TECHNICAL PAPERS
Nov 1, 2004

Removal of Aqueous Phase Trichloroethylene Using Membrane Air Stripping Contactors

Publication: Journal of Environmental Engineering
Volume 130, Issue 11

Abstract

This work investigates the use of membrane air-stripping (MAS) contactors containing microporous polypropylene hollow-fiber membranes to remove volatile organic compounds from water into the gas phase. Experiments using countercurrent and cross-flow flow configurations to remove trichloroethylene (TCE) from water into air were performed. The effects of influent TCE concentration, liquid and gas flow rates, and air-to-water ratio were investigated. In each case studied, it was found that mass transfer in MAS contactors is controlled by liquid-phase resistance. Maximum removal of TCE was obtained at air-to-water ratios that were significantly lower than those required for conventional packed-tower stripping. Mathematical models based on empirical correlations for the liquid-phase convective mass transfer coefficients were developed and validated with experimental data, and subsequently used to perform simulations of full-scale MAS contactors. At the operating conditions explored, full-scale cross-flow contactors were shown to be superior to countercurrent-flow contactors: for the same gas and liquid flow rates and number of fibers, cross-flow contactors removed more than 95% of the original TCE in the feed liquid whereas countercurrent-flow contactors removed less than 50%. In comparison with packed-tower stripping, MAS contactors are shown to be an alternative feasible technology.

