Technical Papers
Apr 25, 2024

Influence of Waste Coral Powder on the Properties of Alkali-Activated Slag Cement Prepared with Seawater

Publication: Journal of Materials in Civil Engineering
Volume 36, Issue 7

Abstract

In this paper, alkali-activated materials (AAMs) were prepared combining waste coral powder (CP) and blast furnace slag (BFS) as precursors, artificial seawater and deionized water as mixing water, and blends of NaOH and sodium silicate solution as alkaline activators. The effect of CP and seawater on the fluidity, mechanical properties, and hydration was discussed. The experimental results showed that a 15% CP content effectively improved the fluidity of fresh paste while having little effect on compressive strength of the samples. Compared with deionized water, the use of seawater for sample preparation resulted in a reduction of the fluidity and mechanical properties of the samples. The pore structure could be refined by CP and seawater, but gel micropores increased significantly when the CP content reached 25%. The use of CP and seawater did not cause significant changes in the type of hydration products. Although the amount of hydration products in the early stages of the samples prepared with seawater was relatively low compared with those prepared with deionized water, it gradually surpassed that in samples prepared with deionized water with increasing curing time. Increasing the CP content led to a higher reaction degree, and a CP content of 25% resulted in a reaction degree of approximately 30%–50%, which was roughly twice that of a sample containing 5% CP. These findings have important implications for the development of sustainable construction materials for utilization in marine engineering.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

All data, models, and code generated or used during the study appear in the published paper.

Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 52378280) and the Natural Science Foundation of Guangdong Province (No. 2019A1515011981). The authors thank Jiawei Jiang from Shiyanjia Lab (www.shiyanjia.com) for the mercury intrusion porosimetry (MIP) test.

