Technical Papers
Jun 23, 2023

Mechanical and Microstructural Characteristics of Manufactured Sand-Based High-Strength Geopolymer Concrete and Its Environmental Impact

Publication: Practice Periodical on Structural Design and Construction
Volume 28, Issue 4

Abstract

Geopolymer concrete (GPC) is one of the best alternative options for conventional concrete due to its adequate mechanical and durability properties with the addition of a lower carbon footprint. This research presents the experimental results of using ground granulated blast furnace slag (GGBS), fly ash (FA), and silica fume (SF) as a binder and manufactured sand (MS) as a fine aggregate on fresh and hardened high-strength geopolymer concrete (HSGPC). Initially, 16 mortar mixes were prepared and tested for compressive strength to finalize solution/binder and sodium silicate/sodium hydroxide ratios for HSGPC. The different mix proportions for M70, M80, M90, and M100 were calculated and validated experimentally. The proposed mix design methodology achieved the maximum compressive strength as high as 104 MPa at 28 days, along with coarse aggregate and MS. The promising mechanical properties were observed at 28 days for all grades of concrete. The mechanism of strength increment was appropriately justified by microstructural analysis. The equations of split tensile and flexural strength in terms of compressive strength were compared with the previously proposed equations in the literature. Microstructural analysis of HSGPC revealed that the enhancement in mechanical properties creates a dense microstructure of different gel formations like calcium-silicate-hydrate (C-S-H), calcium-alumino-silicate-hydrate (C-A-S-H), and sodium-alumino-silicate-hydrate (N-A-S-H) gels in HSGPC. Finally, the environmental impact assessment in terms of carbon emission of HSGPC was evaluated. It is found to be 90% lower compared with conventional concrete.

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Data Availability Statement

All data, models, or codes supporting this study’s findings are available from the corresponding author, Gaurav Jagad, upon reasonable request.

Acknowledgments

The authors would like to express thanks to Tejas Rathi, Mallikarjun Hulagabali, Mr. Yogesh H. Varasada (Suyog Element India Pvt. Ltd.), and Material Testing Laboratory, SVNIT, Surat, staff members for their continuous and immeasurable support and help.

