TECHNICAL PAPERS
Jan 1, 2001

Approach to Steady State in Completely Mixed Flow Reactors

Publication: Journal of Environmental Engineering
Volume 127, Issue 1

Abstract

Environmental engineers frequently employ the assumption that steady-state conditions are approximated after three hydraulic residence times. In this paper, the conditions under which this assumption is valid are elucidated. For well-mixed systems, the time to approach steady state depends on the kinetic order of removal mechanisms, the initial pollutant concentration in the control volume (=C0), and the kinetic rate constant. The assumption of three hydraulic residence times to steady state was found to be conservative if C0 = 0. However, if C0 equals the influent concentration, then more than three hydraulic residence times may be required to approach steady-state conditions with some zero-order reactions.

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References

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Amirtharajah, A., and O'Melia, C. R. ( 1990). “Coagulation processes: Destabilization, mixing, and flocculation.” Water quality and treatment, 4th Ed., F. W. Pontius, ed., McGraw-Hill, New York, 269–366.
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Denbigh, K. G., and Turner, J. C. R. ( 1984). Chemical reactor theory: An introduction, 3rd Ed., Cambridge University Press, London.
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Fogler, H. S. ( 1999). Elements of chemical reaction engineering, 3rd Ed., Prentice-Hall, Upper Saddle River, N.J.
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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 127Issue 1January 2001
Pages: 13 - 18

History

Received: Mar 22, 2000
Published online: Jan 1, 2001
Published in print: Jan 2001

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Authors

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James N. Jensen
Assoc. Prof., Dept. of Civ., Struct., and Envir. Engrg., 212 Ketter Hall, State Univ. of New York at Buffalo, Buffalo, NY 14260.

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