Mesoporous Material Modified by Poly-O-Phenylene and Aquatic Plants Cellulose for Effective Removal of Hg(II) Ions
Publication: Journal of Environmental Engineering
Volume 149, Issue 10
Abstract
In this work, a composite adsorbent (modified poly-o-phenylene aquatic plant cellulose; MPP-AC) was prepared by using aminated mesoporous material as the carrier, aquatic cellulose as the dopant, and supporting poly-o-phenylenediamine. The adsorption study indicates that the adsorbent can reach a maximum saturation adsorption capacity of . The data fit analysis reveals that the adsorption of Hg(II) by MPP-AC is consistent with a quasi-second-order kinetic model and followed the Langmuir adsorption isotherm model. The whole adsorption process is a heat absorption process that proceeds spontaneously. Interfering ion experiments show that coexisting cations have almost no competitive effect on the removal of Hg(II), indicating that the adsorbent has good selectivity for Hg(II) adsorption. After five cycles of adsorbent regeneration experiments, the adsorption capacity of MPP-AC can reach , indicating that the adsorbent has good regeneration performance. The composite can be used as an effective, economical, and environmentally friendly potential adsorbent for the adsorption of mercury ions.
Get full access to this article
View all available purchase options and get full access to this article.
Data Availability Statement
All data, models, and code generated or used during the study appear in the published article.
Acknowledgments
This work was supported by Fujian Marine Economic Development Special project (FJHJF-L-2022-21) and Scientific Research Fund project of Ningde Normal University (2020Z02).
References
Algarra, M., M. V. Jiménez, E. Rodríguez-Castellón, A. Jiménez-López, and J. Jiménez-Jiménez. 2005. “Heavy metals removal from electroplating wastewater by aminopropyl Si MCM-41.” Chemosphere 59 (6): 779–786. https://doi.org/10.1016/j.chemosphere.2004.11.023.
Alsharari, S. F., A. A. Tayel, and S. H. Moussa. 2018. “Soil emendation with nano-fungal chitosan for heavy metals biosorption.” Int. J. Biol. Macromol. 118 (Oct): 2265–2268. https://doi.org/10.1016/j.ijbiomac.2018.07.103.
Awual, M., H. Rabiul, and M. Munjur. 2016. “Treatment of copper(II) containing wastewater by a newly developed ligand based facial conjugate materials.” Chem. Eng. J. 288 (Mar): 368–376. https://doi.org/10.1016/j.cej.2015.11.108.
Bansal, M., B. Ram, G. S. Chauhan, and A. Kaushik. 2018. “L-Cysteine functionalized bagasse cellulose nanofibers for mercury(II) ions adsorption.” Int. J. Biol. Macromol. 112 (Jun): 728–736. https://doi.org/10.1016/j.ijbiomac.2018.01.206.
Borreguero, A., A. Leura, and J. F. Rodriguez. 2018. “Modelling the mercury removal from polluted waters by using TOMAC microcapsules considering the metal speciation.” Chem. Eng. J. 341 (Jun): 308–316. https://doi.org/10.1016/j.cej.2018.01.113.
Broere, D. L., R. Plessius, and J. I. Vlugt. 2015. “New avenues for ligand-mediated processes—Expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands.” Chem. Soc. Rev. 44 (19): 6886–6915. https://doi.org/10.1039/C5CS00161G.
Buonomenna, M. G., S. M. Mousavi, S. A. Hashemi, and C. W. Lai. 2022. “Water cleaning adsorptive membranes for efficient removal of heavy metals and metalloids.” Water 14 (Aug): 2718. https://doi.org/10.3390/w14172718.
Chandra, V., and K. S. Kim. 2011. “Highly selective adsorption of by a polypyrrole-reduced graphene oxide composite.” Chem. Commun. 47 (13): 3942–3944. https://doi.org/10.1039/c1cc00005e.
Chen, C., K. Jing, J. Shen, S. X. Zhao, B. Y. Wang, Z. L. Chen, and Q. Chen. 2021. “Selective and efficient removal of Hg(II) from aqueous media by a low-cost dendrimer-grafted polyacrylonitrile fiber: Performance and mechanism.” Chemosphere 262 (Jan): 127836. https://doi.org/10.1016/j.chemosphere.2020.127836.
