issue 6June 1993
Pages: 1019 - 1036

History

Received: Aug 10, 1991
Published online: Jun 1, 1993
Published in print: Jun 1993

Permissions

Request permissions for this article.

Authors

Affiliations

Brett W. Gunnink, Member, ASCE
Asst. Prof., Dept. of Civ. Engrg., Univ. of Missouri‐Columbia, Columbia, MO 65211
Jalal El‐Jayyousi
Grad. Asst., Univ. of Missouri‐Columbia, Columbia, MO

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share