References

Abdalqader, A. F., F. Jin, and A. Al-Tabbaa. 2015. “Characterisation of reactive magnesia and sodium carbonate-activated fly ash/slag paste blends.” Constr. Build. Mater. 93 (Sep): 506–513. https://doi.org/10.1016/j.conbuildmat.2015.06.015.
Adu-Amankwah, S., M. Zajac, C. Stabler, B. Lothenbach, and L. Black. 2017. “Influence of limestone on the hydration of ternary slag cements.” Cem. Concr. Res. 100 (Oct): 96–109. https://doi.org/10.1016/j.cemconres.2017.05.013.
Alarcon-Ruiz, L., G. Platret, E. Massieu, and A. Ehrlacher. 2005. “The use of thermal analysis in assessing the effect of temperature on a cement paste.” Cem. Concr. Res. 35 (3): 609–613. https://doi.org/10.1016/j.cemconres.2004.06.015.
Ammari, M. S., M. B. Tobchi, Y. Amrani, A. Mim, M. Bederina, and A. Ferhat. 2023. “Influence of glass powder incorporation on the physical-mechanical properties of sand concrete.” World J. Eng. 20 (2): 314–324. https://doi.org/10.1108/WJE-08-2021-0474.
ASTM. 2013. Standard practice for the preparation of substitute ocean water. ASTM D1141-98. West Conshohocken, PA: ASTM.
Bakolas, A., E. Aggelakopoulou, A. Moropoulou, and S. Anagnostopoulou. 2006. “Evaluation of pozzolanic activity and physicomechanical characteristics in metakaolin-lime pastes.” J. Therm. Anal. Calorim. 84 (1): 157–163. https://doi.org/10.1007/s10973-005-7262-y.
Ben Haha, M., G. Le Saout, F. Winnefeld, and B. Lothenbach. 2011. “Influence of activator type on hydration kinetics, hydrate assemblage and microstructural development of alkali activated blast-furnace slags.” Cem. Concr. Res. 41 (3): 301–310. https://doi.org/10.1016/j.cemconres.2010.11.016.
Bian, Z., G. Jin, and T. Ji. 2021. “Effect of combined activator of Ca(OH)2 and Na2CO3 on workability and compressive strength of alkali-activated ferronickel slag system.” Cem. Concr. Compos. 123 (Oct): 104179. https://doi.org/10.1016/j.cemconcomp.2021.104179.
Brough, A. R., and A. Atkinson. 2002. “Sodium silicate-based, alkali-activated slag mortars: Part I. Strength, hydration and microstructure.” Cem. Concr. Res. 32 (6): 865–879. https://doi.org/10.1016/S0008-8846(02)00717-2.
Brough, A. R., M. Holloway, J. Sykes, and A. Atkinson. 2000. “Sodium silicate-based alkali-activated slag mortars: Part II. The retarding effect of additions of sodium chloride or malic acid.” Cem. Concr. Res. 30 (9): 1375–1379. https://doi.org/10.1016/S0008-8846(00)00356-2.
Cao, Y., J. Bao, P. Zhang, Y. Sun, and Y. Cui. 2022. “A state-of-the-art review on the durability of seawater coral aggregate concrete exposed to marine environment.” J. Build. Eng. 60 (Aug): 105199. https://doi.org/10.1016/j.jobe.2022.105199.
Chinese Standard. 2001. Test methods for water requirement of normal consistency, setting time and soundness of the Portland cement. GB/T 1346-2001. Beijing: Standardization Administration of China.
Chinese Standard. 2004. Standard test method for drying shrinkage of mortar. JC/T 603-2004. Beijing: China Building Materials Academy.
Chinese Standard. 2012. Methods for testing uniformity of concrete admixture. GB/T 8077-2012. Beijing: Standardization Administration of China.
Da, B., Y. Chen, H. Yu, H. Ma, D. Chen, Z. Wu, J. Liu, and Y. Li. 2022. “Preparation technology, mechanical properties and durability of coral aggregate seawater concrete in the island-reef environment.” J. Cleaner Prod. 339 (Mar): 130572. https://doi.org/10.1016/j.jclepro.2022.130572.
Dai, X., S. Aydin, M. Yücel Yardimci, R. E. N. Qiang, K. Lesage, and G. De Schutter. 2021. “Rheology, early-age hydration and microstructure of alkali-activated GGBFS-Fly ash-limestone mixtures.” Cem. Concr. Compos. 124 (Nov): 104244. https://doi.org/10.1016/j.cemconcomp.2021.104244.
De’nan, F., M. A. Megat Johari, S. C. Anak Nyandau, and N. S. Hashim. 2023. “The influence of palm oil fuel ash and metakaolin on the strength of concrete and crack resistance of reinforced concrete beam: A review.” World J. Eng. 20 (5): 989–1000. https://doi.org/10.1108/WJE-01-2022-0010.
Ebead, U., D. Lau, F. Lollini, A. Nanni, P. Suraneni, and T. Yu. 2022. “A review of recent advances in the science and technology of seawater-mixed concrete.” Cem. Concr. Res. 152 (Feb): 106666. https://doi.org/10.1016/j.cemconres.2021.106666.