References

ACI (American Concrete Institute). 1999. Measurement of properties of fiber reinforced concrete. ACI 544.2 R-89. Farmington Hills, MI: ACI.
ACI (American Concrete Institute). 2005. High-strength concrete. ACI 363R. Farmington Hills, MI: ACI.
Ahmed, M., K. M. El Hadi, M. A. Hasan, J. Mallick, and A. Ahmed. 2014. “Evaluating the co-relationship between concrete flexural tensile strength and compressive strength.” Int. J. Struct. Eng. 5 (2): 115–131. https://doi.org/10.1504/IJSTRUCTE.2014.060902.
Akaözolu, S., and C. D. Ati. 2011. “Effect of granulated blast furnace slag and fly ash addition on the strength properties of lightweight mortars containing waste PET aggregates.” Constr. Build. Mater. 25 (10): 4052–4058. https://doi.org/10.1016/j.conbuildmat.2011.04.042.
Amran, Y. H. M., R. Alyousef, H. Alabduljabbar, and M. El-Zeadani. 2020. “Clean production and properties of geopolymer concrete: A review.” J. Cleaner Prod. 251 (Apr): 119679. https://doi.org/10.1016/j.jclepro.2019.119679.
Anuradha, R., V. Sreevidya, R. Venkatasubramani, and B. V. Rangan. 2012. “Modified guidelines for geopolymer concrete mix design using Indian standard.” Asian J. Civil Eng. 13 (3): 353–364.
Arioglu, N., Z. C. Girgin, and E. Arioglu. 2006. “Evaluation of ratio between splitting tensile strength and compressive strength for concrete up to 120 MPa and its application in strength criterion.” ACI Mater. J. 103 (1): 18–24.
ASTM. 2008. Standard specification for coal fly ash and raw or calcined natural pozzolan for use in concrete. ASTM C618-08. West Conshohocken, PA: ASTM.
Bae, B.-I., H.-K. Choi, and C.-S. Choi. 2015. “Correlation between tensile strength and compressive strength of ultra high strength concrete reinforced with steel fiber.” J. Korea Concr. Inst. 27 (3): 253–263. https://doi.org/10.4334/JKCI.2015.27.3.253.
Bairagi, N. K., and C. D. Modhera. 2001. “Shear strength of fibre reinforced concrete.” ICI J. 1 (4): 47–52.
Bajpai, R., K. Choudhary, A. Srivastava, K. S. Sangwan, and M. Singh. 2020. “Environmental impact assessment of fly ash and silica fume based geopolymer concrete.” J. Cleaner Prod. 254 (May): 120147. https://doi.org/10.1016/j.jclepro.2020.120147.
Bhanja, S., and B. Sengupta. 2005. “Influence of silica fume on the tensile strength of concrete.” Cem. Concr. Res. 35 (4): 743–747.
Bhogayata, A., S. V. Dave, and N. K. Arora. 2020. “Utilization of expanded clay aggregates in sustainable lightweight geopolymer concrete.” J. Mater. Cycles Waste Manage. 22 (6): 1780–1792. https://doi.org/10.1007/s10163-020-01066-7.
Bhogayata, A. C., and N. K. Arora. 2018. “Impact strength, permeability and chemical resistance of concrete reinforced with metalized plastic waste fibers.” Constr. Build. Mater. 161 (Feb): 254–266. https://doi.org/10.1016/j.conbuildmat.2017.11.135.
BIS (Bureau of Indian Standards). 1983. Use of immersion vlbrators for consolidating concrete. IS:3558-1983. New Delhi, India: BIS.
Bisschop, J., and J. G. M. Van Mier. 2002. “How to study drying shrinkage microcracking in cement-based materials using optical and scanning electron microscopy?” Cem. Concr. Res. 32 (2): 279–287. https://doi.org/10.1016/S0008-8846(01)00671-8.
Cepuritis, R., B. J. Wigum, E. J. Garboczi, E. Mørtsell, and S. Jacobsen. 2014. “Filler from crushed aggregate for concrete: Pore structure, specific surface, particle shape and size distribution.” Cem. Concr. Compos. 54 (Nov): 2–16. https://doi.org/10.1016/j.cemconcomp.2014.03.010.
