Impact of Graphene on Microstructure and Compressive Strength of Cement Mortars Utilizing Two Different Dispersion Methods
Publication: Practice Periodical on Structural Design and Construction
Volume 29, Issue 1
Abstract
Carbon-based nanomaterials are currently used to reinforce cement-based composite materials based on their superior properties. However, the mechanical performance of the cement-based composite materials can be improved by achieving an effective dispersion of nanomaterials in the cement matrix. Hence, this study investigates the effect of the surfactant coating method with or without the help of ultrasonication to promote the use of graphene in cement mortars. The dosages of graphene materials used were 0.01%, 0.02%, 0.03%, and 0.04% by weight of cement. A commonly used polycarboxylate superplasticizer (PCE) was used as a dispersant agent of graphene with a surfactant-to-graphene weight ratio of . Dynamic light scattering (DLS) analysis was utilized to assess graphene aqueous suspensions and obtain the optimum surfactant-to-graphene weight ratio. In addition, compressive strength tests and scanning electron microscopic (SEM) micrographs were employed to verify the embedment and dispersion of graphene in the cement matrix. As a result, the 28-day compressive strength of the cement mortars containing graphene with 0.03% by weight of cement was enhanced by 17.5% and 13.7% for ultrasonication with surfactant coating and mechanical blending with surfactant coating employed as dispersion methods of graphene, respectively, compared to the control specimens. However, mechanical blending with surfactant coating is more convenient than ultrasonication with surfactant coating in terms of practicality and cost.
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Data Availability Statement
All data, models, or code generated or used during the study appear in the published article.
References
Anagnostopoulos, C. A. 2014. “Effect of different superplasticisers on the physical and mechanical properties of cement grouts.” Constr. Build. Mater. 50 (Jan): 162–168. https://doi.org/10.1016/j.conbuildmat.2013.09.050.
Arvidsson, R. 2017. “Review of environmental life cycle assessment studies of graphene production.” Adv. Mater. Lett. 8 (3): 187–195. https://doi.org/10.5185/amlett.2017.1413.
ASTM. 2006. Standard test method for sieve analysis of fine and coarse aggregates. ASTM C136–06. West Conshohocken, PA: ASTM International.
ASTM. 2020a. Standard specification for flow table for use in tests of hydraulic cement. ASTM C 230/C 230M–20. West Conshohocken, PA: ASTM International.
ASTM. 2020b. Standard test method for compressive strength of hydraulic cement mortars. ASTM C 109/C109M–20. West Conshohocken, PA: ASTM International.
ASTM. 2020c. Standard test method for flow of hydraulic cement mortar. ASTM C1437–20. West Conshohocken, PA: ASTM International.
Bai, S., L. Jiang, N. Xu, M. Jin, and S. Jiang. 2018. “Enhancement of mechanical and electrical properties of graphene/cement composite due to improved dispersion of graphene by addition of silica fume.” Constr. Build. Mater. 164 (Jan): 433–441. https://doi.org/10.1016/j.conbuildmat.2017.12.176.
Balandin, A. A., S. Ghosh, W. Bao, I. Calizo, D. Teweldebrhan, F. Miao, and C. N. Lau. 2008. “Superior thermal conductivity of single-layer graphene.” Nano Lett. 8 (3): 902–907. https://doi.org/10.1021/nl0731872.
Baquerizo, L. G., T. Matschei, K. L. Scrivener, M. Saeidpour, and L. Wadsö. 2015. “Hydration states of AFm cement phases.” Cem. Concr. Res. 73 (Jul): 143–157. https://doi.org/10.1016/j.cemconres.2015.02.011.
Bentur, A., and S. Mindess. 2007. Fibre reinforced cementitious composites. London: Taylor & Francis.
Bolotin, K. I., K. J. Sikes, Z. Jiang, M. Klima, G. Fudenberg, J. Hone, P. Kim, and H. L. Stormer. 2008. “Ultrahigh electron mobility in suspended graphene.” Solid State Commun. 146 (9–10): 351–355. https://doi.org/10.1016/j.ssc.2008.02.024.
Cao, M., C. Zhang, and J. Wei. 2013. “Microscopic reinforcement for cement based composite materials.” Constr. Build. Mater. 40 (Mar): 14–25. https://doi.org/10.1016/j.conbuildmat.2012.10.012.
