TECHNICAL PAPERS
May 1, 2001

Use of Iron Oxides to Enhance Metal Removal in Crossflow Microfiltration

Publication: Journal of Environmental Engineering
Volume 127, Issue 5

Abstract

This research investigated whether iron oxyhydroxides used in conjunction with microfiltration could improve the removal of metals from a waste while maintaining adequate flux. Filtration of individual metals, a mixture of metals, and the mixture with two iron oxides were investigated. The research indicated that use of a coagulant (an iron-containing salt) might not be as important in microfiltration systems as in conventional gravity separation systems, because of the small pore size of microfilters. In some cases, filtration efficiency was relatively poor at the beginning of a treatment cycle, but in almost all cases it became excellent once a layer had built up on the membrane surface. The greatest benefit provided by iron oxides might be to reduce membrane fouling. A crystalline iron oxide such as goethite is more attractive than ferrihydrite. The flux improvement with goethite is greatest if a thin layer is deposited on the membrane surface before the contaminant metals are injected into the system, so that the goethite can trap the potentially foulant metal hydroxide particles away from the membrane surface.

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References

1.
Anderson, P. A., and Benjamin, M. M. ( 1985). “Effects of silicon on the crystallization and adsorption properties of ferric oxides.” Envir. Sci. and Technol., 19, 1048–1053.
2.
Benjamin, M. M. ( 1983). “Adsorption and surface precipitation of metals on amorphous iron oxyhydroxide.” Envir. Sci. and Technol., 17, 686–692.
3.
Benjamin, M. M., and Leckie, J. O. ( 1981). “Competitive adsorption of Cd, Cu, Zn, and Pb, on amorphous iron oxyhydroxide.” J. Colloid Interface Sci., 83, 420–419.
4.
Broom, G. P., Squires, R. C., Simpson, M. P. J., and Martin, I. ( 1994). “The treatment of heavy metal effluents by crossflow microfiltration.” J. Membrane Sci., 87, 219–230.
5.
Chang, Y-J., and Benjamin, M. M. ( 1996). “A combined iron oxide adsorption and ultrafiltration process for natural organic matter removal and fouling control.” J. Am. Water Works Assn., 88(12), 74–88.
6.
Chang, Y-J., Choo, K-H., Benjamin, M. M., and Reiber, S. ( 1998). “Combined adsorption-UF process increases TOC removal.” J. Am. Water Works Assn., 90(5), 57–71.
7.
Coughlin, B. R., and Stone, A. T. ( 1995). “Nonreversible adsorption of divalent metal ions (Mn(II), Co(II), Ni(II), Cu(II), and Pb(II)) onto goethite: Effects of acidification, Fe(II) addition, and picolinic acid addition.” Envir. Sci. and Technol., 29, 2445–2454.
8.
Edwards, M. ( 1988). “Application of ferrihydrite adsorbents in treatment of metal bearing wastes.” Masters thesis, Department of Civil Engineering, University of Washington, Seattle.
9.
Johnson, B. B. ( 1990). “Effect of pH, temperature, and concentration on the adsorption of cadmium on goethite.” Envir. Sci. and Technol., 24, 112–118.
10.
Pirbazari, M., Bradriyha, B. N., and Ravindran, V. ( 1992). “MF-PAC for treating waters contaminated with natural and synthetic organics.” J. Am. Water Works Assn., 84(12), 95.
11.
Schecker, W. ( 1994). Mineql+, Chemical Equilibrium Management System, Version 3.01a.
12.
Schwertmann, U., and Cornell, R. M. ( 1991). Iron oxides in the laboratory: Preparation and characterization, VCH, New York.
13.
Voges, L. E. ( 1996). “The use of iron oxides to enhance metal removal in crossflow microfiltration.” Masters thesis, Department of Civil Engineering, University of Washington, Seattle.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 127Issue 5May 2001
Pages: 411 - 419

History

Received: Dec 1, 1998
Published online: May 1, 2001
Published in print: May 2001

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Authors

Affiliations

P.E.
Engr., Kennedy/Jenks Consultants, 530 South 336 St., Federal Way, WA 98003.
Prof., Dept. of Civ. Engrg., Univ. of Washington, Seattle, WA 98195.
Nat. Dir., Advanced Water Treatment, HDR Engineering, Inc.

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