Abstract

This research aims to investigate the impact of short- and long-term aging on the chemo-physical properties of various conventional and modified asphalt binders. The study incorporates different technologies, namely, polymers, rubber, nano, and antiaging modifiers with a combination of 11 original (unaged) asphalt binders, which were short-term aged in the rolling thin film oven, and then long-term aged in the pressure aging vessel (PAV). A comparison between the set of unaged and the two sets of aged asphalt binders was carried out using series of physical and rheological laboratory tests as well as two chemical analyses. Measured laboratory data for the three sets (33 asphalt binders) was used to study the interrelationships between the selected aging indices (AIs) using regression analysis. Results showed that styrene butadiene styrene polymer modified asphalt was one of the best asphalt binders to resist physical changes but fell in the middle range when tested chemically. The carbon nano tubes modified asphalt binder showed great resistance to aging physically and chemically. Although most antioxidant modified binders generally perform better than conventional ones in terms of aging resistance, furfural antioxidant modified asphalt showed poor resistance to rheological changes after aging, while it was superior to resist PAV aging by means of chemical analysis. According to the relationships for long-term aging indices, complex shear moduli at high and intermediate temperatures correlated the most with other physical and rheological parameters. Nonetheless, rotational viscosity and creep compliance (Jnr) correlated the most with other parameters for short-term aging. Finally, the AI of carbonyl chemical group (ICO) from the Fourier infrared spectrometry had poor correlations with most rheological indices at all aging levels. ICO was found to have fair to good correlations with Jnr and linear amplitude sweep test parameters after PAV aging.

Practical Applications

Asphalt binders play a crucial role in the performance and durability of asphalt pavements. Over time, asphalt binders undergo aging, which leads to changes in their rheological properties and chemical interactions. Understanding the effects of aging on asphalt binders is essential for designing long-lasting and sustainable road infrastructure. The study specifically focuses on asphalt binder’s aging incorporating different technologies. It sheds light on the complexities of asphalt binder aging and offers valuable insights for pavement design. The research outcomes provide deeper understanding of how different modifiers and aging conditions influence the chemo-physical properties of different asphalt binders, ultimately contributing to the development of more robust and sustainable pavement designs.

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Data Availability Statement

Some or all data or models that support the findings of this study are available from the corresponding author upon reasonable request.

