TECHNICAL PAPERS
Jan 1, 2007

Information Collection Rule Data Evaluation and Analysis to Support Impacts on Disinfection By-Product Formation

Publication: Journal of Environmental Engineering
Volume 133, Issue 1

Abstract

Information Collection Rule (ICR) water quality and treatment data were screened from an end-user’s perspective and data distributions were developed based on the screened data set. Questionable data were flagged and missing categorical variables were replaced where possible. Sparseness of flagged data indicated a high level of ICR data quality while recovery of missing descriptors substantially amplified the data set. Data patterns demonstrated anticipated relationships between disinfection practices and water quality: plants with high concentrations of organic precursors preferentially employed chloramines and avoided prechlorination; plants with high bromide levels also tended to employ chloramines although bromide did not impact prechlorination practice. Though plants employing chloramination used significantly higher chlorine doses than plants using only free chlorine, when normalized to total organic carbon (TOC) this difference largely disappeared. The median ICR chlorine to TOC ratio was 1.54mg Cl2mgC . Applied chlorine to ammonia-nitrogen ratios at chloramine plants varied widely but the median value was near the theoretical 1:1molar ratio. Significantly higher bromide to TOC ratios at ground water plants, compared to surface water plants, resulted from the typically lower TOC and higher bromide levels in ground waters.

Get full access to this article

View all available purchase options and get full access to this article.

Acknowledgments

This work was supported by funding from the USEPA Office of Water and Office of Research and Development under Cooperative Agreement No. 82920001. Richard Miltner of the USEPA provided guidance for the project. The writers also thank Mike McGuire and members of the Stage 2 M/DBP Technical Workgroup who assisted with development of the Aux 1 database and laid the foundation for current and future ICR data analysis efforts. Finally, this work is based on the significant contributions of all participating ICR water utilities.