El-Didamony, H., A. A. Amer, and H. Abd Ela-Ziz. 2012. “Properties and durability of alkali-activated slag pastes immersed in sea water.” Ceram. Int. 38 (5): 3773–3780. https://doi.org/10.1016/j.ceramint.2012.01.024.
Fu, Q., Z. Zhang, X. Zhao, M. Hong, B. Guo, Q. Yuan, and D. Niu. 2021. “Water saturation effect on the dynamic mechanical behaviour and scaling law effect on the dynamic strength of coral aggregate concrete.” Cem. Concr. Compos. 120 (Jul): 104034. https://doi.org/10.1016/j.cemconcomp.2021.104034.
Guo, X., C. Xiong, Z. Jin, and B. Pang. 2022. “A review on mechanical properties of FRP bars subjected to seawater sea sand concrete environmental effects.” J. Build. Eng. 58 (Aug): 105038. https://doi.org/10.1016/j.jobe.2022.105038.
Gupta, T., and M. Chakradhara Rao. 2023. “Effect on properties of geopolymer concrete by inclusion of recycled aggregate and methods to enhance the packing density of aggregate.” World J. Eng. https://doi.org/10.1108/WJE-04-2023-0088.
Hu, X., J. Xiao, K. Zhang, and Q. Zhang. 2022. “The state-of-the-art study on durability of FRP reinforced concrete with seawater and sea sand.” J. Build. Eng. 51 (Jul): 104294. https://doi.org/10.1016/j.jobe.2022.104294.
Huang, B.-T., J.-Q. Wu, J. Yu, J.-G. Dai, C. K. Y. Leung, and V. C. Li. 2021. “Seawater sea-sand engineered/strain-hardening cementitious composites (ECC/SHCC): Assessment and modeling of crack characteristics.” Cem. Concr. Res. 140 (Feb): 106292. https://doi.org/10.1016/j.cemconres.2020.106292.
Jiao, D., C. Shi, Q. Yuan, X. An, Y. Liu, and H. Li. 2017. “Effect of constituents on rheological properties of fresh concrete—A review.” Cem. Concr. Compos. 83 (Oct): 146–159. https://doi.org/10.1016/j.cemconcomp.2017.07.016.
Jin, F., K. Gu, and A. Al-Tabbaa. 2015. “Strength and hydration properties of reactive MgO-activated ground granulated blastfurnace slag paste.” Cem. Concr. Compos. 57 (Mar): 8–16. https://doi.org/10.1016/j.cemconcomp.2014.10.007.
Juenger, M. C. G., P. J. M. Monteiro, E. M. Gartner, and G. P. Denbeaux. 2005. “A soft X-ray microscope investigation into the effects of calcium chloride on tricalcium silicate hydration.” Cem. Concr. Res. 35 (1): 19–25. https://doi.org/10.1016/j.cemconres.2004.05.016.
Jun, Y., T. Kim, and J. H. Kim. 2020. “Chloride-bearing characteristics of alkali-activated slag mixed with seawater: Effect of different salinity levels.” Cem. Concr. Compos. 112 (Sep): 103680. https://doi.org/10.1016/j.cemconcomp.2020.103680.
Kabay, N., M. M. Tufekci, A. B. Kizilkanat, and D. Oktay. 2015. “Properties of concrete with pumice powder and fly ash as cement replacement materials.” Constr. Build. Mater. 85 (Jun): 1–8. https://doi.org/10.1016/j.conbuildmat.2015.03.026.
Kaushik, S. K., and S. Islam. 1995. “Suitability of sea water for mixing structural concrete exposed to a marine environment.” Cem. Concr. Compos. 17 (3): 177–185. https://doi.org/10.1016/0958-9465(95)00015-5.
Kim, M. S., Y. Jun, C. Lee, and J. E. Oh. 2013. “Use of CaO as an activator for producing a price-competitive non-cement structural binder using ground granulated blast furnace slag.” Cem. Concr. Res. 54 (Dec): 208–214. https://doi.org/10.1016/j.cemconres.2013.09.011.
Lee, J., and T. Lee. 2020. “Durability and engineering performance evaluation of CaO content and ratio of binary blended concrete containing ground granulated blast-furnace slag.” Appl. Sci. 10 (7): 2504. https://doi.org/10.3390/app10072504.
Li, F., B. Zhang, H. Zhu, Q. Wang, and J. Ji. 2022. “Axial compressive behavior of GFRP-confined seawater coral aggregate concrete incorporating slag-based alkali-activated materials.” Constr. Build. Mater. 347 (Sep): 128437. https://doi.org/10.1016/j.conbuildmat.2022.128437.
Li, L. G., X. Q. Chen, S. H. Chu, Y. Ouyang, and A. K. H. Kwan. 2019. “Seawater cement paste: Effects of seawater and roles of water film thickness and superplasticizer dosage.” Constr. Build. Mater. 229 (Dec): 116862. https://doi.org/10.1016/j.conbuildmat.2019.116862.
Li, Z., T. Lu, X. Liang, H. Dong, and G. Ye. 2020. “Mechanisms of autogenous shrinkage of alkali-activated slag and fly ash pastes.” Cem. Concr. Res. 135 (Sep): 106107. https://doi.org/10.1016/j.cemconres.2020.106107.
