TECHNICAL PAPERS
Sep 1, 1998

Adsorption of Natural Organic Matter on Preformed Aluminum Hydroxide Flocs

Publication: Journal of Environmental Engineering
Volume 124, Issue 9

Abstract

Natural organic matter (NOM) was extracted from a raw water source (Forge Pond, Granby, Mass.) and fractionated into eight groups: fulvic acid, humic acid, hydrophilic acid, weak hydrophobic acids, hydrophilic neutrals, hydrophobic neutrals, hydrophilic bases, and hydrophobic bases. The extent of adsorption of these fractions on preformed aluminum hydroxide flocs was determined. Also, the adsorption affinities of various fractions were correlated to selected NOM properties, i.e., organic charge, molecular weight, and specific ultraviolet absorbance. The nature of the reactions leading to adsorption was discussed, along with the induced dissolution of aluminum from the floc surface and its resulting association with NOM in particulate or colloidal forms.

Get full access to this article

View all available purchase options and get full access to this article.

References

1.
APHA, AWWA, WEF. (1995). Standard methods for the examination of water and wastewater. APHA, Washington, D.C.
2.
Babcock, D. B., and Singer, P. C.(1979). “Chlorination and coagulation of humic and fulvic acid.”J. Am. Water Works Assn., 71(3), 149–152.
3.
Baes, C. F., and Mesmer, R. E. (1976). The hydrolysis of cations. Wiley–Interscience, New York, N.Y.
4.
Bose, P. (1994). “Selected physico-chemical properties of natural organic matter and its changes due to ozone treatment: Implications for coagulation using alum,” PhD dissertation, Univ. of Massachusetts, Amherst.
5.
Bowles, E. C., Antweiler, R. C., and MacCarthy, P. (1989). “Acid-base titrations of suwannee river fulvic acid.”U.S. Geological Survey Water-Open-File Rep. 87-557, USGS, Denver, Colo., 209.
6.
Davis, J. A. (1980). “Adsorption of natural organic matter from freshwater environments by aluminum oxide.”Contaminants and sediments, R. A. Baker, ed., Vol. 2, Ann Arbor Sci., Ann Arbor, Mich., 279–304.
7.
Davis, J. A.(1982). “Adsorption of natural dissolved organic matter at the oxide/water interface.”Geochim. Cosmochim. Acta, 46, 2381–2393.
8.
Davis, J. A., and Gloor, R.(1981). “Adsorption of dissolved organics in lake water by aluminum oxide: Effect of molecular weight.”Environ. Sci. Technol., 15(10), 1223–1229.
9.
Dempsey, B. A.(1987). “Reactions between fulvic acid and aluminum-effects on the coagulation process.”Div. of Envir. Chem., ACS, Denver, Colo., 27(1), 484–486.
10.
Dempsey, B. A. (1989). “Reactions between fulvic acid and aluminum.”Aquatic humic substances: Influence on fate and treatment of pollutants, I. H. Suffet and P. MacCarthy, eds., American Chemical Society, Washington, D.C., 409–424.
11.
Edwards, M. E. (1990). “Ozonation: Transformations of NOM, effect of organic matter-coagulant interactions and ozone induced particle destabilization,” Doctoral dissertation, University of Washington, Seattle.
12.
Edzwald, J. K.(1993). “Coagulation in drinking water treatment: Particles, organics and coagulants.”Water Sci. and Technol., 27(11), 21–25.
13.
Furrer, G., and Stumm, W.(1986). “The coordination chemistry of weathering: I. Dissolution kinetics of δ-Al2O3 and BeO.”Geochim. Cosmochim. Acta, 50, 1847–1860.
14.
Hall, E. S., and Packham, R. F.(1965). “Coagulation of organic color with hydrolyzing coagulants.”J. Am. Water Works Assn., 57(9), 1149.
15.