References

Archer, A., and Singer, P. C. (2006). “An evaluation of the relationship between SUVA and NOM coagulation using the ICR database.” J. Am. Water Works Assoc., 98(7), 110–123.
Chen, J., and Regli, S. (2002). “Disinfection practices and pathogen inactivation in ICR surface water plants.” Information Collection Rule data analysis, M. J. McGuire, J. L. McLain, and A. Obolensky, eds., American Water Works Association Research Foundation, Denver, 371–396.
Connell, K., Rodgers, C. C., Shank-Givens, H. L., and Miller, K. (2000). “Building a better protozoa data set.” J. Am. Water Works Assoc., 92(10), 30–43.
Croue, J. P., Debroux, J. F., Amy, G. L., Aiken, G. R., and Leenheer, J. A. (1999). “Natural organic matter: Structural characteristics and reactive properties.” Formation and control of disinfection by-products in drinking water, P. C. Singer, ed., American Water Works Association, Denver, 65–93.
DiGiano, F. A., and Bond, R. G. (2004). “Evaluating GAC performance using the ICR database.” J. Am. Water Works Assoc., 96(6), 96–104.
Fair, P. S., Sorrell, R. K., Stultz-Karapondo, M., Bohl, B. J., Frebis, C. P., and Feige, M. A. (2002). “Quality of ICR monitoring data.” Information collection rule data analysis, M. J. McGuire, J. L. McLain, and A. Obolensky, eds., American Water Works Association Research Foundation, Denver, 39–66.
Hooper, S. M., and Allgeier, S. A. (2002). “GAC and membrane treatment studies.” Information collection rule data analysis, M. J. McGuire, J. L. McLain, and A. Obolensky, eds., American Water Works Association Research Foundation, Denver, 501–538.
Liang, L., and Singer, P. C. (2003). “Factors influencing the formation and relative distribution of haloacetic acids and trihalomethanes in drinking water.” Environ. Sci. Technol., 37(13), 2920–2928.
McGuire, M. J., and Hotaling, M. L. (2002). “Relationships between source water quality and choices of primary and secondary disinfectants.” Information Collection Rule data analysis, M. J. McGuire, J. L. McLain, and A. Obolensky, eds., American Water Works Association Research Foundation, Denver, 299–316.
McGuire, M. J., McLain, J. L., and Obolensky, A., eds. (2002). Information Collection Rule data analysis, American Water Works Association Research Foundation, Denver.
Messner, M. J., and Wolpert, R. L. (2002). “Cryptosporidium and Giardia occurrence in ICR drinking water sources—Statistical analysis of ICR data.” Information Collection Rule data analysis, M. J. McGuire, J. L. McLain, and A. Obolensky, eds., American Water Works Association Research Foundation, Denver, 463–482.
Obolensky, A., and Singer, P. C. (2005). “Halogen substitution patterns among disinfection byproducts in the information collection rule database.” Environ. Sci. Technol., 39(8), 2719–2730.
SAS Institute Inc. (1999). SAS/STAT user’s guide, version 8, SAS Institute Inc., Cary, N.C.
Scharfenaker, M. A. (2001). “Reg watch: USEPA offers first glimpse of stage 2 D/DBPR.” J. Am. Water Works Assoc., 93(12), 20–34.
Shukairy, H. M., and Summers, R. S. (1996). “DBP speciation and kinetics as affected by ozonation and biotreatment.” Disinfection byproducts in water treatment: The chemistry of their formation and control, R. A. Minear and G. L. Amy, eds., CRC, Boca Raton, Fla., 311–335.
Symons, J. M., Krasner, S. K., Sclimenti, M. J., Simms, L. A., Sorensen, H. W., Speitel, G. E., and Diehl, A. C. (1996). “Influence of bromide ion on trihalomethane and haloacetic acid formation.” Disinfection byproducts in water treatment: The chemistry of their formation and control, R. A. Minear and G. L. Amy, eds., CRC, Boca Raton, Fla., 91–130.
Symons, J. M., Krasner, S. K., Simms, L. A., and Sclimenti, M. J. (1993). “Measurement of THM and precursor concentrations revisited: The effect of bromide ion.” J. Am. Water Works Assoc., 85(1), 51–62.
U.S. Environmental Protection Agency (USEPA). (1994a). “National primary drinking water regulations; disinfectants and disinfection byproduct; proposed rule.” Federal Register, 59(No. 145; July 29), 38668–38829.
U.S. Environmental Protection Agency (USEPA). (1994b). “National primary drinking water regulations: Monitoring requirements for public drinking water supplies: Cryptosporidium, Giardia, viruses, disinfection byproducts, water treatment plant data and other information requirements; proposed rule.” Federal Register, 59(No. 28; February 10), 6332–6444.
U.S. Environmental Protection Agency (USEPA). (1996a). “DBP/ICR analytical methods manual.” EPA 814-B-96-002, Cincinnati.
U.S. Environmental Protection Agency (USEPA). (1996b). “National primary drinking water regulations: Monitoring requirements for public drinking water supplies: Cryptosporidium, Giardia, viruses, disinfection byproducts, water treatment plant data and other information requirements; final rule.” Federal Register, 61(No. 94; May 14), 24354–24388.
U.S. Environmental Protection Agency (USEPA). (2000a). “ICR auxiliary 1 database version 5.0, query tool version 2.0.” EPA 815-C-00-002 (CD-ROM), Cincinnati.
U.S. Environmental Protection Agency (USEPA). (2000b). “ICR treatment study database version 1.0.” EPA 815-C-00-003 (CD-ROM), Cincinnati.
U.S. Environmental Protection Agency (USEPA). (2000c). “Stage 2 microbial and disinfection byproducts federal advisory committee agreement in principle.” Federal Register, 65(No. 251; December 29), 83015–83024.
U.S. Environmental Protection Agency (USEPA). (2006a). “National primary drinking water regulations: Stage 2 disinfectants and disinfection byproducts rule; final rule.” Federal Register, 71(No. 2; January 4), 388–493.
U.S. Environmental Protection Agency (USEPA). (2006b). “National primary drinking water regulations: Long term 2 enhanced surface water treatment rule; final rule.” Federal Register, 71(No. 3; January 5), 654–786.
Wysock, B. M., Cummins, M. D., Fair, P. S., Feige, M. A., Sorrell, R. K., Walasek, J. B., Allgeier, S. C., Shukairy, H. M., Stultz-Karapondo, M., and Bohl, B. J. (2002). “ICR implementation and data collection challenges.” Information collection rule data analysis, M. J. McGuire, J. L. McLain, and A. Obolensky, eds., American Water Works Association Research Foundation, Denver, 1–38.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 133Issue 1January 2007
Pages: 53 - 63

History

Received: Aug 11, 2005
Accepted: May 10, 2006
Published online: Jan 1, 2007
Published in print: Jan 2007

Permissions

Request permissions for this article.

Authors

Affiliations

Alexa Obolensky
Research and Regulatory Programs Chemist, Philadelphia Water Dept., 1500 East Hunting Park Ave., Philadelphia, PA 19124.
Philip C. Singer, M.ASCE
P.E.
Dan Okun Distinguished Professor of Environmental Engineering, Dept. of Environmental Sciences and Engineering, CB #7431, Univ. of North Carolina, Chapel Hill, NC 27599-7431.
Hiba M. Shukairy
Environmental Scientist, U.S. Environmental Protection Agency Technical Support Center, MS140, 26 West M.L. King Dr., Cincinnati, OH 45268.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share