TECHNICAL PAPERS
May 1, 1997

Zero-Valent Iron Colloid Emplacement in Sand Columns

Publication: Journal of Environmental Engineering
Volume 123, Issue 5

Abstract

Studies were conducted to evaluate a novel approach of emplacing chemically reactive barriers composed of zero-valent iron (Fe0) by injecting suspensions of colloidal-size Fe0 particles into porous media. The specific objective of this study was to evaluate the effect of influent colloid concentration, rate, and volume of colloidal suspensions on Fe0 colloid emplacement in sand columns. Relatively even distributions of Fe0 throughout a sand column were obtained at low influent colloid concentrations and high injection rates. As the concentration of influent suspension was increased, a point was reached beyond which a significant increase in the filtration of Fe0 particles near the front of the column was observed. This point was also found to occur at lower influent colloid concentrations as the injection rate was decreased, i.e., there was an interactive effect of influent colloid concentration and injection rate on the extent of filtration that occurred near the front of the column. As the volume of the colloidal suspension injected into the column was increased, the distribution of Fe0 colloids within the column became increasingly even.

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References

1.
Agrawal, A., Tratnyek, P. G., Stoffyn-Egli, P., and Liang, L.(1995). “Processes affecting nitro reduction by iron metal: mineralogical consequences of precipitation in aqueous carbonate environments.”Preprint of Extended Abstracts from the 209th ACS Nat. Meeting, Anaheim, Calif., 35(1), 720–723.
2.
American Chemical Society (ACS).(1995). “Contaminant remediation with zero-valent metals: session.”Preprint of Extended Abstracts from the 209th ACS Nat. Meeting, Anaheim, Calif., 35(1), 689–835.
3.
Cantrell, K. J., Martin, P. F., and Szecsody, J. E. (1994). “Clinoptilolite as an in situ permeable barrier to strontium migration in ground water.”In-situ remediation: scientific basis for current and future technologies, G. W. Gee and N. R. Wing, eds., Battelle Press, Columbus, Ohio, 839–850.
4.
Cantrell, K. J., Kaplan, D. I., and Wietsma, T. W.(1995). “Zero-valent iron for the in-situ remediation of selected metals in groundwater.”Haz. Waste Technol., 42(2), 201–212.
5.
Gillham, R. W., and O'Hannesin, S. F.(1994). “Enhanced degradation of halogenated aliphatics by zero-valent iron.”Ground Water, 32(6), 958–967.
6.
Gillham, R. W., Blowes, D. W., Ptacek, C. J., and O'Hannesin, S. F. (1994). “Use of zero-valent metals in in-situ remediation of contaminated ground water.”In-situ remediation: Scientific basis for current and future technologies, G. W. Gee and N. R. Wing, eds., Battelle Press, Columbus, Ohio, 913–930.
7.
Gould, J. P.(1982). “The kinetics of hexavalent chromium reduction by metallic iron.”Water Resour., 16(6), 871–877.
8.
Gould, J. P., Masingale, M. Y., and Miller, M.(1984). “Recovery of silver and mercury from COD samples by iron cementation.”J. Wat. Pollution Control Fed., 56, 280–286.
9.
Heertjes, P. M., and Lerk, C. F. (1967). “The functioning of deep-bed filters part II: the filtration of flocculated suspensions.”Trans. Instn. Chemical Engrs., 45, T138–T145.
10.
Kaplan, D. I., Cantrell, K. J., and Wietsma, T. W. (1994). “Formation of a barrier to groundwater contaminants by the injection of zero-valent iron colloids: suspension properties.”In-situ remediation: scientific basis for current and future technologies, G. W. Gee and N. R. Wing, eds., Battelle Press, Columbia, Ohio, 820–838.
11.
Kaplan, D. I., Cantrell, K. J., Wietsma, T. W., and Potter, M. A.(1996). “Formation of a chemical barrier with zero-valent iron colloids for groundwater remediation.”J. Envir. Quality, 25, 1086–1094.
12.
Keely, J. F.(1984). “Optimizing pumping strategies for contaminant studies and remedial actions.”Ground Water Monitoring Rev., 4(3), 63–74.
13.
Kim, B. J., Gee, C. S., Bandy, J. T., and Huang, C. S.(1991). “Hazardous waste treatment technologies.”Res. J. WPCF, 63(4), 501–509.
14.
Mackenzie, P. D., Baghel, S. S., Eykholt, G. R., Horney, D. P., Salvo, J. J., and Sivavec, T. M.(1995). “Pilot-scale demonstration of reductive dechlorination of chlorinated ethenes by iron metal.”Preprint of Extended Abstracts from the 209th ACS Nat. Meeting, Anaheim, Calif., 35(1), 796–799.