References

Adwani, D., A. Sreeram, G. Pipintakos, J. Mirwald, Y. Wang, R. Hajj, R. Jing, and A. Bhasin. 2023. “Interpreting the effectiveness of antioxidants to increase the resilience of asphalt binders: A global interlaboratory study.” Constr. Build. Mater. 366 (Feb): 130231. https://doi.org/10.1016/j.conbuildmat.2022.130231.
Airey, G. D. 2002. “Use of black diagrams to identify inconsistencies in rheological data.” Road Mater. Pavement Des. 3 (4): 403–424. https://doi.org/10.1080/14680629.2002.9689933.
Alani, M. W., W. Zeiada, G. Al-Khateeb, H. Ezzat, and A. Shanableh. 2021. “Investigating the cracking resistance of asphalt binder in the UAE using styrene-butadiene-styrene polymer.” IOP Conf. Ser.: Earth Environ. Sci. 798 (1): 012016. https://doi.org/10.1088/1755-1315/798/1/012016.
Ali, A. H., N. S. Mashaan, and M. R. Karim. 2012. “Investigation on aging resistance of rubberized bitumen binder.” Int. J. Environ. Bioenergy 2 (1): 33–41.
Ali, A. H., N. S. Mashaan, and M. R. Karim. 2013. “Investigations of physical and rheological properties of aged rubberised bitumen.” Adv. Mater. Sci. Eng. 2013 (Feb): 239036. https://doi.org/10.1155/2013/239036.
Alnaqbi, A., W. Zeiada, G. Al-Khateeb, H. Ezzat, and A. Shanableh. 2021. “Effect of styrene-butadiene-styrene on the properties and grading of local asphalt binder in the UAE.” IOP Conf. Ser.: Mater. Sci. Eng. 1044 (1): 012003. https://doi.org/10.1088/1757-899X/1044/1/012003.
Al-Sabaeei, A. M., M. Napiah, M. Sutanto, W. Alaloul, N. I. Md Yusoff, M. Imran Khan, and S. Modibbo Saeed. 2021. “Physicochemical, rheological and microstructural properties of nano-silica modified bio-asphalt.” Constr. Build. Mater. 297 (Aug): 123772. https://doi.org/10.1016/j.conbuildmat.2021.123772.
Apeagyei, A. K. 2011. “Laboratory evaluation of antioxidants for asphalt binders.” Constr. Build. Mater. 25 (1): 47–53. https://doi.org/10.1016/j.conbuildmat.2010.06.058.
Ashish, P. K., and D. Singh. 2020. “Study on understanding functional characteristics of multi-wall CNT modified asphalt binder.” Int. J. Pavement Eng. 21 (9): 1069–1082. https://doi.org/10.1080/10298436.2018.1519190.
ASTM. 2014. Standard practice for determining the separation tendency of polymer from polymer-modified asphalt. ASTM D7173. West Conshohocken, PA: ASTM.
ASTM. 2019a. Standard practice for accelerated aging of asphalt binder using a pressurized aging vessel (PAV). ASTM D6521. West Conshohocken, PA: ASTM.
ASTM. 2019b. Standard test method for effect of heat and air on a moving film of asphalt (rolling thin-film oven test). ASTM D2872. West Conshohocken, PA: ASTM.
Camargo, I., B. Hofko, and J. Mirwald. 2022. “Effect of DLTDP and furfural on asphalt binders: Optimal dosage and PG grading.” Constr. Build. Mater. 314 (Jan): 125489. https://doi.org/10.1016/j.conbuildmat.2021.125489.
Chen, R., H. Zhu, L. Kong, Y. Xu, and L. Ou. 2023. “Stage-aging characteristics and stages division of crumb rubber modified asphalt binder.” Constr. Build. Mater. 367 (Feb): 129712. https://doi.org/10.1016/j.conbuildmat.2022.129712.
Chen, Z., H. Zhang, C. Zhu, and B. Zhao. 2015. “Rheological examination of aging in bitumen with inorganic nanoparticles and organic expanded vermiculite.” Constr. Build. Mater. 101 (Dec): 884–891. https://doi.org/10.1016/j.conbuildmat.2015.10.153.
Chiu, C.-T., M. Tia, B. E. Ruth, and G. C. Page. 1994. “Investigation of laboratory aging processes of asphalt binders used in Florida.” In Vol. 1436 Transportation Research Record, 60–70. Washington, DC: Transportation Research Board.
Cong, P., J. Wang, K. Li, and S. Chen. 2012. “Physical and rheological properties of asphalt binders containing various antiaging agents.” Fuel 97 (Jul): 678–684. https://doi.org/10.1016/j.fuel.2012.02.028.
Ding, Y., S. Zhang, X. Luo, and J. Zhou. 2023. “AFM characterization of morphological evolution and adhesion properties of ZnO/C nanosheet-modified asphalt under UV irradiation.” Surf. Topogr. Metrol. Prop. 11 (1): 015003. https://doi.org/10.1088/2051-672X/acaff6.
Edwards, Y., Y. Tasdemir, and U. Isacsson. 2005. “Influence of commercial waxes on bitumen aging properties.” Energy Fuels 19 (6): 2519–2525. https://doi.org/10.1021/ef050166r.
Ezzat, H., S. El-Badawy, A. Gabr, E.-S. I. Zaki, and T. Breakah. 2016. “Evaluation of asphalt binders modified with nanoclay and nanosilica.” Procedia Eng. 143 (Jul): 1260–1267. https://doi.org/10.1016/j.proeng.2016.06.119.
Ezzat, H., S. El-Badawy, A. Gabr, S. Zaki, T. Breakah, M. Arab, and W. Zeiada. 2023. “Nanomodified asphalt binders aging study and predicted performance under different climatic conditions using AASHTOWare.” J. Mater. Civ. Eng. 35 (6): 04023146. https://doi.org/10.1061/JMCEE7.MTENG-14997.
