TECHNICAL PAPERS
Feb 1, 2001

Long-Term AS/SVE for Petroleum Removal in Low-Permeability Piedmont Saprolite

Publication: Journal of Environmental Engineering
Volume 127, Issue 2

Abstract

A 3.5-year pilot test of air sparging/soil vapor extraction (AS/SVE) was carried out to determine whether the heterogeneity of the Piedmont saprolite would allow adequate soil vapor velocities and effective vapor-phase extraction rates for petroleum hydrocarbon (PHC) remediation. The objectives were to compare: (1) the effectiveness of pulsed SVE versus pulsed AS/SVE operation; (2) benzene, toluene, ethylbenzene, and xylene (BTEX) versus PHC removal; and (3) biological versus physical removal of PHC. Stack exhaust gas, SVE wells, and soil vapor probes were monitored for total combustible hydrocarbons (TCH), BTEX, O2, CO2, temperature, and flow rate using handheld meters and gas chromatography. The majority of contaminant recovered was removed from the vadose zone via SVE. BTEX and TCH were both effectively removed from the more-permeable and highly contaminated unsaturated-saturated zone interface. Bioremediation accounted for 23% of total removal. Overall, the AS/SVE system physically removed an estimated 18,800 kg of PHC and 5,300 g of BTEX with an average rate of 70 kg d−1 and 0.4 g d−1, respectively, which was consistent with other AS/SVE studies in sandy media.

Get full access to this article

View all available purchase options and get full access to this article.