15.
Matheson, L. J., and Tratnyek, P. G.(1994). “Reductive dehalogenation of chlorinated methanes by iron metal.”Envir. Sci. Technol., 28(12), 2045–2053.
16.
Morrison, S. J., and Spangler, R. R.(1993). “Chemical barriers for controlling groundwater contamination.”Envir. Progress, 12(3), 175–181.
17.
O'Hannesin, S. F., and Gillham, R. W. (1992). “A permeable reaction wall for in situ degradation of halogenated organic compounds.”Proc., 45th Can. Geotech. Soc. Conf., Toronto, Ont., Canada, 1–9.
18.
Olson, R. V., and Ellis, Jr., R. (1982). “Iron.”Methods of soil analysis, part 2, 2nd Ed., A. L. Page et al., eds., Am. Soc. of Agronomy, Madison, Wis., 301–312.
19.
Orth, W. C., and Gillham, R. W.(1996). “Dechlorination of trichloroethene in aqueous solution using Fe0.”Envir. Sci. Technol., 30(1), 66–71.
20.
Patterson, J. W., and Jancuk, W. A. (1981). “Cementation treatment of copper in wastewater.”Proc., 35th Purdue Industrial Waste Conf., Ann Arbor Science, Ann Arbor, Mich., 853–855.
21.
Pulgarin, C., Schwitzguebel, J. P., Peringer, P., Pajonk, G. M., Bandara, J., and Kiwi, J. T. (1995). “Abiotic degradation of atrazine on zero-valent iron activated by visible light.”Preprint of Extended Abstracts from the 209th ACS Nat. Meeting, Anaheim, Calif., 35(1), 767– 770.
22.
Puls, R. W., Powell, R. M., and Paul, C. J. (1995). “In situ remediation of ground water contaminated with chromate and chlorinated solvents using zero-valent iron: a field study.”Preprint of Extended Abstracts from the 209th ACS Nat. Meeting, Anaheim, Calif., 35(1), 788– 791.
23.
Reardon, E. J.(1995). “Anaerobic corrosion of granular iron: measurement and interpretation of hydrogen evolution rates.”Envir. Sci. Technol., 29(12), 2936–2945.
24.
Roberts, A. L., Totten, L. A., Arnold, W. A., Burris, D. R., and Campbell, T. J.(1996). “Reductive elimination of chlorinated ethylenes by zero-valent metals.”Envir. Sci. Technol., 30(8), 2654–2659.
25.
Schuckrow, A. J., Pajak, A. P., and Touhill, C. J. (1982). Hazardous waste leachate management manual. Noyes Data Corporation, Park Ridge, N.J.
26.
Siantar, D. P., Schreier, C. G., and Reinhard, M.(1995). “Transformation of the pesticide 1,2-dibromo-3-chloropropane (DBCP) and nitrate by iron powder and by H2/Pd/Al2O3.”Preprint of Extended Abstracts from the 209th ACS Nat. Meeting, Anaheim, Calif., 35(1), 745–748.
27.
Spooner, P. A., Wetzel, R. S., Spooner, C. E., Furman, C. A., and Tokarski, E. F. (1985). Slurry trench construction for pollution migration control. Noyes Data Corporation, Park Ridge, N.J.
28.
Thomson, B. M., and Shelton, S. P. (1988). “Permeable barriers: a new alternative for treatment of contaminated ground waters.”Proc. FOCUS Conf. on Southwestern Ground Water Issues, Albuquerque, N.M., 441–453.
29.
Tolman, A. L., Ballestero Jr., A. P., Beck Jr., W. W., and Emrich, G. H. (1978). “Guidance manual for minimizing pollution from waste disposal sites.”EPA-600 12-78-142, U.S. Envir. Protection Agency, Cincinnati, Ohio.
30.
Vogan, J. L.(1995). “Site specific degradation of VOCs in groundwater using zero valent iron.”Preprint of Extended Abstracts from the 209th ACS Nat. Meeting, Anaheim, Calif., 35(1), 800–804.
31.
Wilson, E. K.(1995). “Zero-valent metals provide possible solution to groundwater problems.”Chemical Engrg. News, 73(3), 19–22.
32.
Yamane, C. L., Warner, S. D., Gallinatti, J. D., Szerdy, F. S., Delfino, T. A., Hankins, D. A., and Vogan, J. L.(1995). “Installation of a subsurface groundwater treatment wall composed of granular zero-valent iron.”Preprint of Extended Abstracts from the 209th ACS Nat. Meeting, Anaheim, Calif., 35(1), 792–975.

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Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 123Issue 5May 1997
Pages: 499 - 505

History

Published online: May 1, 1997
Published in print: May 1997

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Authors

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K. J. Cantrell
Sr. Res. Sci., Battelle Memorial Inst., Pacific Northwest Nat. Lab., P.O. Box 999, Mailstop K6-81, Richland, WA 99352.
D. I. Kaplan
Sr. Res. Sci., Battelle Memorial Inst., Pacific Northwest Nat. Lab., P.O. Box 999, Mailstop K6-81, Richland, WA.

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