Fang, C., M. Zhang, Z. Zhang, and S. Zhou. 2009. “UV-aging resistance of packaging waste PE modified asphalts.” Polym. Plast. Technol. Eng. 48 (9): 945–949. https://doi.org/10.1080/03602550902995059.
Feng, Z., S. Xu, Y. Sun, and J. Yu. 2012. “Performance evaluation of SBS modified asphalt with different anti-aging additives.” J. Test. Eval. 40 (5): 728–733. https://doi.org/10.1520/JTE20120047.
Fini, E. H., F. S. Buabeng, T. Abu-Lebdeh, and F. Awadallah. 2016. “Effect of introduction of furfural on asphalt binder ageing characteristics.” Road Mater. Pavement Des. 17 (3): 638–657. https://doi.org/10.1080/14680629.2015.1108219.
Goosen, E. S., and K. J. Jenkins. 2023. “Understanding bitumen aging through interrelationships and aging ratios.” Transp. Res. Rec. 10 (2). https://doi.org/10.1177/03611981221147519.
Ismail, M., W. A. Zeiada, G. Al-Khateeb, and H. Ezzat. 2022. Rheological properties of rubber modified asphalt binder in the UAE, 1083–1097. Berlin: Springer.
Januszke, R. M. 1971. “Paving asphalt. Additives in durability determination.” Product R&D 10 (2): 209–214. https://doi.org/10.1021/i360038a021.
Johansson, L. S., J. F. Branthaver, and R. E. Robertson. 1996. “The influence of metal-containing compounds on enhancement and inhibition of asphalt oxidation.” Fuel Sci. Technol. Int. 14 (8): 1143–1159. https://doi.org/10.1080/08843759608947632.
Kassem, E., M. S. Khan, S. Katukuri, O. Sirin, A. Muftah, and F. Bayomy. 2019. “Retarding aging of asphalt binders using antioxidant additives and copolymers.” Int. J. Pavement Eng. 20 (10): 1154–1169. https://doi.org/10.1080/10298436.2017.1394098.
Knowles, E. C., and F. C. McCoy. 1943. “Surface consistency characteristics of asphalts.” Ind. Eng. Chem. 35 (10): 1118–1122. https://doi.org/10.1021/ie50406a022.
Lee, D. Y. 1973. Asphalt durability correlation in Iowa. Washington, DC: Highway Research Board.
Lesueur, D., and D. N. Little. 1999. “Effect of hydrated lime on rheology, fracture, and aging of bitumen.” Transp. Res. Rec. 1661 (1): 93–105. https://doi.org/10.3141/1661-14.
Li, Y., S. Wu, Q. Liu, Y. Dai, C. Li, H. Li, S. Nie, and W. Song. 2019. “Aging degradation of asphalt binder by narrow-band UV radiations with a range of dominant wavelengths.” Constr. Build. Mater. 220: 637–650. https://doi.org/10.1016/j.conbuildmat.2019.06.035.
Lim, C.-S., D.-S. Jang, S.-M. Yu, and J.-J. Lee. 2022. “Analysis of the properties of modified asphalt binder by FTIR method.” Materials 15 (16): 5743. https://doi.org/10.3390/ma15165743.
Liu, W., K. Yan, D. Ge, and M. Chen. 2018. “Effect of APAO on the aging properties of waste tire rubber modified asphalt binder.” Constr. Build. Mater. 175 (Jun): 333–341. https://doi.org/10.1016/j.conbuildmat.2018.04.098.
Lu, X., and U. Isacsson. 1998. “Chemical and rheological evaluation of ageing properties of SBS polymer modified bitumens.” Fuel 77 (9): 961–972. https://doi.org/10.1016/S0016-2361(97)00283-4.
Malinowski, S. 2023. “Aromatisation process as part of bitumen ageing in the light of electronic structure and further oxidation of its components.” Constr. Build. Mater. 366 (Feb): 130198. https://doi.org/10.1016/j.conbuildmat.2022.130198.
Mastrofini, D., and M. Scarsella. 2000. “The application of rheology to the evaluation of bitumen ageing.” Fuel 79 (9): 1005–1015. https://doi.org/10.1016/S0016-2361(99)00244-6.
Naderi, K., S. M. Asgharzadeh, N. Tabatabaee, and M. N. Partl. 2014. “Evaluating aging properties of crumb rubber and styrene–butadiene–styrene modified binders: Using double logistic master curve model.” Transp. Res. Rec. 2444 (1): 110–119. https://doi.org/10.3141/2444-13.
Onochie, A., E. Fini, X. Yang, J. Mills-Beale, and Z. You. 2013. “Rheological characterization of nano-particle based bio-modified binder.” In Proc., Transportation Research Board 92nd Annual Meeting, 125–131. Washington, DC: National Research Council.
Ouyang, C., S. Wang, Y. Zhang, and Y. Zhang. 2006. “Improving the aging resistance of asphalt by addition of zinc dialkyldithiophosphate.” Fuel 85 (7–8): 1060–1066. https://doi.org/10.1016/j.fuel.2005.08.023.
Peeri, N., J. Kister, L. Quoniam, J. P. Planche, and L. Germanaud. 1996. “Assessment of asphalt rheological behaviors by studying their aromatic structures.” Polycyclic Aromat. Compd. 9 (1–4): 29–36. https://doi.org/10.1080/10406639608031198.
Peng, C., J. Yu, J. Dai, and J. Yin. 2015. “Effect of Zn/Al layered double hydroxide containing 2-Hydroxy-4-n-octoxy-benzophenone on UV aging resistance of asphalt.” Adv. Mater. Sci. Eng. 2015 (Apr): 739831. https://doi.org/10.1155/2015/739831.
Poulikakos, L., D. Wang, L. Porot, and B. Hofko. 2019. “Impact of asphalt aging temperature on chemo-mechanics.” RSC Adv. 9 (21): 11602–11613. https://doi.org/10.1039/C9RA00645A.
