TECHNICAL PAPERS
Aug 1, 1995

Cleaning Contaminated Soil Using Electrical Heating and Air Stripping

Publication: Journal of Environmental Engineering
Volume 121, Issue 8

Abstract

In the summer of 1992, a proof-of-concept demonstration of direct electrical heating and air stripping was conducted for enhancing the removal of a volatile organic contaminant, trichloroethylene (TCE), from soil. Six electrodes were buried in shallow boreholes so that a target region 6.1 m in diameter and 3.05 m in height was heated by ohmic dissipation of power-line–frequency electrical currents supplied by a diesel generator. Air stripping of TCE contamination from the same region was accomplished from a single well at the center of the heated volume. The electrical energy used during the demonstration was 3.46 × 10 10 J (9,600 kWs˙h), and the temperature of the extracted air rose from 16°C to 38°C. An energy balance shows that the input energy is consistent with the temperature rise in the target volume and the amount of water vaporized at the electrodes. Prior to heating, the TCE concentration in the vapor decreased from about 80 parts per million by volume (ppm V ) to around 60 ppm V . As soon as electrical heating started, TCE concentrations began to increase. Some concentration data were lost shortly after electrical heating began. After the system was repaired, the TCE concentration fell rapidly from about 140 ppm V to 5 ppm V over a period of about 25 days. A simple two-dimensional model for calculation of heating rates is also presented and verified experimentally. Finally some of the operational and safety issues associated with electrical heating are discussed.