Chen, L. Y., M. Rong, L. R. Yang, J. M. Yu, H. N. Qu, Q. Y. Meng, S. Ni, Z. H. Xu, X. Y. Zhu, L. Wang, H. F. Xing, and H. Z. Liu. 2022. “Construction of super-hydrophobic hypercrosslinked porous polymers for selectively removing aromatic diamines from the polyurethane bio-hydrolysate.” Chem. Eng. J. 428 (Jan): 132509. https://doi.org/10.1016/j.cej.2021.132509.
Cheng, R., M. Kang, S. Zhuang, L. Shi, X. Zheng, and J. Wang. 2018. “Adsorption of Sr(II) from water by mercerized bacterial cellulose membrane modified with EDTA.” J. Hazard. Mater. 64 (Feb): 645–653. https://doi.org/10.1016/j.jhazmat.2018.10.083.
Cheng, S. Y., S. Pau-Loke, F. L. Beng, C. Jo-Shu, and C. L. Tau. 2019. “New prospects for modified algae in heavy metal adsorption.” Trends Biotechnol. 37 (Nov): 1255–1268. https://doi.org/10.1016/j.tibtech.2019.04.007.
Chu, S. Y., X. F. Feng, C. C. Liu, H. R. Wu, and X. B. Liu. 2022. “Advances in chelating resins for adsorption of heavy metal ions.” Ind. Eng. Chem. Res. 61 (31): 11309–11328. https://doi.org/10.1021/acs.iecr.2c01353.
Dickschat, A. T., F. Behrends, and M. Buhner. 2012. “Preparation of bifunctional mesoporous silica nanoparticles by orthogonal click reactions and their application in cooperative catalysis.” Chemistry 18 (52): 16689–16697. https://doi.org/10.1002/chem.201200499.
Esquivel, D., J. Ouwehand, M. Meledina, S. Turner, G. Van Tendeloo, F. J. Romero-Salguero, J. De Clercq, and P. Van Der Voort. 2017. “Thiol-ethylene bridged PMO: A high capacity regenerable mercury adsorbent via intrapore mercury thiolate crystal formation.” J. Hazard. Mater. 339 (Oct): 368–377. https://doi.org/10.1016/j.jhazmat.2017.06.051.
Hendriks, A. T., and G. Zeeman. 2009. “Pretreatments to enhance the digestibility of lignocellulosic biomass.” Bioresour. Technol. 100 (1): 10–18. https://doi.org/10.1016/j.biortech.2008.05.027.
Hieu, V., B. Bac, and B. Xuan. 2020. “A novel approach in adsorption of heavy metal ions from aqueous solution using synthesized MCM-41 from coal bottom ash.” Int. J. Environ. Anal. Chem. 100 (11): 1226–1244. https://doi.org/10.1080/03067319.2019.1651300.
Li, T., C. Yuan, and Y. Zhao. 2013. “Facile synthesis and characterization of poly (o-phenylenediamine) submicrospheres doped with glycine.” J. Macromol. Sci. Part A: Pure Appl. Chem. 50 (3): 330–333. https://doi.org/10.1080/10601325.2013.755882.
Liao, F., S. Yang, and X. Li. 2014. “Synthesis of nanoscale poly (o-phenylenediamine) regular hexagonal prisms: A new way to build the 3D structure from 2D structure with amorphous structure.” Synth. Met. 190 (Apr): 79–85. https://doi.org/10.1016/j.synthmet.2014.02.006.
Liu, Y., X. Xu, B. Qu, X. Liu, W. Yi, and H. Zhang. 2021. “Study on adsorption properties of modified corn cob activated carbon for mercury ion.” Energies 14 (15): 4483. https://doi.org/10.3390/en14154483.
Liu, Z. Y., F. Zhen, Q. G. Zhang, X. Qian, W. Z. Li, Y. Sun, L. L. Zhang, and B. Qu. 2022. “Nanoporous biochar with high specific surface area based on rice straw digestion residue for efficient adsorption of mercury ion from water.” Bioresour. Technol. 359 (Sep): 127471. https://doi.org/10.1016/j.biortech.2022.127471.
Lu, D., S. Xu, and W. Qiu. 2020. “Adsorption and desorption behaviors of antibiotic ciprofloxacin on functionalized spherical MCM-41 for water treatment.” J. Cleaner Prod. 264 (Aug): 121644. https://doi.org/10.1016/j.jclepro.2020.121644.