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References

1.
Ahmed, T., and Semmens, M. J. (1996). “Use of transverse flow hollow fibers for bubbleless membrane aeration.” Water Res., 30, 440–446.
2.
Amy, G. L., and Cooper, W. (1986). “Air stripping of volatile organic compounds using structured media.” J. Environ. Eng., 112(4), 729–743.
3.
Ball, W. P., Jones, M. D., and Kavanaugh, M. C. (1984). “Mass transfer of volatile organic compounds in packed tower aeration.” J. Water Pollut. Control Fed., 56(2), 127–136.
4.
Banat, F. A., and Simandl, J. (1996). “Removal of benzene trace from contaminated water by vacuum membrane distillation.” Chem. Eng. Sci., 51(8), 1257–1265.
5.
Bhaumik, D., Majumdar, S., and Sirkar, K. K. (1998). “Adsorption of CO2 in a transverse flow hollow fiber membrane module having a few wraps of the fiber mat.” J. Membr. Sci., 138, 77–82.
6.
Bosewell, S.T., Vaccari, D.A. ( 1994). “Plate and frame membrane air stripping.” Proc., 21st Annual Conf. on Water Policy and Proc. of 21st. Annual Conf. on Water Policy Management Solving Problems 1994, ASCE, New York, 726–729.
7.
Castro, K., and Zander, A. K. (1995). “Membrane air-stripping: effect of pretreatment.” J. Am. Water Works Assoc., 87(3), 50–61.
8.
Costello, M. J., Fane, A. G., Hogan, P. A., and Schofield, R. W. (1993). “The effect of shell side hydrodynamics on the performance of axial flow hollow fiber modules.” J. Membr. Sci., 80, 1–11.
9.
Cote, P., Bersillon, J.-L., and Huyard, A. (1989). “Bubble-free aeration using membranes: mass transfer analysis.” J. Membr. Sci., 47, 91–106.
10.
Cussler, E.J. ( 1984). Diffusion mass transfer in fluid systems, Cambridge University Press, London.
11.
Dahuron, L., and Cussler, E. L. (1988). “Protein extractions with hollow fibers.” AIChE J., 34(1), 130–136.
12.
Dzombak, D.A., Fang, H.J., and Roy, S.B. ( 1993). “ASDC: A microcomputer-based program for air stripper design and costing.” CE Rep. No 92-204, Dept. of Civil Engineering, Carnegie Mellon Univ., Pittsburgh.
13.
Gabelman, A., and Hwang, S.-T. (1999). “Hollow fiber membrane contactors.” J. Membr. Sci., 159, 61–106.
14.
Hand, D. W., Crittenden, J. C., Gehin, J. L., and Lykins, B. W., Jr. (1986). “Design and evaluation of an air-stripping tower for removing VOCs from groundwater.” J. Am. Water Works Assoc., 78(9), 87–97.
15.
Johnson, D. W., Semmens, M. J., and Gulliver, J. S. (1997). “Diffusive transport across unconfined hollow fiber membranes.” J. Membr. Sci., 128, 67–81.
16.
Kesting, R.E. ( 1971). Synthetic polymeric membranes, McGraw-Hill, New York.
17.
Kreith, F., and Black, W.Z. ( 1980). Basic heat transfer, Harper & Row, New York.
18.
Kreulen, H., Smolders, C. A., Versteeg, G. F., and Van Swaaiji, W. P. M. (1993). “Determination of mass transfer rates in wetted and non-wetted microporous membranes.” Chem. Eng. Sci., 48(11), 2093–2102.
19.
LaGrega, M.D., Buckingham, P.L., and Evans, J.C. ( 1994). Hazardous waste management, McGraw-Hill, New York.
20.
Matsuura, T. ( 1993). Synthetic membranes and membrane separation processes, CRC, Boca Raton, Fla.
21.
National Research Council (NRC). (1997). Innovations in groundwater and soil cleanup, National Academy Press, Washington, D. C.
22.
Prasad, R., and Sirkar, K. K. (1988). “Dispersion-free solvent extraction with microporous hollow-fiber modules.” AIChE J., 34(2), 177–188.
23.
Qi, Z., and Cussler, E. L. (1985a). “Hollow fiber gas membranes.” AIChE J., 31(9), 1548–1533.
24.
Qi, Z., and Cussler, E. L. (1985b). “Microporous hollow fibers for gas absorption. II. Mass transfer across the membrane.” J. Membr. Sci., 23, 333–345.
25.
Semmens, M. J., Qin, R., and Zander, A. (1989). “Using a microporous hollow-fiber membrane to separate VOCs from water.” J. Am. Water Works Assoc., 81(4), 162–167.
26.
Wang, K. L., and Cussler, E. L. (1993). “Baffled membrane modules made with hollow fiber fabric.” J. Membr. Sci., 85, 265–278.
27.
Wickramasinghe, S. R., Semmens, M. J., and Cussler, E. L. (1992). “Mass transfer in various hollow fiber geometries.” J. Membr. Sci., 69, 235–250.
28.
Wickramasinghe, S. R., Semmens, M. J., and Cussler, E. L. (1993). “Hollow fiber modules made with hollow fiber fabric.” J. Membr. Sci., 84, 1–14.
29.
Yang, M. C., and Cussler, E. L. (1986). “Designing hollow-fiber contactors.” AIChE J., 32(11), 1910–1916.
30.
Zander, A. K., Semmens, M. J., and Narbaitz, R. M. (1998). “Removing VOCs by membrane stripping.” J. Am. Water Works Assoc., 81(11), 76–81.

Information & Authors

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 130Issue 11November 2004
Pages: 1232 - 1241

History

Published online: Nov 1, 2004
Published in print: Nov 2004

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Authors

Affiliations

Jiahan He
Engineer, MPR Engineering Corp., Inc., 3010 S. Canal St., Chicago, IL 60616. E-mail: [email protected]
Robert G. Arnold
Professor, Dept. of Chemical and Environmental Engineering, Univ. of Arizona, Tucson, AZ 85721. E-mail: [email protected]
A. Eduardo Sáez
Associate Professor, Dept. of Chemical and Environmental Engineering, Univ. of Arizona, Tucson, AZ 85721. E-mail: [email protected]
Eric A. Betterton
Professor, Dept. of Atmospheric Science, Univ. of Arizona, Tucson, AZ 85721. E-mail: [email protected]
Wendell P. Ela
Associate Professor, Dept. of Chemical and Environmental Engineering, Univ. of Arizona, Tucson, AZ 85721 (corresponding author). E-mail: [email protected]

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