Kinetics of Manganese(II) Oxidation with Chlorine
Publication: Journal of Environmental Engineering
Volume 117, Issue 3
Abstract
Kinetics of manganese(II) oxidation with chlorine as well as the effects of chlorine dose and the presence of complexing agents are evaluated. Mn(II) oxidation is facilitated by excess chlorine at An autocatalytic model analogous to that for Mn(II) oxidation by is developed in which the major mechanism for Mn(II) removal is heterogeneous Mn(II) adsorption onto newly precipitated The same model also describes the effects of pH and the external addition of on Mn(II) removal. The model applications in water treatment and acid mine drainage control for Mn(II) removal with chlorine are discussed. Mn(II) oxygenation in the presence of equimolar ligand indicated the following: complete inhibition in the Mn‐ethylenediaminetetracetic acid (Mn‐EDTA) system, moderate inhibition in the Mn‐iminodiacetic acid (Mn‐IDA) system, and slight inhibition in the Mn‐glycine (Mn‐GLY) system. The degree of inhibition, similar to that previously found for Fe(II) oxidation, follows the Mn‐ligand complex affinity. However, Mn(II) removal in these systems occurs differently with chlorine as the oxidizing agent. Mn‐EDTA accelerates the reaction while both Mn‐IDA and Mn‐GLY retards the reaction. The catalytic effect of the Mn‐EDTA complex is discussed. Mn(II) oxidation kinetics in terms of complexation stability constant, ligand/Mn(II) ratio, and chlorine dose are described.
Get full access to this article
View all available purchase options and get full access to this article.
References
1.
Bailey, P. L., and Bishop, E. (1973). “Hydrolysis of cyanogen chlorite.” J. Chem. Soc. Dalton Trans., 9(9), 912–917.
2.
Beck, M. T., and Kling, O. (1961). “Reactivity of coordinated substances I. The oxidation of EDTA bound in the Cr(III) EDTA complex by permanganate ion.” Acta Chem. Scand., 15(3), 453–454.
3.
Bowers, A. R., and Huang, C. P. (1987). “Role of Fe(III) in metal adsorption by hydrous solids.” Water Res., 21(7), 757–764.
4.
Cameron, A. J., and Liss, P. S. (1984). “The stabilization of dissolved iron in fresh‐waters.” Water Res., 18(2), 179–185.
5.
Davies, S. H. R., and Morgan, J. J. (1989). “Manganese (II) oxidation kinetics on metal oxide surface.” J. Colloid Interface Sci., 129(1), 63–77.
6.
Eilbeck, W. T., and Mattock, G. (1987). Chemical processes in waste water treatment, Ellis Horwood, Chichester, West Sussex, England.
7.
Fair, H. M., Geyer, J. C., and Okun, D. A. (1968). Water and wastewater engineering. Vol. 2, John Wiley and Sons, Inc., New York, N.Y.
8.
Gardiner, J. (1976). “Complexation of trace metals by EDTA in natural waters.” Water Res., 10(6), 507–514.
9.
Gilbert, E., and Hoffmann‐Glewe, S. (1990). “Ozonation of EDTA in aqueous solution, influence of pH values and metal ions.” Water Res., 24(1), 39–44.
10.
Gould, J. D., Richards, J. T., and Miles, M. G. (1984). “The kinetics and products of uracil chlorination.” Water Res., 18(2), 205–212.
11.
Hem, J. D. (1963). “Chemical equilibria and rate of manganese oxidation.” U.S. Geological Survey Water Supply Papers, 1667‐A, U.S. Geological Survey, Washington, D.C.
12.
Huang, C. P., and Quist, A. C. (1983). “The dissolution of a manganese ore in dilute aqueous solution.” Envir. Int., 9(5), 379–389.
13.
Kawashima, M., Tainka, Y., Hori, T., Koyama, M., and Takamatsu, T. (1986). “Phosphate adsorption onto hydrous Mn02 in the presence of divalent cations.” Water Res., 20(4), 471–476.
14.
Knocke, W. R., Holhn, R. C., and Sinsabangh, R. L. (1987). “Using alternative oxidants to removal dissolved manganese from waters laden with organics.” J. Am. Water Works Assoc., 79(3), 75–79.
15.
Kurimura, Y., Ochiai, R., and Matsuura, N. (1968). “Oxygen oxidation of ferrous ions induced by chelation.” Bull. Chem. Soc. Japan, 41(10), 2234–2239.
16.
Lambert, D. G., and Jones, M. M. (1966). “Oxidation of some chelating agents and complexes with alkaline ferricyanide.” J. Am. Chem. Soc., 88(20), 4615–4618.
17.
Martell, A. E., and Smith, R. M. (1982). Critical stability constants, Vol. 5: First supplement. Plenum Press, New York, N.Y.
18.
Mathews, E. R. (1947). “Iron and manganese removal by free residual chlorination.” J. Am. Water Works Assoc., 39(7), 680–686.
19.
Morgan, J. J. (1967a). “Application and limitations of chemical thermodynamics in water systems.” Equilibrium concepts in natural water systems, R. F. Gould, ed., American Chemical Society, Washington, D.C.
20.
Morgan, J. J. (1967b). “Chemical equilibria and kinetic properties of manganese in natural waters.” Principles and application in water chemistry, S. D. Faust and J. Hunter, eds., John Wiley and Sons, Inc., New York, N.Y.
21.
O'Connor, J. T. (1971). “Iron and manganese.” Water quality and treatment, McGraw‐Hill, New York, N.Y.
22.
Pankow, J. F., and Morgan, J. J. (1981). “Kinetics of the aquatic environment.” Envir. Sci. Tech., 15(11), 1306–1313.
23.
Rav‐Acha, C., and Blits, R. (1985). “The different reaction mechanisms by which and react with PAH.” Water Res., 19(10), 1273–1281.
24.
Rosenblatt, D. H., Hull, L. A., DeLuca, D. C., Davis, G. T., and Weglein, R. C. (1967). “Oxidation of amines. II. Substituent effects in chlorine dioxide oxidation.” J. Am. Chem. Soc., 89(5), 1158–1163.
25.
Sung, W., and Morgan, J. J. (1981). “Oxidative removal of Mn(II) from solution catalyzed by the a‐FeOOH surface.” Geochimica et. Cosmochimica Acta, 45(12), 2377–2383.
26.
Theis, T. L., and Singer, P. C. (1974). “Complexation of iron(II) by organic matter and its effect on iron(II) oxygenation.” Envir. Sci. Tech., 8(6), 569–573.
27.
White, G. C. (1986). The handbook of chlorination, 2nd Ed., Van Nostrand Reinhold, New York, N.Y.
28.
Wilson, D. E. (1980). “Surface and complexation effects on the rate of Mn(II) oxidation in natural waters.” Geochimica et. Cosmochimica Acta, 44(9), 1311–1317.
Information & Authors
Information
Published In
Journal of Environmental Engineering
Volume 117 • Issue 3 • May 1991
Pages: 359 - 374
Copyright
Copyright © 1991 ASCE.
History
Published online: May 1, 1991
Published in print: May 1991
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.