TECHNICAL PAPERS
Feb 19, 2004

Destruction of 1,1,1-Trichloroethane Using Dielectric Barrier Discharge Nonthermal Plasma

Publication: Journal of Environmental Engineering
Volume 130, Issue 3

Abstract

This study investigates the feasibility of using nonthermal plasma produced in a dielectric barrier discharge reactor to destroy 1,1,1-trichloroethane (TCA) in a stream of air. The effects of various operating parameters on the destruction and removal efficiency (DRE) of TCA were examined. The experiments indicated that the water vapor concentration greatly influenced the destruction of TCA and the relative amount of oxidation by-products. DRE as high as 99.9% could be achieved at very low relative humidity (RH) conditions. Analysis of the CO/CO2 concentrations in the reactor effluent indicated a decrease in the amount of CO generated as the RH was increased. The lowest CO/CO2 ratio, 1:3, was observed at 88% RH. The estimated cost and energy requirement for operation were also determined. The calculated energy density values (β) varied with respect to the RH, and ranged from 1,478 to 3,010 J/L over a RH range of 0–88%.

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References

Cal, M. P., and Schluep, M.(2001). “Destruction of benzene in non-thermal plasma in dielectric barrier discharge reactor.” Environ. Prog., 20(3), 151–156.
Chang, M. B., Kushner, M. J., and Rood, M. J.(1993). “Removal of SO2 and NO from gas streams with combined plasma photolysis.” J. Environ. Eng., 119(3), 414–423.
Chang, M. B., and Lee, C. C.(1995). “Destruction of formaldehyde with dielectric barrier discharge plasmas.” Environ. Sci. Technol., 29, 181–186.
Coogan, J. J., and Jassal, A. S. (1997). “Silent discharge plasma for point of use (POU) abatement of volatile organic compound (VOC) emission: Final report (ESHC003).” SEMATECH Technology Transfer Document No. 97023244A-ENG, SEMATECH, Austin, Tex.
Evans, D., Rosocha, L. A., Anderson, G. K., Coogan, J. J., and Kushner, M. J.(1993). “Plasma remediation of trichloroethylene in silent discharge plasma.” J. Appl. Phys., 74, 5378–5386.
Falkenstein, Z., and Coogan, J.(1997). “Microdischarge behavior in the silent discharge of nitrogen–oxygen and water–air mixtures.” J. Phys. D, 30(5), 817–825.
Futamura, S., Zhang, A., et al. (2002). “Involvement of catalyst materials in nonthermal plasma chemical processing of hazardous air pollutants.” Catal. Today, 72, 259–265.
Manley, T. C.(1943). “The electric characteristics of the ozonator discharges.” Trans. Electrochem. Soc., 84, 83–96.
McCulla, W. H., Rosocha, L. A., Neely, W. C., Clothiaux, E. J., Kushner, M. J., and Rood, M. J. (1991). “Treatment of hazardous organic wastes using wet air plasma.” Proc., 1st NEL Workshop on Plasma Applications to Waste Treatment.
Meek, J. M., and Craggs, J. D. (1953). “Breakdown voltage characteristics.” Electrical breakdown of gases, Wiley–Interscience, New York, 533–545.
National Safety Council (NSC). (2001). http://www.nsc.org/
Nunez, C. M., Ramsey, G. H., Ponder, W. H., Abbot, J. H., Hamel, L. E., and Kariher, P. H.(1993). “Corona destruction: An innovative control technology for VOCs and air toxics.” J. Air Waste Manage. Assoc., 42(2), 242.
Rosocha, L. A. (1991). “Cold plasma destruction of Savannah River off-gas VOCs.” Technical Task Plan No. TTP a11211109, U.S. Dept. of Energy, Office of Environmental Management Technology Development, Washington, D.C.
Rosocha, L. A., Anderson, G. K., Bechtold, L. A., Coogan, J. J., Heck, H. G., Kang, M., McCulla, W. H., Tennant, R. A., and Wantuck, P. J. (1993). “Treatment of hazardous organic wastes using silent discharge plasma.” Non-Thermal Plasma Techniques for Pollution Control, NATO ASI Ser. G, B. M. Penetrante and S. E. Schultheis, eds., Springer, G34-Part B, 281–306.
Rosocha, L. A., and Korzekwa, R. A.(1999a). “Advanced oxidation and reduction processes in the gas phase using nonthermal plasmas.” J. Adv. Oxid. Technol., 4(3), 247–264.
Rosocha, L. A., and Korzekwa, R. A.(1999b). “Treatment of a multicomponent VOC mixture in air using a dielectric barrier discharge.” J. Adv. Oxid. Technol., 4(4), 390–399.
Snyder, H., and Anderson, G. K.(1998). “Effect of air and oxygen content on the dielectric barrier discharge decomposition of chlorobenzene.” IEEE Trans. Plasma Sci., 26, 1695–1699.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 130Issue 3March 2004
Pages: 349 - 355

History

Received: Sep 11, 2002
Accepted: Jul 15, 2003
Published online: Feb 19, 2004
Published in print: Mar 2004

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Authors

Affiliations

Sandeep Agnihotri
PhD Candidate, Dept. of Civil and Environmental Engineering, Univ. of Illinois, Urbana–Champaign, 205 N. Mathews, Urbana, IL 61820.
Mark P. Cal
Dept. Chair, Dept. of Environmental Engineering, New Mexico Tech, 801 Leroy Place, Socorro, NM 87801.
Justin Prien
MS Student, Dept. of Environmental Engineering, New Mexico Tech, 801 Leroy Place, Socorro, NM 87801.

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