TECHNICAL PAPERS
Sep 1, 1995

Regeneration of Granular Activated Carbon (GAC) Columns Used for Removal of Lead

Publication: Journal of Environmental Engineering
Volume 121, Issue 9

Abstract

Granular activated carbon (GAC) columns that were used for Pb removal were regenerated using several regeneration schemes. Acid type (HCl and HNO 3 ), regenerant concentration (0.1 N or 1 N), acid reuse, and a NaOH-only rinse were studied. Column performance was assessed using the Pb surface loading (X/M) at exhaustion, and the number of bed volumes (BVs) treated at breakthrough and exhaustion. The type of acid used did not affect column performance. Increasing the regenerant concentrations from 0.1 N to 1 N increased the surface loading at exhaustion and the BVs treated at breakthrough by 20% and 25%, respectively. Acid reuse did not significantly affect column performance, although desorption efficiencies decreased with the run number. The insensitivity of Pb removal to desorption efficiency indicates that the dominant removal mechanism is precipitation on the carbon surface or in the carbon pore, not adsorption. All measures of column performance deteriorated slightly when base-only regeneration was employed. However, column performance for the 1 N NaOH experiments were similar to the 0.1 N HCl-0.1 N NaOH studies.

Get full access to this article

View all available purchase options and get full access to this article.

References

1.
Arulanantham, A., Balasubramanian, N., and Ramakrishna, T. V.(1989). “Coconut shell carbon for treatment of cadmium and lead containing wastewater.”Metal Finishing, 87, 51–55.
2.
Arunachalam, S. A. (1993). “Removal of lead and cadmium using granular activated carbon (GAC) columns,” MSc thesis, Dept. of Civ. and Envir. Engrg., West Virginia Univ., Morgantown, W. Va.
3.
Corapcioglu, M. O., and Huang, C. P.(1987). “The adsorption of heavy metals onto hydrous activated carbon.”Water Res., 9(9), 1031–1044.
4.
Farley, K. J., Dzomback, D. A., and Morel, F. M. M.(1985). “A surface precipitation model for the sorption of cations on metal oxides.”J. Colloid and Interface Sci., 106(1), 226–242.
5.
Garcia, D. (1995). “Modeling of Pb (II) adsorption by activated carbon,” MSc thesis, Dept. of Civ. and Envir. Engrg., West Virginia Univ., Morgantown, W. Va.
6.
Huang, C. P., and Ostovic, F. B.(1978). “Removal of cadmium (II) by activated carbon adsorption.”J. Envir. Engrg., ASCE, 104(5), 863–878.
7.
Huang, C. P., and Smith, E. H. (1981), “Removal of Cd(II) by from plating wastewater by an activated carbon process.”Chemistry in water reuse, Vol. 2, W. J. Cooper, ed., Ann Arbor Science Publishers, Inc., Ann Arbor, Mich.
8.
Huang, C. P., and Wirth, P. K.(1982). “Activated carbon for the treatment of cadmium wastewater.”J. Envir. Engrg., ASCE, 108(6), 1280–1299.
9.
Noh, J. S., and Schwarz, J. A. (1990). “Effect of HNO 3 treatment on the surface of activated carbon.”Carbon, 28(5), 675–683.
10.
Reed, B. E., and Matsumoto, M. R.(1993). “Modeling cadmium adsorption in single and binary adsorbent (powdered activated carbon) systems.”J. Envir. Engrg., ASCE, 119(2), 332–348.
11.
Reed, B. E. (1994) “Identification of removal mechanisms for lead in granular activated carbon (GAC) columns.”Separation Sci. and Technol., 29(1), 1529–1551.
12.
Reed, B. E., and Arunachalam, S.(1994). “Use of granular activated carbon columns for lead removal.”J. Envir. Engrg., ASCE, 120(2), 416–436.
13.
Reed, B. E., Arunachalam, S., and Thomas, B. B.(1994). “Removal of lead and cadmium from aqueous waste streams using granular activated carbon (GAC) columns.”Envir. Progress, 13(1), 60–64.
14.
Stumm, W., and Morgan, J. (1981). Aquatic chemistry, John Wiley & Sons, Inc., New York, N.Y.

Information & Authors

Information

Published In

Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 121Issue 9September 1995
Pages: 653 - 662

History

Published online: Sep 1, 1995
Published in print: Sep 1995

Permissions

Request permissions for this article.

Authors

Affiliations

B. E. Reed, Associate Member, ASCE
Assoc. Prof., Dept. of Civ. and Envir. Engrg., West Virginia Univ., Morgantown, WV 26103.
J. Robertson
Envir. Engr., Arch of West Virginia, Div. of Apogee Coal Co., Yolyn, WV 25654.
M. Jamil
Grad. Res. Asst., Dept. of Civ. and Envir. Engrg., West Virginia Univ., Morgantown, WV.

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

Cited by

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share