Saleh, A., M. El-Shafie, G. ElKady, M. Wassel, and E. Ghally. 2013. “Performance enhancement of asphalt pavement.” Al-Azhar Bull. Sci. 24 (1): 157–168. https://doi.org/10.21608/absb.2013.6493.
Stroup-Gardiner, M., D. E. Newcomb, and B. Tanquist. 1993. “Asphalt-rubber interactions.” Transp. Res. Rec. 1417: 99.
Thomas, K. P., and P. Michael Harnsberger. 1996. “Evaluation of an Eastern shale oil residue as an asphalt additive.” Fuel Sci. Technol. Int. 14 (9): 1253–1280. https://doi.org/10.1080/08843759608947638.
Traxler, R. N. 1968. Hardening of asphalt cements by exposure to ultraviolet and short wave length visible light. Bryan, TX: Texas Transportation Institute.
Wan Azahar, W. N. A., M. Bujang, R. P. Jaya, M. R. Hainin, N. Ngadi, and A. M. M. Al Bakri. 2016. “Effect of antioxidant characteristic from waste cooking oil in modified asphalt binder.” Key Eng. Mater. 700 (Jul): 197–206. https://doi.org/10.4028/www.scientific.net/KEM.700.197.
Wang, H., X. Liu, P. Apostolidis, M. van de Ven, S. Erkens, and A. Skarpas. 2020. “Effect of laboratory aging on chemistry and rheology of crumb rubber modified bitumen.” Mater. Struct. 53 (2): 26. https://doi.org/10.1617/s11527-020-1451-9.
Wang, H., J. Yang, and M. Gong. 2016. Rheological characterization of asphalt binders and mixtures modified with carbon nanotubes, 141–150. Berlin: Springer.
Wang, R., G. Xu, X. Chen, W. Zhou, and H. Zhang. 2019. “Evaluation of aging resistance for high-performance crumb tire rubber compound modified asphalt.” Constr. Build. Mater. 218: 497–505. https://doi.org/10.1016/j.conbuildmat.2019.05.124.
Xu, G., et al. 2021a. “Rheological and aging properties of composite modified bitumen by styrene–butadiene–styrene and desulfurized crumb rubber.” Polymers (Basel) 13 (18): 3037. https://doi.org/10.3390/polym13183037.
Xu, J., et al. 2021b. “Performance improvement and aging property of oil/SBS modified asphalt.” Constr. Build. Mater. 300 (Sep): 123735. https://doi.org/10.1016/j.conbuildmat.2021.123735.
Yan, C., W. Huang, P. Lin, Y. Zhang, and Q. Lv. 2019. “Chemical and rheological evaluation of aging properties of high content SBS polymer modified asphalt.” Fuel 252 (Sep): 417–426. https://doi.org/10.1016/j.fuel.2019.04.022.
Ye, Q., W. Dong, S. Wang, and H. Li. 2020. “Research on the rheological characteristics and aging resistance of asphalt modified with tourmaline.” Materials (Basel) 13 (1): 69. https://doi.org/10.3390/ma13010069.
Zhang, E., L. Shan, X. Qi, X. Wang, and Y. Fan. 2022. “Investigating the relationship between chemical composition and mechanical properties of asphalt binders using atomic force microscopy (AFM).” Constr. Build. Mater. 343 (Aug): 128001. https://doi.org/10.1016/j.conbuildmat.2022.128001.
Zhang, H., Z. Chen, G. Xu, and C. Shi. 2018. “Evaluation of aging behaviors of asphalt binders through different rheological indices.” Fuel 221 (Jun): 78–88. https://doi.org/10.1016/j.fuel.2018.02.087.
Zhang, H., X. Jia, J. Yu, and L. Xue. 2013. “Effect of expanded vermiculite on microstructures and aging properties of styrene–butadiene–styrene copolymer modified bitumen.” Constr. Build. Mater. 40 (Mar): 224–230. https://doi.org/10.1016/j.conbuildmat.2012.09.103.
Zhang, H., Y. Wang, T. Yu, and Z. Liu. 2020. “Microstructural characteristics of differently aged asphalt samples based on atomic force microscopy (AFM).” Constr. Build. Mater. 255 (Sep): 119388. https://doi.org/10.1016/j.conbuildmat.2020.119388.
Zhang, H., J. Yu, and D. Kuang. 2012. “Effect of expanded vermiculite on aging properties of bitumen.” Constr. Build. Mater. 26 (1): 244–248. https://doi.org/10.1016/j.conbuildmat.2011.06.017.
Zhang, H., C. Zhu, J. Yu, C. Shi, and D. Zhang. 2015. “Influence of surface modification on physical and ultraviolet aging resistance of bitumen containing inorganic nanoparticles.” Constr. Build. Mater. 98 (Nov): 735–740. https://doi.org/10.1016/j.conbuildmat.2015.08.138.
Zhou, T., J. Zhou, Q. Li, and B. Li. 2020a. “Aging properties and mechanism of microwave-activated crumb rubber modified asphalt binder.” Front. Mater. 7 (Dec): 603938. https://doi.org/10.3389/fmats.2020.603938.
Zhou, Z., J. Wang, and P. Cong. 2020b. “Investigation of thermal degradation of asphalt binders during storage and transportation.” Constr. Build. Mater. 231 (Jan): 117196. https://doi.org/10.1016/j.conbuildmat.2019.117196.
Zhu, C., H. Zhang, D. Zhang, and Z. Chen. 2018. “Influence of base asphalt and SBS modifier on the weathering aging behaviors of SBS modified asphalt.” J. Mater. Civ. Eng. 30 (3): 04017306. https://doi.org/10.1061/(ASCE)MT.1943-5533.0002188.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 36Issue 4April 2024

