Technical Papers
Jun 18, 2024

Green and Sustainable Superhydrophobic Phosphogypsum Mortar Coating with Self-Cleaning Properties and Water Resistance

Publication: Journal of Materials in Civil Engineering
Volume 36, Issue 9

Abstract

Phosphogypsum (PG) is a solid waste generated by phosphate fertilizer industries that is currently used in concrete materials. However, adding PG to concrete usually results in reducing its water resistance and corrosion resistance. This paper presents a new method of applying PG to concrete to improve its water resistance. In this paper, a green superhydrophobic PG (SPG) coating was prepared using modified PG as a hydrophobic medium and cement as the bonding material. The contact angle between the superhydrophobic phosphogypsum coating (SPG coating) and water was 156°, and the coating reached a superhydrophobic state with good self-cleaning ability. Even when sandpaper was used to polish the coating, the water contact angle of the coating was still greater than 150°, indicating that the coating had good wear resistance. In addition, the results of water absorption and electrochemical experiments indicated that mortar coated with SPG had better water resistance and corrosion resistance than ordinary mortar. The SPG coatings with water resistance, wear resistance, and self-cleaning properties have potential applications in building exterior walls.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

Some or all data or models that support the findings of this study are available from the corresponding author upon request.

Acknowledgments

This work was supported by Taishan Scholar Project of Shandong Province (No. TSHW20130956) and the Natural Science Foundation of Shandong Province, China (No. ZR2023QE053).

