Weathering Rates of Marble in Laboratory and Outdoor Conditions
Publication: Journal of Environmental Engineering
Volume 122, Issue 9
Abstract
In the modern urban atmosphere SO2 and NO2 attack calcite (CaCO3) in marble exposed at rain-sheltered surfaces creating largely gypsum (CaSO4⋅2H2O) crusts that eventually exfoliate. In combination with CO2 these gases erode the marble at unsheltered surfaces. We report the development of mathematical models to predict the rate of growth of crust and the rate of surface recession. To determine the rate of growth of crust the kinetic rate constant, diffusion rate, and the order of reaction were determined by the application of the shrinking-core model applied to data generated in laboratory experiments. Based on these parameters and average ambient levels of 10 parts per billion (ppb) SO2 and 25 ppb NO2 in Louisville, Ky., the rate of crust formation for this metro area was calculated to be 1.8 μm in the first year. However, the rate of recession was modeled from data obtained by exposing marble slabs to rainfalls. A surface recession of 15 μm/yr was calculated. The models predicted well the rate of growth of crust observed at several sites in Louisville and the predicted surface recession compared well with values reported in the literature.
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Information & Authors
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Published In
Journal of Environmental Engineering
Volume 122 • Issue 9 • September 1996
Pages: 856 - 863
Copyright
Copyright © 1996 American Society of Civil Engineers.
History
Published online: Sep 1, 1996
Published in print: Sep 1996
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