TECHNICAL PAPERS
Jul 1, 1997

Correlation of Plume Opacity with Particles and Sulfates from Boilers

Publication: Journal of Environmental Engineering
Volume 123, Issue 7

Abstract

The effects of emission concentrations of particulate matters and sulfates on plume opacity are investigated by in situ measurements. The studies are conducted for three processes of two coal-fired plants and one oil-fired that are all equipped with electrostatic precipitators. Flue-gas sampling and analysis include the concentrations of particles and total water soluble sulfates, particle size distribution, and flue-gas composition; while in-stack and out-of-stack opacities are determined by a transmissometer and certified smoke inspectors, respectively. Experimental results show that plume opacity outside the stack linearly correlates well with the in-stack opacity. The mixing of hot flue gas with cold ambient air would result in the condensation of hygroscopic sulfuric acid aerosols and an increase about 1.6% out of typical 15–25% measured opacity. An empirical equation similar to the Beer-Lambert-Bouger form is derived for predicting the plume opacity in terms of the stack diameter and the concentrations of particles and total water soluble sulfates. Good comparisons are achieved between predictions by the empirical equation and other available field data.

Get full access to this article

View all available purchase options and get full access to this article.

References

1.
Chen, K. S., and Lou, J. C. (1993). “Correlation studies of plume opacity with emission concentrations of particulates and sulfuric acid vapor.”EPA-82-F105-09-019, Taipei, Taiwan.
2.
Cheney, J. L., and Homolya, J. B. (1978). “Characterization of combustion source sulfate emissions with a selective condensation sampling system.”Workshop Proc. on Primary Sulfate Emissions from Combustion Sources, EPA-600/9-78-020b, Vol. 1, Envir. Protection Agency (EPA), Washington, D.C., 53–62.
3.
Damle, A. S., Ensor, D. S., and Sparks, L. E.(1984). “Prediction of the opacity of detached plumes formed by condensation of vapors.”Atmospheric Environment, 18(2), 435–444.
4.
Damle, A. S., Ensor, D. S., and Sparks, L. E. (1987). “Options for controlling condensation aerosols to meet opacity standards.”J. Air Pollution Control Assn. 37(8), 925–933.
5.
Dellinger, B., Grotecloss, G., and Fortune, C. R.(1980). “Sulfur dioxide oxidization and plume formation at cement kilns.”Envir. Sci. and Technol., 14(10), 1244–1249.
6.
Dietz, R. N., Wieser, R. F., and Newman, L. (1978). “Operating parameters affecting sulfate emissions from oil-fired power unit.”Workshop Proc. on Primary Sulfate Emissions from Combustion Sources, Vol. 2, Characterization: EPA-600/9-78-020b, NTIS PB 287437, Envir. Protection Agency, Washington, D.C.
7.
Goklany, I. M., Hoffnagle, G. F., and Brackbill, E. A. (1984). “Acid and total primary sulfates: development of emission factors for major stationary sources.”J. Air Pollution Control Assn. 31(2), 124–134.
8.
Homolya, J. B., and Cheney, J. L. (1978). “An assessment of sulfuric acid and sulfate emissions from the combustion of fossil fuels.”Workshop Proc. on Primary Sulfate Emissions from Combustion Sources, Vol. 2, Characterization, EPA-600/9-78-020b, NTIS PB 287437. Envir. Protection Agency, Washington, D.C.
9.
Homolya, J. B., and Lambert, S.(1981). “Characterization of sulfur emission from nonutility boiler firing low-S residual oils in New York City.”J. Air Pollution Control Assn., 31(2), 139–143.
10.
Howes, J. E. Jr. (1978). “Sulfur oxides measurements of utility power plant emissions.”Workshop Proc. on Primary Sulfate Emissions from Combustion Sources, EPA-600/9-78-020b. Envir. Protection Agency, Washington, D.C. 2, 87–98.
11.
Hunter, S. C., and Engel, P. K. (1978). “Sulfur oxides emissions from boilers, turbines, and industrial combustion equipment.”Workshop Proc. on Primary Sulfate Emissions from Combustion Sources, Vol. 2, Characterization: EPA-600/9-78-020b, NTIS PB 287437, Envir. Protection Agency, Washington, D.C.
12.
Lee, K. T. (1987). “Development and application of microcomputer based model for acid plume opacity.”Proc., 80th Annu. Meeting of the Air Pollution Control. Assn., Air Pollution Control Assn., Pittsburgh, Pa., 87–106.
13.
Lodge, J. E. Jr., ed. (1989). Methods of air sampling and analysis, 3rd Ed., Lewis Publishers Inc., Chelsea, Mich.
14.
Nader, J. S., and Conner, W. D. (1978). “Impact of sulfuric acid emissions on plume opacity.”Workshop Proc. on Primary Sulfate Emissions from Combustion Sources, Vol. 2, Characterization; EPA-600/9-78-020b, NTIS PB 287437. Envir. Protection Agency, Washington, D.C.
15.
Nader, J. S.(1978). “Workshop on primary sulfate emissions.”J. Air Pollution Control Assn., 28(10), 1002–1005.
16.
Nader, J. S., and Conner, W. D. (1979). “Impact of sulfuric acid emissions on plume opacity.”Proc. of Second Symp. on Transfer and Utilization of Particulate Control Technol. Vol. IV; Rep. EPA-600/7-79-044d, NTIS PB 295229, Envir. Protection Agency, Washington, D.C.
17.
Pilat, M. J., Ensor, D. S, and Bosch, J. C.(1970). “Source test cascade impactor.”Atmospheric Environment, 4(6), 671–675.
18.
Pilat, M. J., Raemhild, G. A., Powel, E. B., Fioretti, G. M., and Meyer, D. A. (1978). “Development of a cascade impactor system for sampling 0.02 to 20 micron diameter particles.”EP-844, Vol. 1, Electr. Power Res. Inst., Palo Alto, Calif.
19.
Pilat, M. J., and Wilder, J. M.(1983). “Opacity of monodisperse sulfuric acid aerosols.”Atmospheric Environment, 17(9), 1825–1835.
20.
Steig, T. W., and Pilat, M. J.(1983). “Comparison of opacities measured by portable and cross-stack transmissionmeters at a coal-fired power plant.”Atmospheric Environment, 17(1), 1–9.
21.
Thielke, J. F., and Pilat, M. J.(1978). “Plume opacity related to particle mass concentration and size distribution.”Atmospheric Environment, 12(12), 2439–2447.
22.
U.S. Environmental Protection Agency (U.S. EPA). (1971). “Protection of environment, part 60—standards for performance for new stationary sources, appendix: test methods method 5, determination of particulate emissions from stationary sources. Fed. Reg., Washington, D.C., 36, 888.
23.
Wilder, J. M., and Pilat, M. J.(1983). “Calculated droplet size distributions and opacities of condensed sulfuric acid aerosols.”J. Air Pollution Control Assn., 33(9), 858–863.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 123Issue 7July 1997
Pages: 698 - 703

History

Published online: Jul 1, 1997
Published in print: Jul 1997

Permissions

Request permissions for this article.

Authors

Affiliations

J. C. Lou
Assoc. Prof., Inst. of Envir. Engrg., Nat. Sun Yat-Sen Univ., Kaohsiung, Taiwah, ROC.
M. Lee
Grad. Student, Inst. of Envir. Engrg., Nat. Sun Yat-Sen Univ., Kaohsiung, Taiwan, ROC.
K. S. Chen
Prof., Inst. of Envir. Engrg., Nat. Sun Yat-Sen. Univ., Kaohsiung, Taiwan, ROC.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share