References

Balkaya, N., and H. Cesur. 2016. “A kinetic study on cadmium adsorption from aqueous solutions by pre-conditioned phosphogypsum.” Desalin. Water Treat. 57 (6): 2515–2521. https://doi.org/10.1080/19443994.2015.1038854.
Bormashenko, E. 2016. “Physics of solid–liquid interfaces: From the Young equation to the superhydrophobicity.” Low Temp. Phys. 42 (8): 622–635. https://doi.org/10.1063/1.4960495.
Chernysh, Y., O. Yakhnenko, V. Chubur, and H. Roubík. 2021. “Phosphogypsum recycling: A review of environmental issues, current trends, and prospects.” Appl. Sci. 11 (4): 1575. https://doi.org/10.3390/app11041575.
Ding, C., T. Sun, Z. Shui, Y. Xie, and Z. Ye. 2022. “Physical properties, strength, and impurities stability of phosphogypsum-based cold-bonded aggregates.” Constr. Build. Mater. 331 (May): 127307. https://doi.org/10.1016/j.conbuildmat.2022.127307.
Feng, L., K. Jin, and H. Wang. 2021. “Research on the thermal conductivity and water resistance of foamed phosphogypsum.” Coatings 11 (7): 802. https://doi.org/10.3390/coatings11070802.
Gong, X., J. Liu, Z. Sun, and F. Li. 2020. “Effects of phosphogypsum and calcined phosphogypsum content on the basic physical and mechanical properties of portland cement mortar.” J. Test. Eval. 48 (5): 3539–3549. https://doi.org/10.1520/JTE20180380.
Horgnies, M., and J. J. Chen. 2014. “Superhydrophobic concrete surfaces with integrated microtexture.” Cem. Concr. Compos. 52 (May): 81–90. https://doi.org/10.1016/j.cemconcomp.2014.05.010.
Islam, G. S., F. H. Chowdhury, M. T. Raihan, S. K. S. Amit, and M. R. Islam. 2017. “Effect of phosphogypsum on the properties of portland cement.” Procedia Eng. 171 (Jan): 744–751. https://doi.org/10.1016/j.proeng.2017.01.440.
Jin, Z., B. Ma, Y. Su, H. Qi, and W. Lu. 2021. “Preparation of eco-friendly lightweight gypsum: Use of beta-hemihydrate phosphogypsum and expanded polystyrene particles.” Constr. Build. Mater. 297 (Aug): 123837. https://doi.org/10.1016/j.conbuildmat.2021.123837.
Kocak, Y., E. Tascı, and U. Kaya. 2013. “The effect of using natural zeolite on the properties and hydration characteristics of blended cements.” Constr. Build. Mater. 47 (May): 720–727. https://doi.org/10.1016/j.conbuildmat.2013.05.033.
Li, B., L. Li, X. Chen, Y. Ma, and M. Zhou. 2022. “Modification of phosphogypsum using circulating fluidized bed fly ash and carbide slag for use as cement retarder.” Constr. Build. Mater. 338 (Jul): 127630. https://doi.org/10.1016/j.conbuildmat.2022.127630.
Li, X., Q. Wang, L. Lei, Z. Shi, and M. Zhang. 2021. “Amphiphobic concrete with good oil stain resistance and anti-corrosion properties used in marine environment.” Constr. Build. Mater. 299 (Sep): 123945. https://doi.org/10.1016/j.conbuildmat.2021.123945.
Lin, C., W. Dai, Z. Li, and Y. Wang. 2020. “Study on the inorganic synthesis from recycled cement and solid waste gypsum system: Application in grouting materials.” Constr. Build. Mater. 251 (Aug): 118930. https://doi.org/10.1016/j.conbuildmat.2020.118930.
Macías, F., C. R. Cánovas, P. Cruz-Hernández, S. Carrero, M. P. Asta, J. M. Nieto, and R. Pérez-López. 2017. “An anomalous metal-rich phosphogypsum: Characterization and classification according to international regulations.” J. Hazard Mater. 331 (Jun): 99–108. https://doi.org/10.1016/j.jhazmat.2017.02.015.
Mashifana, T., F. Okonta, and F. Ntuli. 2019. “Effect of curing temperature and particle size distribution on unconfined compressive strength of raw and treated fly ash-lime modified phosphogypsum waste.” IOP Conf. Ser.: Mater. Sci. Eng. 652 (1): 012044. https://doi.org/10.1088/1757-899X/652/1/012044.
Mousa, S. M., N. S. Ammar, and H. A. Ibrahim. 2016. “Removal of lead ions using hydroxyapatite nano-material prepared from phosphogypsum waste.” J. Saudi Chem. Soc. 20 (3): 357–365. https://doi.org/10.1016/j.jscs.2014.12.006.
Qu, L., Q. Wang, J. Mao, S. Xu, H. Zhang, Z. Shi, and X. Li. 2021. “Study of anti-chlorine corrosion of anion exchange resin based superhydrophobic cement mortar in chloride salt environment.” Constr. Build. Mater. 313 (Dec): 125540. https://doi.org/10.1016/j.conbuildmat.2021.125540.
Ramesh, B. A., and B. Kondraivendhan. 2020. “Effect of accelerated carbonation on the performance of concrete containing natural zeolite.” J. Mater. Civ. Eng. 32 (4): 04020037. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003050.
Shahid, M., S. Maiti, R. V. Adivarekar, and S. Liu. 2022. “Biomaterial based fabrication of superhydrophobic textiles–A review.” Mater. Today Chem. 24 (Jun): 100940. https://doi.org/10.1016/j.mtchem.2022.100940.