Luukkonen, T., H. Sreenivasan, Z. Abdollahnejad, J. Yliniemi, A. Kantola, V.-V. Telkki, P. Kinnunen, and M. Illikainen. 2020. “Influence of sodium silicate powder silica modulus for mechanical and chemical properties of dry-mix alkali-activated slag mortar.” Constr. Build. Mater. 233 (Feb): 117354. https://doi.org/10.1016/j.conbuildmat.2019.117354.
Lv, W., Z. Sun, and Z. Su. 2020. “Study of seawater mixed one-part alkali activated GGBFS-fly ash.” Cem. Concr. Compos. 106 (Feb): 103484. https://doi.org/10.1016/j.cemconcomp.2019.103484.
Lyu, B., A. Wang, Z. Zhang, K. Liu, H. Xu, L. Shi, and D. Sun. 2019. “Coral aggregate concrete: Numerical description of physical, chemical and morphological properties of coral aggregate.” Cem. Concr. Compos. 100 (Jul): 25–34. https://doi.org/10.1016/j.cemconcomp.2019.03.016.
Lyu, X., N. Robinson, M. Elchalakani, M. L. Johns, M. Dong, and S. Nie. 2022. “Sea sand seawater geopolymer concrete.” J. Build. Eng. 50 (Jun): 104141. https://doi.org/10.1016/j.jobe.2022.104141.
Ma, H., H. Zhu, C. Wu, H. Chen, J. Sun, and J. Liu. 2020. “Study on compressive strength and durability of alkali-activated coal gangue-slag concrete and its mechanism.” Powder Technol. 368 (May): 112–124. https://doi.org/10.1016/j.powtec.2020.04.054.
Mirouzi, G., and A. Houda. 2023. “Effect of mineral additions on the mechanical behavior of polymer concretes.” World J. Eng. https://doi.org/10.1108/WJE-12-2022-0513.
Pan, D., S. A. Yaseen, K. Chen, D. Niu, C. K. Y. Leung, and Z. Li. 2021. “Study of the influence of seawater and sea sand on the mechanical and microstructural properties of concrete.” J. Build. Eng. 42 (Oct): 103006. https://doi.org/10.1016/j.jobe.2021.103006.
Puligilla, S., and P. Mondal. 2013. “Role of slag in microstructural development and hardening of fly ash-slag geopolymer.” Cem. Concr. Res. 43 (Jan): 70–80. https://doi.org/10.1016/j.cemconres.2012.10.004.
Qu, F., W. Li, K. Wang, V. W. Y. Tam, and S. Zhang. 2021. “Effects of seawater and undesalted sea sand on the hydration products, mechanical properties and microstructures of cement mortar.” Constr. Build. Mater. 310 (Dec): 125229. https://doi.org/10.1016/j.conbuildmat.2021.125229.
Rashad, A. M. 2022. “Effect of limestone powder on the properties of alkali-activated materials—A critical overview.” Constr. Build. Mater. 356 (Nov): 129188. https://doi.org/10.1016/j.conbuildmat.2022.129188.
Ren, J., H. Sun, K. Cao, Z. Ren, B. Zhou, W. Wu, and F. Xing. 2021. “Effects of natural seawater mixing on the properties of alkali-activated slag binders.” Constr. Build. Mater. 294 (Aug): 123601. https://doi.org/10.1016/j.conbuildmat.2021.123601.
Saleh, F., M. A. Gunawan, T. I. Yolanda, F. Monika, H. Prayuda, M. D. Cahyati, and M. M. A. Pratama. 2023. “Properties of mortar made with bottom ash and silica fume as sustainable construction materials.” World J. Eng. 20 (5): 835–845. https://doi.org/10.1108/WJE-08-2021-0481.
Sharqawy, M. H., J. H. Lienhard, and S. M. Zubair. 2012. “Thermophysical properties of seawater: A review of existing correlations and data.” Desalin. Water Treat. 16 (1–3): 354–380. https://doi.org/10.5004/DWT.2010.1079.
Shi, D., Y. Yao, J. Ye, and W. Zhang. 2019. “Effects of seawater on mechanical properties, mineralogy and microstructure of calcium silicate slag-based alkali-activated materials.” Constr. Build. Mater. 212 (Jul): 569–577. https://doi.org/10.1016/j.conbuildmat.2019.03.288.
Shi, H., Q. Wu, Z. Yu, J. Ma, and X. Shen. 2020. “Properties of eco-friendly coral sand powder—Calcium sulfoaluminate cement binary system.” Constr. Build. Mater. 263 (Dec): 120181. https://doi.org/10.1016/j.conbuildmat.2020.120181.
Song, S., and H. M. Jennings. 1999. “Pore solution chemistry of alkali-activated ground granulated blast-furnace slag.” Cem. Concr. Res. 29 (2): 159–170. https://doi.org/10.1016/S0008-8846(98)00212-9.
Song, S., D. Sohn, H. M. Jennings, and T. O. Mason. 2000. “Hydration of alkali-activated ground granulated blast furnace slag.” J. Mater. Sci. 35 (Jan): 249–257. https://doi.org/10.1023/A:1004742027117.
Su, Y., Z. Xiong, Z. Hu, W. Zhu, K. Zhou, J. Wang, F. Liu, and L. Li. 2022. “Dynamic bending study of glass fiber reinforced seawater and sea-sand concrete incorporated with expansive agents.” Constr. Build. Mater. 358 (Dec): 129415. https://doi.org/10.1016/j.conbuildmat.2022.129415.
Wang, F., J. Hua, X. Xue, N. Wang, F. Yan, and D. Feng. 2023a. “Effect of superfine cement modification on properties of coral aggregate concrete.” Materials 16 (3): 1103. https://doi.org/10.3390/ma16031103.