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References

1.
Agrelot, J. C., Malot, J. J., and Visser, M. J. (1984). “Vacuum: defense system for ground water VOC contamination.”Proc., 5th Nat. Symp. on Aquifer Restoration and Ground Water Monitoring, 485–494.
2.
Aines, R. D., et al. (1992). “Dynamic underground stripping demonstration project interim progress report, 1991.”Rep., UCRL-ID-109906, Lawrence Livermore Nat. Lab., Livermore, Calif.
3.
Batchelder, G. V., Panazeri, W. A., and Phillips, H. T. (1986). “Soil ventilation for the removal of adsorbed liquid hydrocarbons in the subsurface.”Proc., NWWA/API Conf. on Petroleum Hydrocarbons and Organic Chemicals in Ground Water.
4.
Bergsman, T. M., Roberts, J. S., Lessor, D. L., and Heath, W. O. (1993). “Field test of six phase heating and evaluation of engineering design code.”Proc., Symp. on Waste Mgmt., 61–865.
5.
Bergsman, T. M. (1993). “Six-phase soil heating to enhance removal of contaminants.”Proc., Fifth Nat. Technol. Information Exchange (TIE) Workshop.
6.
Blake, S. B., and Gates, M. M. (1986). “Vacuum enhanced hydrocarbon recovery: A case study.”Proc., NWWA/API Conf. on Petroleum Hydrocarbons and Organic Chemicals in Ground Water.
7.
Brown, R. A., Hoag, G. E., and Norris, R. D. (1987). “The remediation game: Pump, dig, or treat.”Proc., Annu. Conf., Water Pollution Control Federation, Alexandria, Va.
8.
Bryn, S. M., Landgraf, R. K., and Booth, S. E. (1990). “Draft remedial investigation and feasibility study for the Lawrence Livermore National Laboratory Site 300 Building 834 Complex.”Rep., UCRL-ID-103963, Lawrence Livermore Nat. Lab., Livermore, Calif.
9.
Buettner, H. M., Daily, W. D., and Ramirez, A. L. (1992). “Enhancing cyclic steam injection and vapor extraction of volatile organic compounds in soils with electrical heating.”Proc., Nuclear and Hazardous Waste Mgmt., Spectrum '92, 1321–1324.
10.
Buettner, H. M. (1994). “The electrical soil heating preheat phase of dynamic underground stripping.”Dynamic Underground Stripping Project: LLNL Gasoline Spill Demonstration Rep., Vol. 2, UCRL-ID-116964, Lawrence Livermore Nat. Lab., Livermore, Calif., 3-135–3-186.
11.
Carslaw, H. S., and Jaeger, J. C. (1959). Conduction of heat in solids, 2nd Ed., Oxford Univ. Press, New York, N.Y.
12.
Chute, F. S., and Vermeulen, F. E. (1988). “Present and potential applications of electromagnetic heating in the In-situ recovery of oil.”AOSTRA J. Res., 4(1), 19–33.
13.
CRC handbook of chemistry and physics. (1990). 70th Ed., R. C. Weast, ed. in chief.
14.
Crow, W. L., Anderson, E. P., and Minugh, E. M.(1987). “Subsurface venting of vapors emanating from hydrocarbon product on groundwater.”Groundwater Monitoring Rev., 7(1), 51–57.
15.
Daley, P. F.(1992). “Automated monitoring of a soil vapor remediation system.”Scientific Computing and Automation, 8(6), 23–28.
16.
DePaoli, D. W., and Hutzler, N. J. (1991). “Field test of enhancement of soil venting by heating.”Draft Rep., Oak Ridge Nat. Lab., Oak Ridge, Tenn., 1–20.
17.
Dev, H., Sresty, G. C., Bridges, J. E., and Downey, D. (1988). “Field test of the radio frequency in-situ soil decontamination process.”Proc., Superfund '88 Ninth Nat. Conf.
18.
Fall, E. W., and Pickens, W. E. (1988). “In-situ hydrocarbon extraction—a case study.”Proc., FOCUS Conf. on Southwestern Ground Water Issues, 415–437.
19.
Heath, W. O., Roberts, J. S., Lessor, D. L., and Bergsman, T. M. (1992). “Engineering scaleup of electrical soil heating for soil decontamination.”Proc., Nuclear and Hazardous Waste Mgmt., Spectrum '92, 1194–1199.
20.
Hoag, G. E., Baehr, A. L., and Marley, M. C. (1987). “In situ recovery of hydrocarbon contaminated soil utilizing the induced soil venting process.”Waste Management of Hazardous and Toxic Wastes in the Process Industries, S. T. Kolaczkowski and B. D. Crittenden, eds., Elsevier Appl. Sci., London, England, 273–289.
21.
Johnson, R. L. (1989). “Soil venting for remediation of subsurface gasoline releases: Implications of subsurface gasoline transport on the effectiveness of soil vacuum extraction.”Proc., Petroleum Hydrocarbons and Organic Chemicals in Ground Water: Prevention, Detection and Restoration Conf. and Exposition, Nat. Water Well Assoc. and Am. Petroleum Inst., Houston, Tex.
22.
Johnson, P. C., Kemblowski, M. W., and Colthart, J. D.(1990). “Quantitative analysis for the cleanup of hydrocarbon-contaminated soils by in-situ venting.”Ground Water, 28(3), 413–429.
23.
Keller, G. V., and Frischknecht, F. C. (1966). Electrical methods in geophysical prospecting . Pergamon Press, Oxford, England.
24.
Lingineni, S., and Dhir, V. K.(1992). “Modeling of soil venting processes to remediate unsaturated soils.”J. Envir. Engrg., ASCE, 118(1), 135–152.
25.
Marley, M. C., and Hoag, G. E. (1984). “Induced soil venting for the recovery/restoration of gasoline hydrocarbons in the vadose zone.”Proc., NWWA/API Conf. on Petroleum Hydrocarbons and Organic Chemicals in Ground Water, 473–501.
26.
Massmann, J. W.(1989). “Applying groundwater flow models in vapor extraction system design.”J. Envir. Engrg. Div., ASCE, 115(1), 129–149.
27.
Olhoeft, G. R.(1985). “Low frequency electrical properties.”Geophysics, 50(12), 2492–2503.
28.
Siegel, W. H. (1993). “Cleanup of groundwater contaminated with gasoline by using the dynamic underground stripping process.”Operational Safety Procedure, L-52, Lawrence Livermore Nat. Lab., Livermore, Calif.
29.
Thornton, J. S., Montgomery, R. E., Voynick, T., and Wootan, W. L. (1984). “Removal of gasoline vapor from aquifers by forced venting.”Proc., Hazardous Mat. Spills Conf., J. Ludwigson, ed.
30.
Thornton, J. S., and Wootan, W. L. Jr. (1982). “Venting for the removal of hydrocarbon vapors from gasoline contaminated soil.”J. Environ. Sci. Health, A17(1), 31–44.
31.
Wilson, R. E., Montgomery, R. E., and Sheller, M. R.(1987). “A mathematical model for removing volatile subsurface hydrocarbons by miscible displacement.”Water, Air and Soil Pollution, 33, 231–255.

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 121Issue 8August 1995
Pages: 580 - 589

History

Published online: Aug 1, 1995
Published in print: Aug 1995

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Authors

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H. Michael Buettner
Group Leader, Electronics Engrg. Dept., Lawrence Livermore Nat. Lab., L-156, 7000 East Ave., Livermore, CA 94550.
William D. Daily
Proj. Engr., Electronics Engrg. Dept., Lawrence Livermore Nat. Lab., L-156, 7000 East Ave., Livermore, CA.

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