TECHNICAL PAPERS
Aug 15, 2002

Role of Natural Attenuation in Life Cycle of MTBE Plumes

Publication: Journal of Environmental Engineering
Volume 128, Issue 9

Abstract

The natural life cycle of a plume of methyl tert-butyl ether from a spill of gasoline is controlled by the rate of attenuation of the source (due to partitioning from the residual gasoline to the flow of groundwater) and the rate of attenuation in the plume (due to dispersion and natural biodegradation). Rates of attenuation were extracted for plumes in California, Florida, North Carolina, New York, and New Jersey. The maximum rate of attenuation of the source was 0.75 per year. The rates of attenuation in the plumes varied from 0.56 to 4.3 per year. In all cases, the rate of attenuation of the plume exceeded the rate of attenuation of the source. As these plumes progress through their life cycle, they should recede back toward their source.

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References

Borden, R. C., Daniel, R. A., LeBrun, IV, L. E., and Davis, C. W.(1997). “Intrinsic Biodegradation of MTBE and BTEX in a gasoline-contaminated aquifer.” Water Resour. Res., 33(5), 1105–1115.
Buscheck, T. E., and Alcantar, C. M. (1995). “Regression techniques and analytical solutions to demonstrate intrinsic bioremediation.” Proc., 3rd Int. In Situ and On-Site Bioremediation Symposium, Battelle, Columbus, Ohio, 3(1), 109–116.
Johnson, R., Pankow, J., Bender, D., Price, C., and Zogorski, J.(2000). “MTBE: To what extent will past releases contaminate community water supply wells?” Environ. Sci. Technol., 34(9), 210A–217A.
Kolhatkar, R., Wilson, J., and Dunlap, L. E. (2000). “Evaluating natural biodegradation of MTBE at multiple UST sites.” Proc., Petroleum Hydrocarbons and Organic Chemicals in Ground Water: Prevention, Detection, and Remediation Conf., Anaheim, Calif., November 15–17, 2000, National Ground Water Association, Westerville, Ohio, 32–49.
Kolhatkar, R., Wilson, J., and Hinshalwood, G. (2001). “Natural biodegradation of MTBE at a site on Long Island, N.Y.” Proc., 6th Int. In Situ and On-Site Bioremediation Symposium, Battelle, Columbus, Ohio, 6(1), 43–50.
Landmeyer, J. E., Chapelle, F. H., Herlong, H. H., and Bradley, P. M.(2001). “Methyl tert-butyl ether biodegradation by indigenous aquifer microorganisms under natural and artificial oxic Conditions.” Environ. Sci. Technol., 35(6), 1118–1126.
Moeri, E. N., Salvador, M. C., and Coelho, R. (2001). “Natural attenuation of MTBE as part of an integrated remediation design.” Proc., 6th Int. In Situ and On-Site Bioremediation Symposium, Battelle, Columbus, Ohio, 6(1), 27–32.
New England Interstate Water Pollution Control Commission (NEIWPCC). (2000). “Executive summary of a survey of state experiences with MTBE contamination at LUST sites.” New England Interstate Water Pollution Control Commission 〈http://www.neiwpcc.org/mtbemain.html〉.
Peargin, T. R. (2000). “Relative depletion rates of MTBE, benzene, and xylene from smear zone NAPL.” Proc., Petroleum Hydrocarbons and Organic Chemicals in Ground Water: Prevention, Detection, and Remediation Conf., Anaheim, Calif., November 15–17, 2000, National Ground Water Association, Westerville, Ohio, 207–212.
Rice, D. W., Grose, R. D., Michaelsen, J. C., Dooher, B. P., MacQueen, D. H., Cullen, S. J., Kastenberg, W. E., Everett, L. G., and Marino, M. A. (1995). “California leaking underground fuel tank (LUFT) historical case analyses.” Rep. No. UCRL-AR-122207, Environmental Protection Department, Environmental Restoration Division, Lawrence Livermore Laboratories, Livermore, Calif.
Robb, J., and Moyer, E. (2001). “Natural attenuation of dissolved benzene and MTBE—Two case studies.” Proc., 6th Int. In Situ and On-Site Bioremediation Symposium, Battelle, Columbus, Ohio, 6(1), 75–82.
Schirmer, M., and Barker, J. F. (1998). “A study of long-term MYBE attenuation in the Borden Aquifer, Ontario, Canada.” Ground Water Monit. Rem., 113–122.
Schirmer, M., Butler, B. J., Barker, J. F., Church, C. D., and Schirmer, K.(1999). “Evaluation of biodegradation and dispersion as natural attenuation processes of MTBE and benzene at the Borden field site.” Phys. Chem. Earth, 24(6), 557–560.
Small, M. C., and Weaver, J. (1999). “An updated conceptual model for subsurface fate and transport of MTBE and benzene.” Proc., Petroleum Hydrocarbons and Organic Chemicals in Ground Water: Prevention, Detection, and Remediation Conf., Houston, November 17–19, 1999, National Ground Water Association, Westerville, Ohio, 209–220.
U.S. EPA. (1996). “BIOSCREEN natural attenuation decision support system, Version 1.3.” Rep. No. EPA/600/R-96/087, Washington, D.C. 〈http://www.epa.gov/ada/csmos/models.html〉.
U.S. EPA. (1999). “Use of monitored natural attenuation at Superfund, RCRA corrective action, and underground storage tank Sites.” Office of Solid Waste and Emergency Response, Directive No. 9200.4-17P, Washington, D.C. 〈http://www.epa.gov/swerust1/oswermna/mna_epas.htm〉.
Weaver, J. W., Haas, J. E., and Sosik, C. (1999). “Characteristics of gasoline releases in the water table aquifer of Long Island.” Proc., Petroleum Hydrocarbons and Organic Chemicals in Ground Water: Prevention, Detection, and Remediation Conf., Houston, November 17–19, 1999, National Ground Water Assocation, Westerville, Ohio, 260–261.
Wilson, J. T., Cho, J. S., Wilson, B. H., and Vardy, J. A. (2000). “Natural attenuation of MTBE in the subsurface under methanogenic conditions.” Rep. No. EPA/600/R-00/006, EPA, Washington, D.C. 〈http://www.epa.gov/ada/pubs/reports.html〉.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 128Issue 9September 2002
Pages: 876 - 882

History

Received: Feb 13, 2002
Accepted: Apr 8, 2002
Published online: Aug 15, 2002
Published in print: Sep 2002

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Authors

Affiliations

John T. Wilson
Senior Research Microbiologist, Office of Research and Development/National Risk Management Research Laboratory, EPA, R. S. Kerr Environmental Research Center, 919 Kerr Research Drive, Ada, OK 74820.
Ravi Kolhatkar
Environmental Engineer, BP America, Inc., 150 West Warrenville Road, Naperville, IL 60563.

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