Lu, X., M. Hui, and D. Chao. 2007. “Preparation and characterization of poly (o-phenylenediamine) microrods using ferric chloride as an oxidant.” Mater. Lett. 61 (6): 1400–1403. https://doi.org/10.1016/j.matlet.2006.07.040.
Magnusson, L., R. Islam, and R. Sparling. 2008. “Direct hydrogen production from cellulosic waste materials with a single-step dark fermentation process.” Int. J. Hydrogen Energy 33 (20): 5398–5403. https://doi.org/10.1016/j.ijhydene.2008.06.018.
Marius, G. M., I. Ciprian, N. Gheorghe, and V. C. Niculescu. 2019. “High selective mixed membranes based on mesoporous MCM-41 and MCM-41- particles in a polysulfone matrix.” Front. Chem. 7 (Jun): 17. https://doi.org/10.3389/fchem.2019.00332.
Mello, M. R., D. Phanon, G. Q. Silveira, P. L. Llewellyn, and C. M. Ronconi. 2011. “Amine-modified MCM-41 mesoporous silica for carbon dioxide capture.” Microporous Mesoporous Mater. 143 (1): 174–179. https://doi.org/10.1016/j.micromeso.2011.02.022.
Meng, M., Y. Xi, and W. Wang. 2015. “Preparation of monodispersed mesoporous silica particles and their applications in adsorption of and after mercapto-functionalized treatment.” Microporous Mesoporous Mater. 214 (1): 15–22. https://doi.org/10.1016/j.micromeso.2015.04.033.
Mosier, N., C. Wyman, and B. Dale. 2005. “Features of promising technologies for pretreatment of lignocellulosic biomass.” Bioresour. Technol. 96 (6): 673–686. https://doi.org/10.1016/j.biortech.2004.06.025.
Peng, S., H. Meng, Y. Ouyang, and J. Chang. 2014. “Nanoporous magnetic cellulose-chitosan composite microspheres: Preparation, characterization, and application for Cu(II) adsorption.” Ind. Eng. Chem. Res. 53 (6): 2106–2113. https://doi.org/10.1021/ie402855t.
Perez, D., A. Sanchez, and I. Hierro. 2007. “Preparation characterization and adsorption behavior of chemically modified MCM-41 with 5-mercapto-1-methyltetrazole.” J. Colloid Interface Sci. 313 (2): 551–562. https://doi.org/10.1016/j.jcis.2007.04.063.
Perumal, S., R. Atchudan, P. Thirukumaran, D. H. Yoon, Y. R. Lee, and I. W. Cheong. 2022. “Simultaneous removal of heavy metal ions using carbon dots-doped hydrogel particles.” Chemosphere 286 (Jan): 131760. https://doi.org/10.1016/j.chemosphere.2021.131760.
Rasha, S. E., T. E. Shaimaa, E. Ashraf, A. M. Abdel-Ghany, A. S. Hanaa, and M. H. Khaled. 2019. “Silver/quartz nanocomposite as an adsorbent for removal of mercury (II) ions from aqueous solutions.” Heliyon 5 (9): e02415. https://doi.org/10.1016/j.heliyon.2019.e02415.
Rong, L., Z. M. Zhu, B. J. Wang, Z. P. Mao, X. Hong, L. P. Zhang, and Y. Zhang. 2018. “Facile fabrication of thiol-modified cellulose sponges for adsorption of from aqueous solutions.” Cellulose 25 (Mar): 3025–3035. https://doi.org/10.1007/s10570-018-1758-7.
Shi, M., Y. Peng, and Z. Jia. 2007. “Multianalyte immunoassay based on insulating-controllable PoPD film at arrayed electrodes integrated on a silicon chip.” Biosens. Bioelectron. 22 (12): 2841–2847. https://doi.org/10.1016/j.bios.2006.11.023.
Valery, B., B. David, and C. Nazim. 2011. “Biomass pretreatment: Fundamentals toward application.” Biotechnol. Adv. 29 (6): 675–685. https://doi.org/10.1016/j.biotechadv.2011.05.005.