Wang, F., J. Hua, X. Xue, N. Wang, and Y. Yao. 2022. “Effects of polyoxymethylene fiber on mechanical properties of seawater sea-sand concrete with different ages.” Polymers 14 (17): 3472. https://doi.org/10.3390/polym14173472.
Wang, F., Y. Sun, X. Xue, N. Wang, J. Zhou, and J. Hua. 2023b. “Mechanical properties of modified coral aggregate seawater sea-sand concrete: Experimental study and constitutive model.” Case Stud. Constr. Mater. 18 (Jul): e02095. https://doi.org/10.1016/J.CSCM.2023.E02095.
Wang, F., X. Xue, J. Hua, N. Wang, and Y. Yao. 2023c. “Properties of polyoxymethylene fibre-reinforced seawater sea sand concrete exposed to high temperatures.” Constr. Build. Mater. 409 (Dec): 133854. https://doi.org/10.1016/j.conbuildmat.2023.133854.
Wang, J., X. Lyu, L. Wang, X. Cao, Q. Liu, and H. Zang. 2018. “Influence of the combination of calcium oxide and sodium carbonate on the hydration reactivity of alkali-activated slag binders.” J. Cleaner Prod. 171 (Jan): 622–629. https://doi.org/10.1016/j.jclepro.2017.10.077.
Wei, J., B. Cheng, L. Li, W.-J. Long, and K. H. Khayat. 2023. “Prediction of dynamic mechanical behaviors of coral concrete under different corrosive environments and its enhancement mechanism.” J. Build. Eng. 63 (Jan): 105507. https://doi.org/10.1016/j.jobe.2022.105507.
Wu, Z., H. Yu, H. Ma, J. Zhang, and B. Da. 2022. “Physical and mechanical properties of coral aggregates in the South China Sea.” J. Build. Eng. 63 (Jan): 105478. https://doi.org/10.1016/J.JOBE.2022.105478.
Xue, X., F. Wang, J. Hua, N. Wang, L. Huang, Z. Chen, and Y. Yao. 2022. “Effects of polyoxymethylene fiber on fresh and hardened properties of seawater sea-sand concrete.” Polymers 14 (22): 4969. https://doi.org/10.3390/polym14224969.
Ye, H., and A. Radlińska. 2016. “Shrinkage mechanisms of alkali-activated slag.” Cem. Concr. Res. 88 (Oct): 126–135. https://doi.org/10.1016/j.cemconres.2016.07.001.
Yi, Y., D. Zhu, S. Guo, S. Li, G. Feng, Z. Liu, L. Zhou, and C. Shi. 2022. “Development of a low-alkalinity seawater sea sand concrete for enhanced compatibility with BFRP bar in the marine environment.” Cem. Concr. Compos. 134 (Nov): 104778. https://doi.org/10.1016/j.cemconcomp.2022.104778.
Yuan, B., Q. L. Yu, E. Dainese, and H. J. H. Brouwers. 2017. “Autogenous and drying shrinkage of sodium carbonate activated slag altered by limestone powder incorporation.” Constr. Build. Mater. 153 (Oct): 459–468. https://doi.org/10.1016/j.conbuildmat.2017.07.112.
Zhang, X., K. Wei, J. Zuo, Y. Zhou, and Y. Hu. 2022. “Effects of admixtures on the mechanical characteristics and microstructure of coral aggregate mortar.” J. Build. Eng. 60 (Nov): 105182. https://doi.org/10.1016/j.jobe.2022.105182.
Zhu, X., X. Kang, J. Deng, K. Yang, S. Jiang, and C. Yang. 2021. “Chemical and physical effects of high-volume limestone powder on sodium silicate-activated slag cement (AASC).” Constr. Build. Mater. 292 (Jul): 123257. https://doi.org/10.1016/j.conbuildmat.2021.123257.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 36Issue 7July 2024

History

Received: Sep 25, 2023
Accepted: Dec 28, 2023
Published online: Apr 25, 2024
Published in print: Jul 1, 2024
Discussion open until: Sep 25, 2024

Permissions

Request permissions for this article.

ASCE Technical Topics:

Authors

Affiliations

Ph.D. Student, School of Civil Engineering, Sun Yat-Sen Univ. & Southern Marine Science and Engineering Guangdong Laboratory, Zhuhai 519082, China. Email: [email protected]
Associate Professor, School of Civil Engineering, Sun Yat-Sen Univ. & Southern Marine Science and Engineering Guangdong Laboratory, Zhuhai 519082, China (corresponding author). Email: [email protected]
Ph.D. Student, College of Resources and Civil Engineering, Northeastern Univ., Shenyang 110819, China. Email: [email protected]
Master’s Student, School of Civil Engineering, Sun Yat-Sen Univ. & Southern Marine Science and Engineering Guangdong Laboratory, Zhuhai 519082, China. Email: [email protected]
Gangqiang Yang [email protected]
Master’s Student, School of Civil Engineering, Sun Yat-Sen Univ. & Southern Marine Science and Engineering Guangdong Laboratory, Zhuhai 519082, China. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share