Chakraborty, S., S. P. Kundu, A. Roy, B. Adhikari, and S. B. Majumder. 2013. “Effect of jute as fiber reinforcement controlling the hydration characteristics of cement matrix.” Ind. Eng. Chem. Res. 52 (3): 1252–1260. https://doi.org/10.1021/ie300607r.
Chuah, S., Z. Pan, J. G. Sanjayan, C. M. Wang, and W. H. Duan. 2014. “Nano reinforced cement and concrete composites and new perspective from graphene oxide.” Constr. Build. Mater. 73 (Dec): 113–124. https://doi.org/10.1016/j.conbuildmat.2014.09.040.
Dalla, P. T., I. Tragazikis, G. Trakakis, C. Galiotis, K. G. Dassios, and T. E. Matikas. 2021. “Multifunctional cement mortars enhanced with graphene nanoplatelets and carbon nanotubes.” Sensors 21 (3): 933. https://doi.org/10.3390/s21030933.
Dikin, D. A., S. Stankovich, E. J. Zimney, R. D. Piner, G. H. B. Dommett, G. Evmenenko, S. T. Nguyen, and R. S. Ruoff. 2007. “Preparation and characterization of graphene oxide paper.” Nature 448 (7152): 457–460. https://doi.org/10.1038/nature06016.
Ebrahimizadeh Abrishami, M., and V. Zahabi. 2016. “Reinforcing graphene oxide/cement composite with functionalizing group.” Bull. Mater. Sci. 39 (4): 1073–1078. https://doi.org/10.1007/s12034-016-1250-7.
Fernández, J. M., A. Duran, I. Navarro-Blasco, J. Lanas, R. Sirera, and J. I. Alvarez. 2013. “Influence of nanosilica and a polycarboxylate ether superplasticizer on the performance of lime mortars.” Cem. Concr. Res. 43 (1): 12–24. https://doi.org/10.1016/j.cemconres.2012.10.007.
Hammond, G., C. Jones, F. Lowrie, and P. Tse. 2011. Embodied carbon: The inventory of carbon and energy (ICE). Bracknell, UK: Building Services Research and Information Association.
Holschemacher, K., T. Mueller, and Y. Ribakov. 2010. “Effect of steel fibres on mechanical properties of high-strength concrete.” Mater. Des. 31 (5): 2604–2615. https://doi.org/10.1016/j.matdes.2009.11.025.
Indukuri, C. S. R., and R. Nerella. 2021. “Enhanced transport properties of graphene oxide based cement composite material.” J. Build. Eng. 37 (May): 102174. https://doi.org/10.1016/j.jobe.2021.102174.
Islam, M. F., E. Rojas, D. M. Bergey, A. T. Johnson, and A. G. Yodh. 2003. “High weight fraction surfactant solubilization of single-wall carbon nanotubes in water.” Nano Lett. 3 (2): 269–273. https://doi.org/10.1021/nl025924u.
Lee, C., X. Wei, J. W. Kysar, and J. Hone. 2008. “Measurement of the elastic properties and intrinsic strength of monolayer graphene.” Science 321 (5887): 385–388. https://doi.org/10.1126/science.1157996.
Lei, L., and J. Plank. 2012. “A concept for a polycarboxylate superplasticizer possessing enhanced clay tolerance.” Cem. Concr. Res. 42 (10): 1299–1306. https://doi.org/10.1016/j.cemconres.2012.07.001.
Li, G., J. B. Yuan, Y. H. Zhang, N. Zhang, and K. M. Liew. 2018. “Microstructure and mechanical performance of graphene reinforced cementitious composites.” Composites, Part A 114 (Nov): 188–195. https://doi.org/10.1016/j.compositesa.2018.08.026.
Liu, Z., C. Shi, Q. Shi, X. Tan, and W. Meng. 2022. “Recycling waste glass aggregate in concrete: Mitigation of alkali-silica reaction (ASR) by carbonation curing.” J. Cleaner Prod. 370 (Oct) 133545. https://doi.org/10.1016/j.jclepro.2022.133545.
Lv, S., J. Liu, T. Sun, Y. Ma, and Q. Zhou. 2014. “Effect of GO nanosheets on shapes of cement hydration crystals and their formation process.” Constr. Build. Mater. 64 (Aug): 231–239. https://doi.org/10.1016/j.conbuildmat.2014.04.061.
