TECHNICAL PAPERS
Dec 1, 1984

Some Considerations on Iron Removal

Publication: Journal of Environmental Engineering
Volume 110, Issue 6

Abstract

The common technique for the control and removal of iron consists of oxidation followed by solid/liquid separation. The effects of ionic strength and chloride concentration on the oxidation kinetics of ferrous iron in the mg/L range by dissolved oxygen are reported here. The rate constant at 25 °C in infinitely dilute solution is about 6×1013M-2atm-1min-1 and in seawater‐like conditions, 4×1012M-2atm-1min-1. With atmospheric partial pressures of oxygen and pH>6, the chemical half‐life of ferrous iron is on the order of minutes to hours. The particle size distribution of some ferric oxyhydroxide precipitates are reported. The use of other oxidants such as chlorine and potassium permanganate versus oxygen is reviewed.

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Go to Journal of Environmental Engineering
Journal of Environmental Engineering
Volume 110Issue 6December 1984
Pages: 1048 - 1061

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Published online: Dec 1, 1984
Published in print: Dec 1984

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Authors

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Windsor Sung
Asst. Prof., Dept. of Civ. Engrg., Univ. of New Hampshire, Durham, N.H. 03824
Eugene J. Forbes
Grad. Research Asst., Dept. of Civ. Engrg., Univ. of New Hampshire, Durham, N.H. 03824

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