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Received: Jun 6, 2023
Accepted: Oct 13, 2023
Published online: Jan 29, 2024
Published in print: Apr 1, 2024
Discussion open until: Jun 29, 2024

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Ph.D. Candidate, Public Works Engineering Dept., Faculty of Engineering, Mansoura Univ., Mansoura 35516, Egypt (corresponding author). ORCID: https://orcid.org/0000-0002-3014-5337. Email: [email protected]
Associate Professor, Public Works Engineering Dept., Mansoura Univ., Mansoura 35516, Egypt. ORCID: https://orcid.org/0000-0001-7951-1636. Email: [email protected]
Associate Professor, College of Engineering, Univ. of Sharjah, Sharjah 27272, United Arab Emirates; Assistant Professor, Public Works Engineering Dept., Faculty of Engineering, Mansoura Univ., Mansoura 35516, Egypt. ORCID: https://orcid.org/0000-0003-2248-5208. Email: [email protected]; [email protected]
Associate Professor, Public Works Engineering Dept., Faculty of Engineering, Mansoura Univ., Mansoura 35516, Egypt. ORCID: https://orcid.org/0000-0002-2399-2271. Email: [email protected]
Professor, Dept. of Civil Engineering, Faculty of Engineering, Fayoum Univ., Fayoum 2933110, Egypt. ORCID: https://orcid.org/0000-0002-8301-0946. Email: [email protected]
Sherif El-Badawy [email protected]
Professor, Public Works Engineering Dept., Faculty of Engineering, Mansoura Univ., Mansoura 35516, Egypt. Email: [email protected]

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