Lv, S., Y. Ma, C. Qiu, T. Sun, J. Liu, and Q. Zhou. 2013. “Effect of graphene oxide nanosheets of microstructure and mechanical properties of cement composites.” Constr. Build. Mater. 49 (Dec): 121–127. https://doi.org/10.1016/j.conbuildmat.2013.08.022.
Meng, W., and K. H. Khayat. 2016. “Mechanical properties of ultra-high-performance concrete enhanced with graphite nanoplatelets and carbon nanofibers.” Composites, Part B 107 (Dec): 113–122. https://doi.org/10.1016/j.compositesb.2016.09.069.
Mokhtar, M. M., S. A. Abo-El-Enein, M. Y. Hassaan, M. S. Morsy, and M. H. Khalil. 2017. “Mechanical performance, pore structure and micro-structural characteristics of graphene oxide nano platelets reinforced cement.” Constr. Build. Mater. 138 (Jun): 333–339. https://doi.org/10.1016/j.conbuildmat.2017.02.021.
Montes-Navajas, P., N. G. Asenjo, R. Santamaría, R. Menéndez, A. Corma, and H. García. 2013. “Surface area measurement of graphene oxide in aqueous solutions.” Langmuir 29 (44): 13443–13448. https://doi.org/10.1021/la4029904.
Novoselov, K. S., A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and A. A. Firsov. 2004. “Electric field effect in atomically thin carbon films supplementary.” Science 306 (5696): 666–669. https://doi.org/10.1126/science.aab1343.
Pan, Z., L. He, L. Qiu, A. H. Korayem, G. Li, J. W. Zhu, F. Collins, D. Li, W. H. Duan, and M. C. Wang. 2015. “Mechanical properties and microstructure of a graphene oxide-cement composite.” Cem. Concr. Compos. 58 (Aug): 140–147. https://doi.org/10.1016/j.cemconcomp.2015.02.001.
Papanikolaou, I., L. Ribeiro de Souza, C. Litina, and A. Al-Tabbaa. 2021. “Investigation of the dispersion of multi-layer graphene nanoplatelets in cement composites using different superplasticiser treatments.” Constr. Build. Mater. 293 (Jul): 123543. https://doi.org/10.1016/j.conbuildmat.2021.123543.
Peigney, A., C. Laurent, E. Flahaut, R. R. Bacsa, and A. Rousset. 2001. “Specific surface area of carbon nanotubes and bundles of carbon nanotubes.” Carbon 39 (4): 507–514. https://doi.org/10.1016/S0008-6223(00)00155-X.
Prince, W., M. Espagne, and P. C. Aitcin. 2003. “Ettringite formation: A crucial step in cement superplasticizer compatibility.” Cem. Concr. Res. 33 (5): 635–641. https://doi.org/10.1016/S0008-8846(02)01042-6.
Qureshi, T. S., and D. K. Panesar. 2020. “Nano reinforced cement paste composite with functionalized graphene and pristine graphene nanoplatelets.” Composites, Part B 197 (Sep): 108063. https://doi.org/10.1016/j.compositesb.2020.108063.
Rahal, K. N., and H. A. Rumaih. 2011. “Tests on reinforced concrete beams strengthened in shear using near surface mounted CFRP and steel bars.” Eng. Struct. 33 (1): 53–62. https://doi.org/10.1016/j.engstruct.2010.09.017.
Raki, L., J. Beaudoin, R. Alizadeh, J. Makar, and T. Sato. 2010. “Cement and concrete nanoscience and nanotechnology.” Materials 3 (2): 918–942. https://doi.org/10.3390/ma3020918.
Senff, L., D. Hotza, S. Lucas, V. M. Ferreira, and J. A. Labrincha. 2012. “Effect of nano- and nano- addition on the rheological behavior and the hardened properties of cement mortars.” Mater. Sci. Eng., A 532 (Jan): 354–361. https://doi.org/10.1016/j.msea.2011.10.102.
Sharma, S., and S. Arora. 2018. “Economical graphene reinforced fly ash cement composite made with recycled aggregates for improved sulphate resistance and mechanical performance.” Constr. Build. Mater. 162 (Feb): 608–612. https://doi.org/10.1016/j.conbuildmat.2017.12.027.