References

1.
Aelion, C. M. ( 1996). “Impact of aquifer sediment grain size on petroleum hydrocarbon distribution and biodegradation.” J. Contaminant Hydrol., 22, 109–121.
2.
Aelion, C. M., and Kirtland, B. C. ( 2000). “Physical versus biological hydrocarbon removal during air sparging and soil vapor extraction.” Envir. Sci. and Technol., 34, 3167–3173.
3.
Aelion, C. M., Kirtland, B. C., and Stone, P. A. ( 1997). “Radiocarbon assessment of aerobic petroleum bioremediation in the vadose zone and groundwater at an AS/SVE site.” Envir. Sci. and Technol., 31, 3363–3370.
4.
Aelion, C. M., Ray, R. P., Widdowson, M. A., Reeves, H. W., and Shaw, J. N. ( 1996). “Simplified methods for monitoring petroleum-contaminated ground water and soil vapor.” J. Soil Contaminants, 5, 225–241.
5.
Aelion, C. M., Widdowson, M. A., Ray, R. P., Reeves, H. W., and Shaw, J. N. ( 1995). “Biodegradation, vapor extraction, and air sparging in low-permeability soils.” In situ aeration: Air sparging, R. E. Hinchee, R. N. Miller, and P. C. Johnson, eds., 127–134.
6.
Ahlfeld, D. P., Dahmani, A., and Ji, W. ( 1994). “A conceptual model of field behavior of air sparging and its implications for application.” Ground Water Monitoring and Remediation, 14, 132–139.
7.
Bruell, C. J., Marley, M. C., and Hopkins, H. H. ( 1997). “American Petroleum Institute in situ air sparging database.” J. Soil Contaminants, 6, 169–185.
8.
Cho, J. S., GiGiulio, D. C., and Wilson, J. T. ( 1997). “In situ air injection, soil vacuum extraction and enhanced biodegradation: A case study in a JP-4 jet fuel contaminated site.” Envir. Progress, 16, 35–42.
9.
Clayton, W. S., Brown, R. A., and Bass, D. H. ( 1995). “Air sparging and bioremediation: The case for in situ mixing.” In situ aeration: Air sparging, bioventing, and related remediation processes, R. E. Hinchee, ed., Battelle, Columbus, Ohio, 75–86.
10.
Gardner, L. R., Kheoruenromne, I., and Chen, H. S. ( 1978). Geochimica Cosmochimica Acta, 42, 417–424.
11.
Gordon, M. J. ( 1998). “Case history of a large-scale air sparging/soil vapor extraction system for remediation of chlorinated volatile organic compounds in ground water.” Ground Water Monitoring and Remediation, 18, 137–149.
12.
Hinchee, R. E., Downey, D. C., Dupont, R. R., Aggarwal, P. K., and Miller, R. N. ( 1991). “Enhancing the biodegradation of petroleum hydrocarbons through soil venting.” J. Haz. Mat., 27, 315–325.
13.
Hinchee, R. E., and Ong, S. K. ( 1992). “A rapid in situ respiration test for measuring aerobic biodegradation rates of hydrocarbons in soil.” J. Air Waste Mgmt. Assn., 42, 1305–1312.
14.
Ji, W., Dahmani, A., Ahlfeld, D. P., Lin, J. D., and Hill, E. ( 1993). “Laboratory study of air sparging: Air flow visualization.” Ground Water Monitoring and Remediation, 13, 115–127.
15.
Johnson, P. C., Das, A., and Bruce, C. ( 1999). “Effect of flow rate changes and pulsing on the treatment of source zones by in situ air sparging.” Envir. Sci. and Technol., 33, 1726–1731.
16.
Johnson, P. C., Kemblowski, M. W., Colthart, J. D. ( 1990). “Quantitative analysis for the cleanup of hydrocarbon-contaminated soils by in-situ venting.” Ground Water, 28, 413–429.
17.
Johnson, T. F. ( 1972). “Paleoenvironmental analysis and structural petrogenesis of the Carolina Slate Belt near Columbia, South Carolina.” MS thesis, University of South Carolina, Columbia, S.C.
18.
Johnston, C. D., Rayner, J. L., Patterson, B. M., and Davis, G. B. ( 1998). “Volatilisation and biodegradation during air sparging of dissolved BTEX-contaminated groundwater.” J. Contaminant Hydrol., 33, 377–404.
19.
Kirtland, B. C., and Aelion, C. M. ( 2000). “Petroleum mass removal from low permeability sediment using air sparging/soil vapor extraction: Impact of continuous or pulsed operation.” J. Contaminant Hydrol., 41, 367–383.
20.
Marley, M., Hazenbrouck, D. J., and Walsh, M. T. ( 1992). “The application of in situ air sparging as an innovative soils and ground water remediation technology.” Ground Water Monitoring Rev., 12, 137–145.
21.
McCray, J. E., and Falta, R. W. ( 1996). “Defining the air sparging radius of influence for groundwater remediation.” J. Contaminant Hydrol., 24, 25–52.
22.
McCray, J. E., and Falta, R. W. ( 1997). “Numerical simulation of air sparging for remediation of NAPL contamination.” Ground Water, 35, 99–110.
23.
Mehran, M. ( 1995). “Combined effects of water table drawdown, vapor extraction and air sparging on soil and groundwater remediation.” Proc., Emerging Technol. in Haz. Waste Mgmt. VI, American Chemical Society, Washington, D.C., 998–1001.
24.
Payne, F. C., Blaske, A. R., and Van Houten, G. A. ( 1995). “Contamination removal rates in pulsed and steady-flow aquifer sparging.” Air sparging for site remediation, R. E. Hinchee, ed., Lewis, Boca Raton, Fla., 177–183.
25.
Pijls, C. G. J. M., Urlings, L. G. C. M., van Vree, H. B. R. J., and Spuij, F. ( 1994). “Applications of in situ soil vapor extraction and air injection.” Air sparging for site remediation, R. E. Hinchee, ed., Lewis, Boca Raton, Fla., 128–136.
26.
Reddy, K. R., and Adams, J. A. (1998). “System effects on benzene removal from saturated soils and ground water using air sparging.”J. Envir. Engrg., ASCE, 124(3), 288–299.
27.
SAS/STAT user's guide. (1997). Version 7, SAS Institute, Cary, N.C.
28.
Reisinger, H. J., Mountain, S. A., Montney, P. A., Hullman, A. S., and Darnall, A. W. ( 1995). “Pressure dewatering: An extension of bioventing technology.” Air sparging and site remediation, R. E. Hinchee, ed., Lewis, Boca Raton, Fla., 267–276.
29.
Stomquist, A. A., and Sundelius, H. W. ( 1969). “Stratigraphy of the Albemarle Group of the Carolina Slate Belt in central North Carolina.” U.S. Geol. Survey Bull., 1274-B, 22.
30.
U.S. Environmental Protection Agency (USEPA). ( 1999). “Corrective Action Measures web site.” Office of Underground Storage Tanks, 〈http://www.epa.gov/swerust1/cat/camarchv.htm〉.
31.
Widdowson, M. A., Aelion, C. M., Ray, R. P., and Reeves, H. W. ( 1995a). “Soil vapor extraction pilot study at a Piedmont UST site.” In situ aeration, air sparging, bioventing, and related remediation processes, R. E. Hinchee, R. N. Miller, and P. C. Johnson, eds., Battelle, Columbus, Ohio, 455–461.
32.
Widdowson, M. A., Haney, O. R., Reeves, H. W., Aelion, C. M., and Ray, R. P. (1997). “Multilevel soil-vapor extraction test for heterogeneous soil.”J. Envir. Engrg., ASCE, 123(2), 160–168.
33.
Widdowson, M. A., Ray, R. P., Reeves, H. W., and Aelion, C. M. ( 1995b). “Integrated site characterization for SVE design.” Proc., The Geoenvironment 2000, Y. B. Acar and D. E. Daniel, eds., Vol. 2, ASCE, New York, 1291–1305.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 127Issue 2February 2001
Pages: 134 - 144

History

Received: Mar 20, 2000
Published online: Feb 1, 2001
Published in print: Feb 2001

Permissions

Request permissions for this article.

Authors

Affiliations

Dept. of Envir. Health Sci., Univ. of South Carolina, Columbia, SC 29208.
Dept. of Envir. Health Sci. and Marine Sci. Prog., Univ. of South Carolina, Columbia, SC (corresponding author). E-mail [email protected]
Dept. of Civ. and Envir. Engrg. Virginia Polytechnic Inst. and State Univ., Blacksburg, VA 24061-0105.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share