TECHNICAL PAPERS
Nov 1, 1992

Phenol Removal from Kaolinite by Electrokinetics

Publication: Journal of Geotechnical Engineering
Volume 118, Issue 11

Abstract

Electro‐osmosis tests are conducted on saturated kaolinite specimens loaded with phenol at a level of 500 μg/g of dry kaolinite. This amount was below the phenol adsorption capacity of this mineral. The flow behavior and the electrochemistry (voltage, current, resistance, pH gradients, and conductivity) in these experiments are presented. Electroosmotic flow with open electrodes is time‐dependent. Acid front generated at the anode sweeps across the specimen neutralizing the base at the cathode. The adsorbed phenol was removed by 85%‐95% by the process. Phenol concentration profile in the effluent did not display any retardation due to desorption. The energy expenditure for removal was of the order of 18–39 kWh/m3 of soil processed. The study displays that it may be feasible to remove low‐concentration organic contaminants from cohesive soils by application of a direct current.

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Published In

Go to Journal of Geotechnical Engineering
Journal of Geotechnical Engineering
Volume 118Issue 11November 1992
Pages: 1837 - 1852

History

Published online: Nov 1, 1992
Published in print: Nov 1992

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Authors

Affiliations

Yalcin B. Acar, Member, ASCE
Prof., Dept. of Civ. Engrg., Louisiana State Univ., Baton Rouge, LA 70803
Heyi Li
Grad. Res. Asst., Dept. of Chem., Louisiana State Univ., Baton Rouge, LA
Robert J. Gale
Assoc. Prof., Dept. of Chem., Louisiana State Univ., Baton Rouge, LA

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