Abstract

Partial replacement of portland cement with supplementary cementitious materials (SCMs), such as fly ash, is an effective strategy for improving durability and reducing the CO2 footprint of concrete. However, using high-volume fly ash (HVFA) binders in precast and prestressed concrete is currently limited; largely due to reduced early-age strength development that impedes rapid production and prestressing of precast concrete. To investigate and address this challenge, HVFA mortars with a minimum of 40% fly ash by mass of cementitious materials were developed and tested in this study. Two fresh fly ashes (an ASTM C618 Class F and a Class C) and a landfilled fly ash (Class F) were included. Various strategies for improving the early strength were evaluated, including gypsum optimization, chemical accelerators, steam curing, use of CSA cements, and adding other reactive SCMs like silica fume, calcined clay, and slag cement. Steam curing and the use of CSA cement at high dosages (40% of total binder) were found to be the most successful strategies across all three fly ashes. Additionally, significant improvements were observed with gypsum optimization (for Class C fly ash) and the use of accelerators (for Class F fly ashes), and these strategies are likely to be more feasible considering later-age strength and economic viability. Interestingly, HVFA mixtures made with the landfilled fly ash used in this study were able to achieve high early strengths with water-to-cementitious materials ratio adjustment alone. These HVFA mixtures were also found to be less responsive to accelerators when compared to the fresh Class F fly ash, highlighting an important distinction between the materials despite the similarity in chemical composition.

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Data Availability Statement

All data, models, and code generated or used during the study appear in the published article. Additional information is available from Sao (2022).

Acknowledgments

This material is based upon work supported by the Department of Energy under Award Number DE-FE0031931. This publication was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof. The authors are grateful for the input provided by Dr. John Fox throughout the project duration.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 36Issue 10October 2024

History

Received: Oct 26, 2023
Accepted: Feb 23, 2024
Published online: Jul 31, 2024
Published in print: Oct 1, 2024
Discussion open until: Dec 31, 2024

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Zacharia Sao [email protected]
Associate Transmissions Line Engineer, Sargent & Lundy, 401 Chestnut St., Ste 500, Chattanooga, TN 37402. Email: [email protected]
Senior Researcher, USG Corporation, 700 N US 45, Libertyville, IL 60060. ORCID: https://orcid.org/0000-0001-8728-8657. Email: [email protected]
Assistant Professor, Dept. of Civil and Environmental Engineering, Konkuk Univ., 120 Neungdong-ro, Gwangjin-gu, Seoul 05029, Republic of Korea. ORCID: https://orcid.org/0000-0003-4451-0953. Email: [email protected]
Postdoctoral Scientist, Dept. of Civil and Environmental Engineering, Pennsylvania State Univ., University Park, PA 16802. ORCID: https://orcid.org/0000-0003-0289-4872. Email: [email protected]
Professor and Interim Head, Dept. of Civil and Environmental Engineering, Pennsylvania State Univ., 212 Sackett Bldg., University Park, PA 16802 (corresponding author). ORCID: https://orcid.org/0000-0002-6616-0539. Email: [email protected]
Assistant Professor, Dept. of Civil, Architectural and Environmental Engineering, Illinois Institute of Technology, Chicago, IL 60616. ORCID: https://orcid.org/0000-0002-4782-5929. Email: [email protected]

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