Hundt, T. R., and O'Melia, C. R.(1988). “Aluminum-fulvic acid interactions: Mechanisms and applications.”J. Am. Water Works Assn., 80(4), 176–186.
16.
Jekel, M. R.(1986). “Interactions of humic acids and aluminum salts in the flocculation process.”Water Res., 12(12), 1535–1542.
17.
Kummert, R., and Stumm, W.(1980). “The surface complexation of organic acids on hydrous-Al2O3.”J. Colloid Interface Sci., 75(2), 373–385.
18.
Leenheer, J. A., and Noyes, T. I. (1984). “A filtration and column adsorption system for on site concentration and fractionation of organic substances from large volumes of water.”U.S. Geological Survey Water Supply Paper 2230, USGS, Denver, Colo.
19.
Mazet, M., Angbo, L., and Serpaud, B.(1990). “Adsorption of humic substances onto preformed aluminum hydroxide flocs.”Water Res., 24(12), 1509.
20.
Moyers, B., and Wu, J. S.(1985). “Removal of organic precursors by permanganate oxidation and alum coagulation.”Water Res., 19(3), 309–314.
21.
Parfitt, R. L., Fraser, A. R., and Farmer, V. C.(1977). “Adsorption on hydrous oxides. III. Fulvic acid and humic acid in goethite, gibbsite and imogolite.”J. Soil Sci., 28, 289.
22.
Perrin, D. D., Dempsey, B., and Serjeant, E. P. (1981). pKa prediction for organic acids and bases. Chapman and Hall, New York, N.Y.
23.
Pontius, F. W.(1993). “D-DBP rule to set tight standards.”J. Am. Water Works Assn., 85(11), 22–30.
24.
Reckhow, D. A., and Singer, P. C.(1984). “The removal of organic halide precursors by preozonation and alum coagulation.”J. Am. Water Works Assn., 76(4), 151–157.
25.
Reckhow, D. A., Singer, P. C., and Malcolm, R. L.(1990). “Chlorination of humic materials: By-product formation and chemical interpretations.”Envir. Sci. and Technol., 24(11), 1655–1664.
26.
Reckhow, D. A., Bose, P., Bezbarua, B. K., Hesse, E., and MacNeill, A. (1992). “Transformations of natural organic matter during preozonation.”Proj. Rep., Drinking Water Res. Div., USEPA, Cincinnati, Ohio.
27.
Rook, J. J.(1976). “Haloforms in drinking water.”J. Am. Water Works Assn., 68(3), 168–172.
28.
Semmens, M. J., and Field, T. K.(1980). “Coagulation: Experiences in organics removal.”J. Am. Water Works Assn., 72(8), 476–483.
29.
Sinsabaugh, R. L., Hoehn, R. C., Knocke, W. R., and Linkins, A. E.(1986). “TOC removal by coagulation with iron sulfate.”J. Am. Water Works Assn., 78(5), 74–82.
30.
Smith, R. W., and Hem, J. D. (1972). “Effect of aging on aluminum hydroxide complexes in dilute aqueous solutions.”U.S. Geological Survey Water Supply Paper 1827-D, U.S. Government Printing Office, Washington, D.C.
31.
Tipping, E.(1981). “The adsorption of aquatic humic substances by iron oxides.”Geochim. Cosmochim. Acta, 45, 191–199.
32.
Tipping, E., Wolf, C., Walters, P. B., and Ohnstad, M.(1988). “Conditions required for the precipitation of aluminum in acidic natural waters.”Water Res., 22(5), 585–592.
33.
USEPA. (1991). “Status report on development of regulations for disinfectants and disinfection by-products.” USEPA, Washington, D.C.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 124Issue 9September 1998
Pages: 803 - 811

History

Published online: Sep 1, 1998
Published in print: Sep 1998

Permissions

Request permissions for this article.

Authors

Affiliations

Purnendu Bose
Asst. Prof., Envir. Engrg. & Mgmt. Programme, India Inst. of Technol., Kanpur, India.
David A. Reckhow
Prof., Dept. of Civ. and Envir. Engrg., Univ. of Massachusetts, Amherst, MA 01003; corresponding author.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share