TECHNICAL PAPERS
Nov 15, 2004

Modeling Long-Term Transport of Contaminants Resulting from Dissolution of a Coal Tar Pool in Saturated Porous Media

Publication: Journal of Environmental Engineering
Volume 130, Issue 12

Abstract

In this study, a three-dimensional mathematical model for simulating the transport of dissolved contaminants originating from an elliptic-shaped coal tar pool in homogeneous saturated porous media is developed. The methodology of the solution is based on a semianalytical approach that assumes the contaminant source input can be represented by the superposition of a series of consecutive short dissolution pulses. The model accounts for possible solidification of polycyclic aromatic hydrocarbon compounds as the coal tar pool dissolves. A circular-shaped synthetic coal tar pool consisting of 22 components is used for model simulation. Simulations show that even after 130 years of dissolution, the coal tar pool remains a potential groundwater pollution threat despite a significant reduction in overall pool volume.

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References

1.
Brown, D. G., Knightes, C. D., and Peters, C. A. (1999). “Risk assessment for polycyclic aromatic hydrocarbon NAPLs using component fractions.” Environ. Sci. Technol., 33(24), 4357–4363.
2.
Chrysikopoulos, C. V. (1995). “Three-dimensional analytical models of contaminant transport from nonaqueous phase liquid pool dissolution in saturated subsurface formations.” Water Resour. Res., 31, 1137–1145.
4.
Chrysikopoulos, C. V., and Lee, K. Y. (1998). “Contaminant transport resulting from multicomponent nonaqueous phase liquid pool dissolution in three-dimensional subsurface formations.” J. Contam. Hydrol., 31(1–2), 1–21.
5.
Chrysikopoulos, C. V., Lee, K. Y., and Harmon, T. C. (2000). “Harmon, Dissolution of a well-defined trichloroethylene pool in saturated porous media: Experimental design and aquifer characterization.” Water Resour. Res., 36(7), 1687–1696.
3.
Chrysikopoulos, C. V., Hsuan, P-Y., Fyrillas, M. M., and Lee, K. Y. (2003). “Mass transfer coefficient and concentration boundary layer thickness for a dissolving NAPL pool in porous media.” J. Hazard. Mater., 97(1–3), 245–255.
6.
Dabestani, R., and Ivanov, I. N. (1999). “A compilation of physical, spectroscopic, and photophysical properties of polycyclic aromatic hydrocarbons.” Photochem. Photobiol., 70(1), 10–34.
7.
de Marsily, G. ( 1986). Quantitative hydrogeology, groundwater hydrology for engineers. Academic, San Diego.
8.
Eberhardt, C., and Grathwohl, P. (2002) “Time scales of organic contaminant dissolution from complex source zones: coal tar pools vs. blobs.” J. Contam. Hydrol., 59(1–2), 45–66.
9.
Hashimoto, I., Deshpande, K. B., and Thomas, H. C. (1964). “Peclet numbers and retardation factors for ion exchange columns.” Ind. Eng. Chem. Fundam., 3, 213–218.
10.
Hayduk, W., and Laudie, H. (1975). “Prediction of diffusion coefficients for nonelectrolytes in dilute aqueous solutions.” AIChE J., 20(3), 611–615.
11.
Incropera, F.P., and DeWitt, D.P. ( 1990). Fundamentals of heat and mass transfer. 3rd Ed., Wiley, New York.
12.
Karickhoff, S. W. (1984). “Organic pollutant sorption in aquatic systems.” J. Hydrol. Eng., 110(6), 707–735.
13.
Lee, K. Y. (2002). “Transport of dissolved contaminants originating from a rectangular prism-shaped, multicomponent nonaqueous-phase liquid source in saturated porous media.” Environ. Geol., 43(1–2), 132–137.
14.
Lee, K. Y., and Chrysikopoulos, C. V. (1995). “Numerical modeling of three-dimensional contaminant migration from dissolution of multicomponent NAPL pools in saturated porous media.” Environ. Geol., 26(3), 157–165.
15.
Lee, K. Y., and Chrysikopoulos, C. V. (2002). “Dissolution of a well-defined trichloroethylene pool in saturated porous media: experimental results and model simulations.” Water Res., 36(15), 3911–3918.
16.
Mackay, D., Shiu, W.Y., and Ma, K.C. ( 1992). Illustrated handbook of physical–chemical properties and environmental fate for organic chemicals, Vols. 1-2 Lewis, Chelsea, Mich.
17.
Muller, P. ( 2002). Potential for occupational and environmental exposure to ten carcinogens in Toronto. Prepared for Toronto Public Health, ToxProbe, Inc.
19.
Peters, C. A., and Luthy, R. G. (1993). “Coal tar dissolution in water-miscible solvents: experimental evaluation.” Environ. Sci. Technol., 27, 2831–2843.
20.
Peters, C. A., and Luthy, R. G. (1994). “Semiempirical thermodynamic modeling of liquid-liquid phase equilibria: Coal tar dissolution in water miscible solvents.” Environ. Sci. Technol., 28, 1331–1340.
21.
Peters, C. A., Mukherji, S., Knightes, C. D., and Weber, W. J. (1997). “Phase stability of multicomponent NAPLs containing PAHs.” Environ. Sci. Technol., 31(9), 2540–2546.
18.
Peters, C. A., Knightes, C. D., and Brown, D. G. (1999). “Long-term composition dynamics of PAH-containing NAPLs and implications for risk assessment.” Environ. Sci. Technol. 33(24), 4499–4507.
22.
Seagren, E. A., Rittmann, B. E., and Valocchi, A. J. (1994). “Quantitative evaluation of the enhancement of NAPL-pool dissolution by flushing and biodegradation.” Environ. Sci. Technol., 28(5), 833–839.
23.
Sverdrup, L. E., Nielsen, T., and Krogh, P. H. (2002). “Soil ecotoxicity of polycyclic aromatic hydrocarbons in relation to soil sorption, lipophilicity, and water solubility.” Environ. Sci. Technol., 36(11), 2429–2435.

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Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 130Issue 12December 2004
Pages: 1507 - 1513

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Published online: Nov 15, 2004
Published in print: Dec 2004

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Authors

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Kenneth Y. Lee
Assistant Professor, Dept. of Civil and Environmental Engineering, Rutgers, The State Univ. of New Jersey, Piscataway, NJ 08854. E-mail: [email protected]

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