TECHNICAL PAPERS
Aug 1, 2006

Zirconia-Supported Copper Oxide—A Catalyst for Removal of Vehicular Exhaust Gas Pollutants

Publication: Journal of Environmental Engineering
Volume 132, Issue 8

Abstract

Copper oxide and zirconia-supported copper oxide catalysts were tested for their catalytic activity for carbon monoxide and propylene oxidation reactions. The synthesized catalyst was supported by wet impregnation on zirconia. The higher activity of zirconia-supported catalyst compared to unsupported catalyst may be attributed to homogeneous and higher dispersion on zirconia, ionic oxygen carrying capacity of zirconia. Catalyst 10%CuOZrO2 showed a best conversion efficiency of 90% at a temperature as low as 265°C for CO oxidation. T50 and T100 for propylene oxidation on zirconia-supported copper oxide were 392 and 450°C , respectively.

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Acknowledgments

The writer acknowledges with thanks Professor I. M. Mishra and Dr. Shri Chand of Chemical Engineering Department, Indian Institute of Technology, Roorkee for their help, guidance, and encouragement during the experimental work carried out.

References

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Kumat, A. G., and Rao, K. C. K. (1997). “Effect of vehicular pollution on urban environment: Light rail transit system—A case study.” Int. Conf. on Civil Engineering for Sustainable Development, Indian Institute of Technology Roorkee, India, 335–346.
Nath, B., and Deb, S. K. (1997). “Transportation strategies for sustainable development of Indian cities—The need of time.” Int. Conf. on Civil Engineering for Sustainable Development, Indian Institute of Technology, Roorkee, India.
Park, P. K., and Ledford, J. S. (1998). “The influence of surface structure on the catalytic activity of alumina supported copper oxide catalysts—oxidation of carbon monoxide and methane.” Appl. Catal., B, 15, 221–232.
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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 132Issue 8August 2006
Pages: 956 - 959

History

Received: Jun 11, 2004
Accepted: Nov 17, 2005
Published online: Aug 1, 2006
Published in print: Aug 2006

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Authors

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Anil Kumar Sharma [email protected]
Assistant Professor, Dept. of Civil Engineering, Maulana Azad National Institute of Technology, Bhopal, M.P., India. E-mail: [email protected]

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