Chen, Z., J. S. Li, B. J. Zhan, U. Sharma, and C. S. Poon. 2018. “Compressive strength and microstructural properties of dry-mixed geopolymer pastes synthesized from GGBS and sewage sludge ash.” Constr. Build. Mater. 182 (Sep): 597–607. https://doi.org/10.1016/j.conbuildmat.2018.06.159.
Cheng, S., Z. Shui, T. Sun, R. Yu, and G. Zhang. 2018. “Durability and microstructure of coral sand concrete incorporating supplementary cementitious materials.” Constr. Build. Mater. 171 (May): 44–53. https://doi.org/10.1016/j.conbuildmat.2018.03.082.
Dave, S. V., and A. Bhogayata. 2020. “The strength oriented mix design for geopolymer concrete using Taguchi method and Indian concrete mix design code.” Constr. Build. Mater. 262 (Nov): 120853. https://doi.org/10.1016/j.conbuildmat.2020.120853.
Dave, S. V., A. Bhogayata, and N. K. Arora. 2021. “Mix design optimization for fresh, strength and durability properties of ambient cured alkali activated composite by Taguchi method.” Constr. Build. Mater. 284: 122822. https://doi.org/10.1016/j.conbuildmat.2021.122822.
Deb, P. S., P. Nath, and P. K. Sarker. 2014. “The effects of ground granulated blast-furnace slag blending with fly ash and activator content on the workability and strength properties of geopolymer concrete cured at ambient temperature.” Mater. Des. 62 (Oct): 32–39. https://doi.org/10.1016/j.matdes.2014.05.001.
Diaz-loya, E. I., E. N. Allouche, and S. Vaidya. 2012. “Mechanical properties of fly-ash-based geopolymer concrete.” ACI Mater. J. 108 (3): 300. https://doi.org/10.14359/51682495.
Donza, H., O. Cabrera, and E. F. Irassar. 2002. “High-strength concrete with different fine aggregate.” Cem. Concr. Res. 32 (11): 1755–1761. https://doi.org/10.1016/S0008-8846(02)00860-8.
Duan, P., C. Yan, W. Zhou, W. Luo, and C. Shen. 2015. “An investigation of the microstructure and durability of a fluidized bed fly ash-metakaolin geopolymer after heat and acid exposure.” Mater. Des. 74 (Jun): 125–137. https://doi.org/10.1016/j.matdes.2015.03.009.
Farhan, N. A., M. N. Sheikh, and M. N. S. Hadi. 2019. “Investigation of engineering properties of normal and high strength fly ash based geopolymer and alkali-activated slag concrete compared to ordinary portland cement concrete.” Constr. Build. Mater. 196 (Jan): 26–42. https://doi.org/10.1016/j.conbuildmat.2018.11.083.
Ferdous, M. W., O. Kayali, and A. Khennane. 2013. “A detailed procedure of mix design for fly ash based geopolymer concrete.” In Proc., 4th Asia-Pacific Conf. on FRP in Structures, APFIS 2013. Lismore, NSW, Australia: South Cross Univ.
García-Lodeiro, I., A. Fernández-Jiménez, A. Palomo, and D. E. MacPhee. 2010. “Effect of calcium additions on N-A-S-H cementitious gels.” J. Am. Ceram. Soc. 93 (7): 1934–1940. https://doi.org/10.1111/j.1551-2916.2010.03668.x.
García-Lodeiro, I., A. Palomo, A. Fernández-Jiménez, and D. E. MacPhee. 2011. “Compatibility studies between N-A-S-H and C-A-S-H gels. Study in the ternary diagram Na2O-CaO-Al2O3-SiO2-H2O.” Cem. Concr. Res. 41 (9): 923–931. https://doi.org/10.1016/j.cemconres.2011.05.006.
Gartner, E. 2004. “Industrially interesting approaches to ‘low-CO2’ cements.” Cem. Concr. Res. 34 (9): 1489–1498. https://doi.org/10.1016/j.cemconres.2004.01.021.
Goble, C. F., and M. D. Cohen. 1999. “Influence of aggregate surface area on mechanical properties of mortar.” ACI Mater. J. 96: 657–662. https://doi.org/10.14359/791.
Hadi, M. N. S., N. A. Farhan, and M. N. Sheikh. 2017. “Design of geopolymer concrete with GGBFS at ambient curing condition using Taguchi method.” Constr. Build. Mater. 140: 424–431. https://doi.org/10.1016/j.conbuildmat.2017.02.131.