Sharma, S., and N. C. Kothiyal. 2015. “Influence of graphene oxide as dispersed phase in cement mortar matrix in defining the crystal patterns of cement hydrates and its effect on mechanical, microstructural and crystallization properties.” RSC Adv. 5 (65): 52642–52657. https://doi.org/10.1039/C5RA08078A.
Sixuan, H. U. A. N. G. 2012. “Multifunctional graphite nanoplatelets (GNP) reinforced cementitious composites.” Master’s theses, Dept. of Civil Engineering, National Univ. of Singapore.
Stankovich, S., D. A. Dikin, G. H. B. Dommett, K. M. Kohlhaas, E. J. Zimney, E. A. Stach, R. D. Piner, S. B. T. Nguyen, and R. S. Ruoff. 2006. “Graphene-based composite materials.” Nature 442 (7100): 282–286. https://doi.org/10.1038/nature04969.
Stynoski, P., P. Mondal, and C. Marsh. 2015. “Effects of silica additives on fracture properties of carbon nanotube and carbon fiber reinforced Portland cement mortar.” Cem. Concr. Compos. 55 (Jan): 232–240. https://doi.org/10.1016/j.cemconcomp.2014.08.005.
Tan, X., A. Abu-Obeidah, Y. Bao, H. Nassif, and W. Nasreddine. 2021. “Measurement and visualization of strains and cracks in CFRP post-tensioned fiber reinforced concrete beams using distributed fiber optic sensors.” Autom. Constr. 124 (Apr): 103604. https://doi.org/10.1016/j.autcon.2021.103604.
Tong, T., Z. Fan, Q. Liu, S. Wang, S. Tan, and Q. Yu. 2016. “Investigation of the effects of graphene and graphene oxide nanoplatelets on the micro- and macro-properties of cementitious materials.” Constr. Build. Mater. 106 (Mar): 102–114. https://doi.org/10.1016/j.conbuildmat.2015.12.092.
Tragazikis, I., K. G. Dassios, P. T. Dalla, D. A. Exarchos, and T. E. Matikas. 2019. “Acoustic emission investigation of the effect of graphene on the fracture behavior of cement mortars.” Eng. Fract. Mech. 210 (Apr): 444–451. https://doi.org/10.1016/j.engfracmech.2018.01.004.
Wang, B., and R. Zhao. 2018. “Effect of graphene nano-sheets on the chloride penetration and microstructure of the cement based composite.” Constr. Build. Mater. 161 (Feb): 715–722. https://doi.org/10.1016/j.conbuildmat.2017.12.094.
Watanabe, K., T. Kimura, and J. Niwa. 2010. “Synergetic effect of steel fibers and shear-reinforcing bars on the shear-resistance mechanisms of RC linear members.” Constr. Build. Mater. 24 (12): 2369–2375. https://doi.org/10.1016/j.conbuildmat.2010.05.009.
Yu, M. F., O. Lourie, M. J. Dyer, K. Moloni, T. F. Kelly, and R. S. Ruoff. 2000. “Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load.” Science 287 (5453): 637–640. https://doi.org/10.1126/science.287.5453.637.
Zheng, Q., B. Han, X. Cui, X. Yu, and J. Ou. 2017. “Graphene-engineered cementitious composites: Small makes a big impact.” Nanomater. Nanotechnol. 7 (Nov): 1847980417742304. https://doi.org/10.1177/1847980417742304.
Zhu, Y., S. Murali, W. Cai, X. Li, J. W. Suk, J. R. Potts, and R. S. Ruoff. 2010. “Graphene and graphene oxide: Synthesis, properties, and applications.” Adv. Mater. 22 (35): 3906–3924. https://doi.org/10.1002/adma.201001068.
Zohhadi, N. 2014. “Scholar commons functionalized graphitic nanoreinforcement for cement composites.” Ph.D. Dissertation, Dept. of Civil and Environmental Engineering, Univ. of South Carolina.
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Practice Periodical on Structural Design and Construction
Volume 29 • Issue 1 • February 2024
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© 2023 American Society of Civil Engineers.
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Received: Jun 10, 2023
Accepted: Oct 19, 2023
Published online: Dec 15, 2023
Published in print: Feb 1, 2024
Discussion open until: May 15, 2024
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