Velempini, T., K. Pillay, X. Y. Mbianda, and O. A. Arotiba. 2019. “Carboxymethyl cellulose thiolimprinted polymers: Synthesis, characterization and selective Hg(II) adsorption.” J. Environ. Sci. 79 (Mar): 280–296. https://doi.org/10.1016/j.jes.2018.11.022.
Vo, T. S., M. M. Hossain, H. M. Jeong, and K. Kim. 2020. “Heavy metal removal applications using adsorptive membranes.” Nano Convergence 36 (Dec): 7. https://doi.org/10.1186/s40580-020-00245-4.
Walcarius, A., and C. Delacôte. 2005. “Mercury(II) binding to thiol-functionalized mesoporous silicas: Critical effect of pH and sorbent properties on capacity and selectivity.” Anal. Chim. Acta 547 (Aug): 3–13. https://doi.org/10.1016/j.aca.2004.11.047.
Wang, F., L. T. Jin, C. N. Guo, L. J. Min, P. Zhang, H. W. Sun, H. K. Zhu, and C. P. Zhang. 2021. “Enhanced heavy metals sorption by modified biochars derived from pig manure.” Sci. Total Environ. 786 (Mar): 147595. https://doi.org/10.1016/j.scitotenv.2021.147595.
Wang, F., F. Liao, and S. Yang. 2011. “A novel route synthesis of poly(ortho-phenylenediamine) fluffy microspheres self-assembled from nanospheres.” Fibers Polym. 12 (8): 997–1001. https://doi.org/10.1007/s12221-011-0997-0.
Wang, Z., Y. Dong, H. Li, Z. Zhao, H. B. Wu, C. Hao, S. Liu, J. Qiu, and X. W. Lou. 2014. “Enhancing lithium-sulphur battery performance by strongly binding the discharge products on amino-functionalized reduced graphene oxide.” Nat. Commun. 5 (1): 5002. https://doi.org/10.1038/ncomms6002.
Xin, L., H. Mei, and W. Duan. 2002. “Novel multifunctional polymers from aromatic diamines by oxidative polymerizations.” Chem. Rev. 102 (9): 2925–3030. https://doi.org/10.1021/cr010423z.
Yang, B., and C. E. Wyman. 2004. “Effect of xylan and lignin removal by batch and flowthrough pretreatment on the enzymatic digestibility of corn stover cellulose.” Biotechnol. Bioeng. 86 (1): 88–98. https://doi.org/10.1002/bit.20043.
Zaimee, M. Z. A., M. S. Sarjadi, and M. L. Rahman. 2021. “Rahman, heavy metals removal from water by efficient adsorbents.” Water 13 (19): 2659. https://doi.org/10.3390/w13192659.
Zhang, L., L. Chai, and H. Wang. 2010. “Facile synthesis of one-dimensional self-assembly oligo(o-phenylenediamine) materials by ammonium persulfate in acidic solution.” Mater. Lett. 64 (10): 1193–1196. https://doi.org/10.1016/j.matlet.2010.02.048.
Zheng, K., H. Yang, and L. Wang. 2013. “Amino-functionalized mesoporous silica nanoparticles: Adsorption and protection for PcDNA3.1(+)-PKB-HA.” J. Porous Mater. 20 (5): 1003–1008. https://doi.org/10.1007/s10934-013-9679-1.
Zhou, Y., Q. Jin, and X. Hu. 2012. “Heavy metal ions and organic dyes removal from water by cellulose modified with maleic anhydride.” J. Mater. Sci. 47 (12): 5019–5029. https://doi.org/10.1007/s10853-012-6378-2.
Information & Authors
Information
Published In
Copyright
© 2023 American Society of Civil Engineers.
History
Received: Jan 7, 2023
Accepted: May 17, 2023
Published online: Jul 24, 2023
Published in print: Oct 1, 2023
Discussion open until: Dec 24, 2023
ASCE Technical Topics:
- Absorption
- Adsorption
- Aquatic habitats
- Chemical processes
- Chemistry
- Composite materials
- Continuum mechanics
- Data analysis
- Dynamics (solid mechanics)
- Ecosystems
- Engineering fundamentals
- Engineering materials (by type)
- Engineering mechanics
- Environmental engineering
- Kinetics
- Materials engineering
- Methodology (by type)
- Porous media
- Research methods (by type)
- Solid mechanics
- Sorption
- Vegetation
Authors
Metrics & Citations
Metrics
Citations
Download citation
If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.