Hasan, N. M. S., et al. 2022. “Integration of rice husk ash as supplementary cementitious material in the production of sustainable high-strength concrete.” Materials 15 (22): 8171. https://doi.org/10.3390/ma15228171.
Imamoto, K., and M. Arai. 2008. “Specific surface area of aggregate and its relation to concrete drying shrinkage.” Mater. Struct. 41 (2): 323–333. https://doi.org/10.1617/s11527-007-9245-x.
Imtiaz, L., S. K. U. Rehman, S. A. Memon, M. K. Khan, and M. F. Javed. 2020. “A review of recent developments and advances in eco-friendly geopolymer concrete.” Appl. Sci. 10 (21): 7838. https://doi.org/10.3390/app10217838.
Iravani, S. 1996. “Mechanical properties of high-performance concrete.” ACI Mater. J. 93 (5): 416–426. https://doi.org/10.14359/9845.
IS (Indian Standard). 1959. Method of tests for strength of concrete. IS 516. New Delhi, India: IS.
IS (Indian Standard). 1980. (First Revision) (First Revision). IS:2720. New Delhi, India: IS.
IS (Indian Standard). 1996. Method of physical tests for hydraulic cement, (Reaffirmed 2021). IS 4031 (Part 1). New Delhi, India: IS.
IS (Indian Standard). 2004. Indian standard methods of sampling and analysis of concrete. IS 1199-1959. New Delhi, India: IS.
IS (Indian Standard). 2016. Coarse and fine aggregate for concrete–specification. IS 383 (2016). New Delhi, India: IS.
IS (Indian Standard). 2019. Concrete mix proportioning. IS 10262: 2019. New Delhi, India: IS.
Ismeik, M. 2009. “Effect of mineral admixtures on mechanical properties of high strength concrete made with locally available materials.” Jordan J. Civ. Eng. 3 (1): 78–90.
Jawahar, J. G., and G. Mounika. 2016. “Strength properties of fly ash and GGBS based geopolymer concrete.” Asian J. Civ. Eng. 17 (1): 127–135.
Jeong, Y., H. Park, Y. Jun, J. H. Jeong, and J. E. Oh. 2015. “Microstructural verification of the strength performance of ternary blended cement systems with high volumes of fly ash and GGBFS.” Constr. Build. Mater. 95 (Oct): 96–107. https://doi.org/10.1016/j.conbuildmat.2015.07.158.
Ji, T., C. Y. Chen, Y. Z. Zhuang, and J. F. Chen. 2013. “A mix proportion design method of manufactured sand concrete based on minimum paste theory.” Constr. Build. Mater. 44 (Jul): 422–426. https://doi.org/10.1016/j.conbuildmat.2013.02.074.
Juki, M. I., M. Awang, M. M. K. Annas, K. H. Boon, N. Othman, M. A. Roslan, and F. S. Khalid. 2013. “Relationship between compressive, splitting tensile and flexural strength of concrete containing granulated waste polyethylene terephthalate (PET) bottles as fine aggregate.” Adv. Mater. Res. 795 (Nov): 356–359. https://doi.org/10.4028/www.scientific.net/AMR.795.356.
Kumar, R., and B. Bhattacharjee. 2003. “Porosity, pore size distribution and in situ strength of concrete.” Cem. Concr. Res. 33 (1): 155–164. https://doi.org/10.1016/S0008-8846(02)00942-0.
Lahoti, M., P. Narang, K. H. Tan, and E. H. Yang. 2017. “Mix design factors and strength prediction of metakaolin-based geopolymer.” Ceram. Int. 43 (14): 11433–11441. https://doi.org/10.1016/j.ceramint.2017.06.006.
Latawiec, R., P. Woyciechowski, and K. J. Kowalski. 2018. “Sustainable concrete performance—CO2-emission.” Environments 5 (2): 27. https://doi.org/10.3390/environments5020027.
Li, H., F. Huang, G. Cheng, Y. Xie, Y. Tan, L. Li, and Z. Yi. 2016. “Effect of granite dust on mechanical and some durability properties of manufactured sand concrete.” Constr. Build. Mater. 109 (Apr): 41–46. https://doi.org/10.1016/j.conbuildmat.2016.01.034.