Song, J., Y. Li, W. Xu, H. Liu, and Y. Lu. 2019. “Inexpensive and non-fluorinated superhydrophobic concrete coating for anti-icing and anti-corrosion.” J. Colloid Interface Sci. 541 (Aug): 86–92. https://doi.org/10.1016/j.jcis.2019.01.014.
Song, J., D. Zhao, Z. Han, W. Xu, Y. Lu, X. Liu, B. Liu, C. J. Carmalt, X. Deng, and I. P. Parkin. 2017. “Super-robust superhydrophobic concrete.” J. Mater. Chem. A 5 (28): 14542–14550. https://doi.org/10.1039/C7TA03526H.
Song, Q., Q. Wang, S. Xu, J. Mao, X. Li, and Y. Zhao. 2022a. “Properties of water-repellent concrete mortar containing superhydrophobic oyster shell powder.” Constr. Build. Mater. 337 (Jun): 127423. https://doi.org/10.1016/j.conbuildmat.2022.127423.
Song, W., Q. Wang, L. Qu, X. Li, and S. Xu. 2022b. “Study of water absorption and corrosion resistance of the mortar with waste marble powder.” Constr. Build. Mater. 345 (Aug): 128235. https://doi.org/10.1016/j.conbuildmat.2022.128235.
Tian, T., Y. Yan, Z. Hu, Y. Xu, Y. Chen, and J. Shi. 2016. “Utilization of original phosphogypsum for the preparation of foam concrete.” Constr. Build. Mater. 115 (Jun): 143–152. https://doi.org/10.1016/j.conbuildmat.2016.04.028.
Wang, N., Q. Wang, and S. Xu. 2021a. “A review on applications of superhydrophobic materials in civil engineering.” Adv. Eng. Mater. 24 (6): 2101238. https://doi.org/10.1002/adem.202101238.
Wang, Q., S. Xu, X. Xing, and N. Wang. 2021b. “Progress in fabrication and applications of micro/nanostructured superhydrophobic surfaces.” Surf. Innovations 10 (2): 89–110. https://doi.org/10.1680/jsuin.21.00031.
Wang, W., S. Wang, D. Yao, X. Wang, X. Yu, and Y. Zhang. 2020. “Fabrication of all-dimensional superhydrophobic mortar with enhanced waterproof ability and freeze-thaw resistance.” Constr. Build. Mater. 238 (Mar): 117626. https://doi.org/10.1016/j.conbuildmat.2019.117626.
Wei, Q., X. Liu, and X. Zhang. 2018. “Facile preparation of mechanically robust superhydrophobic concrete with self-cleaning property.” Mater. Res. Express 6 (1): 015001. https://doi.org/10.1088/2053-1591/aae2a6.
Wu, Y., L. Dong, X. Shu, Y. Yang, W. She, and Q. Ran. 2022. “A review on recent advances in the fabrication and evaluation of superhydrophobic concrete.” Composites Part B 237 (May): 109867. https://doi.org/10.1016/j.compositesb.2022.109867.
Xu, K., S. Ren, J. Song, J. Liu, Z. Liu, J. Sun, and S. Ling. 2021. “Colorful superhydrophobic concrete coating.” Chem. Eng. J. 403 (Jan): 126348. https://doi.org/10.1016/j.cej.2020.126348.
Xu, S., Q. Wang, and N. Wang. 2020. “Chemical fabrication strategies for achieving bioinspired superhydrophobic surfaces with micro and nanostructures: A review.” Adv. Eng. Mater. 23 (3): 2001083. https://doi.org/10.1002/adem.202001083.
Yang, H., W. Li, X. Liu, A. Liu, P. Hang, R. Ding, T. Li, Y. Zhang, W. Wang, and C. Xiong. 2019. “Preparation of corrosion inhibitor loaded zeolites and corrosion resistance of carbon steel in simulated concrete pore solution.” Constr. Build. Mater. 225 (Nov): 90–98. https://doi.org/10.1016/j.conbuildmat.2019.07.141.
Zhang, H., Y. Cheng, L. Yang, and W. Song. 2020. “Modification of lime-fly ash-crushed stone with phosphogypsum for road base.” Adv. Civ. Eng. 2020 (Nov): 1–7. https://doi.org/10.1155/2020/8820522.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 36Issue 9September 2024

History

Received: Nov 8, 2023
Accepted: Feb 21, 2024
Published online: Jun 18, 2024
Published in print: Sep 1, 2024
Discussion open until: Nov 18, 2024

Permissions

Request permissions for this article.

Authors

Affiliations

Xiaoya Zhuo [email protected]
Master’s Student, College of Civil Engineering and Architecture, Shandong Univ. of Science and Technology, Shandong 266590, China. Email: [email protected]
Professor, College of Mechanical and Architectural Engineering, Taishan Univ., Shandong 271000, China (corresponding author). ORCID: https://orcid.org/0000-0001-7228-6472. Email: [email protected]
Ph.D. Candidate, College of Civil Engineering and Architecture, Shandong Univ. of Science and Technology, Shandong 266590, China. Email: [email protected]
Ph.D. Candidate, College of Civil Engineering and Architecture, Shandong Univ. of Science and Technology, Shandong 266590, China. Email: [email protected]
Lecturer, College of Mechanical and Architectural Engineering, Taishan Univ., Shandong 271000, China. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share