Liu, B., K. Zhuang, D. Li, Y. Fang, and G. Pan. 2020. “Understanding the early reaction and structural evolution of alkali activated slag optimized using K-A-S-H nanoparticles with varying K2O/SiO2 ratios.” Composites, Part B 200 (May): 108311. https://doi.org/10.1016/j.compositesb.2020.108311.
Luan, C., X. Shi, K. Zhang, N. Utashev, F. Yang, J. Dai, and Q. Wang. 2021. “A mix design method of fly ash geopolymer concrete based on factors analysis.” Constr. Build. Mater. 272 (Feb): 121612. https://doi.org/10.1016/j.conbuildmat.2020.121612.
Mane, K. M., A. M. Joshi, D. K. Kulkarni, and K. B. Prakash. 2022. “Influence of retempering on properties of concrete made with manufactured sand and industrial waste.” Cleaner Mater. 4 (Jan): 100060. https://doi.org/10.1016/j.clema.2022.100060.
Montes, C., S. A. Gomez, N. Khadka, and E. N. Allouche. 2013. “AStatistical software to improve the accuracy of geopolymer concrete mix design and proportioning.” In Proc., 2013 World of Coal Ash (WOCA) Conf. Lexington, KY: Univ. of Kentucky.
Morsy, A. M., A. M. Ragheb, A. H. Shalan, and O. H. Mohamed. 2022. “Mechanical characteristics of GGBFS/FA-based geopolymer concrete and its environmental impact.” Pract. Period. Struct. Des. Constr. 27 (2): 04022017. https://doi.org/10.1061/(ASCE)SC.1943-5576.0000686.
Nanthagopalan, P., and M. Santhanam. 2011. “Fresh and hardened properties of self-compacting concrete produced with manufactured sand.” Cem. Concr. Compos. 33 (3): 353–358. https://doi.org/10.1016/j.cemconcomp.2010.11.005.
Nath, P., and P. K. Sarker. 2017. “Flexural strength and elastic modulus of ambient-cured blended low-calcium fly ash geopolymer concrete.” Constr. Build. Mater. 130 (Jan): 22–31. https://doi.org/10.1016/j.conbuildmat.2016.11.034.
Ng, T. S., and S. J. Foster. 2013. “Development of a mix design methodology for high-performance geopolymer mortars.” Struct. Concr. 14 (2): 148–156. https://doi.org/10.1002/suco.201200018.
Ojha, A., and P. Aggarwal. 2023. “Development of mix design guidelines for low calcium fly ash-based geopolymer concrete—A quantitative approach.” Silicon 15: 3681–3694. https://doi.org/10.1007/s12633-023-02299-5.
Patankar, S. V., Y. M. Ghugal, and S. S. Jamkar. 2015. “Mix design of fly ash based geopolymer concrete.” In Advances in structural engineering: Materials, volume three, 1619–2647. New Delhi, India: Springer.
Pavithra, P., M. Srinivasula Reddy, P. Dinakar, B. Hanumantha Rao, B. K. Satpathy, and A. N. Mohanty. 2016. “A mix design procedure for geopolymer concrete with fly ash.” J. Cleaner Prod. 133: 117–125. https://doi.org/10.1016/j.jclepro.2016.05.041.
Phoo-Ngernkham, T., C. Phiangphimai, N. Damrongwiriyanupap, S. Hanjitsuwan, J. Thumrongvut, and P. Chindaprasirt. 2018. “A mix design procedure for alkali-activated high-calcium fly ash concrete cured at ambient temperature.” Adv. Mater. Sci. Eng. https://doi.org/10.1155/2018/2460403.
Reddy, M. S., P. Dinakar, and B. H. Rao. 2018. “Mix design development of fly ash and ground granulated blast furnace slag based geopolymer concrete.” J. Build. Eng. 20 (Feb): 712–722. https://doi.org/10.1016/j.jobe.2018.09.010.
Ryu, G. S., Y. B. Lee, K. T. Koh, and Y. S. Chung. 2013. “The mechanical properties of fly ash-based geopolymer concrete with alkaline activators.” Constr. Build. Mater. 47 (2013): 409–418. https://doi.org/10.1016/j.conbuildmat.2013.05.069.
Sahraei Moghadam, A., F. Omidinasab, and S. Moazami Goodarzi. 2021. “Characterization of concrete containing RCA and GGBFS: Mechanical, microstructural and environmental properties.” Constr. Build. Mater. 289 (Jun): 123134. https://doi.org/10.1016/j.conbuildmat.2021.123134.
Serag Faried, A., W. H. Sofi, A. Z. Taha, M. A. El-Yamani, and T. A. Tawfik. 2020. “Mix design proposed for geopolymer concrete mixtures based on ground granulated blast furnace slag.” Aust. J. Civ. Eng. 18 (2): 205–218. https://doi.org/10.1080/14488353.2020.1761513.
Shen, W., Y. Liu, Z. Wang, L. Cao, D. Wu, Y. Wang, and X. Ji. 2018. “Influence of manufactured sand’s characteristics on its concrete performance.” Constr. Build. Mater. 172 (May): 574–583. https://doi.org/10.1016/j.conbuildmat.2018.03.139.
Shen, W., Z. Yang, L. Cao, L. Cao, Y. Liu, H. Yang, Z. Lu, and J. Bai. 2016. “Characterization of manufactured sand: Particle shape, surface texture and behavior in concrete.” Constr. Build. Mater. 114 (Jul): 595–601. https://doi.org/10.1016/j.conbuildmat.2016.03.201.
Turner, L. K., and F. G. Collins. 2013. “Carbon dioxide equivalent (CO2-e) emissions: A comparison between geopolymer and OPC cement concrete.” Constr. Build. Mater. 43 (Jun): 125–130. https://doi.org/10.1016/j.conbuildmat.2013.01.023.
Wallah, S. E. 2010. “Creep behaviour of fly ash-based geopolymer concrete.” Civ. Eng. Dimens. 12 (2): 2021. https://doi.org/10.9744/ced.12.2.73-78.
Xie, T., P. Visintin, X. Zhao, and R. Gravina. 2020. “Mix design and mechanical properties of geopolymer and alkali activated concrete: Review of the state-of-the-art and the development of a new unified approach.” Constr. Build. Mater. 256 (Sep): 119380. https://doi.org/10.1016/j.conbuildmat.2020.119380.
Xu, B. W., and H. S. Shi. 2009. “Correlations among mechanical properties of steel fiber reinforced concrete.” Constr. Build. Mater. 23 (12): 3468–3474. https://doi.org/10.1016/j.conbuildmat.2009.08.017.
Xu, S., P. Yuan, J. Liu, Z. Pan, Z. Liu, Y. Su, J. Li, and C. Wu. 2021. “Development and preliminary mix design of ultra-high-performance concrete based on geopolymer.” Constr. Build. Mater. 308 (Nov): 125110. https://doi.org/10.1016/j.conbuildmat.2021.125110.
Yamei, H., and W. Lihua. 2017. “Effect of particle shape of limestone manufactured sand and natural sand on concrete.” Procedia Eng. 210 (Jan): 87–92. https://doi.org/10.1016/j.proeng.2017.11.052.

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Go to Practice Periodical on Structural Design and Construction
Practice Periodical on Structural Design and Construction
Volume 28Issue 4November 2023

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Received: Dec 9, 2022
Accepted: Apr 26, 2023
Published online: Jun 23, 2023
Published in print: Nov 1, 2023
Discussion open until: Nov 23, 2023

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Research Scholar, Dept. of Civil Engineering, Sardar Vallabhbhai National Institute of Technology, Surat, Gujarat 395007, India (corresponding author). ORCID: https://orcid.org/0000-0001-9369-6278. Email: [email protected]
Chetankumar Modhera [email protected]
Professor Higher Administrative Grade (HAG), Dept. of Civil Engineering, Sardar Vallabhbhai National Institute of Technology, Surat, Gujarat 395007, India. Email: [email protected]
Research Scholar, Dept. of Civil Engineering, Sardar Vallabhbhai National Institute of Technology, Surat, Gujarat 395007, India. ORCID: https://orcid.org/0000-0001-8753-5494. Email: [email protected]
Vimalkumar Patel [email protected]
Professor, Dept. of Civil Engineering, Gardi Vidyapith, Rajkot, Gujarat 360002, India. Email: [email protected]

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