Technical Papers
Mar 19, 2024

Film-Forming Property of Cement Paste with Red Mud as a Supplementary Cementitious Material

Publication: Journal of Materials in Civil Engineering
Volume 36, Issue 6

Abstract

Red mud has been used as a supplement substitute material in the fabrication of concrete. However, the influence mechanism of red mud on the film-forming performance of cement paste is still unclear. In this study, red mud with different substitution rates (by cement mass) was added to cement paste to investigate the influence of red mud on the film-forming performance. The addition of red mud increased the cohesiveness and reduced the fluidity of cement paste. It showed that low fluidity reduced the film thickness of cement paste, and the film thickness decreased gradually with the increase of red mud substitution. Moreover, thermogravimetric analysis, X-ray diffraction, and scanning electron microscopy results demonstrated that red mud promotes the hydration process of cement by providing hydration nucleation sites, making the interfacial transition zone denser, which is important for improving the mechanical properties of cement paste. It is expected that this study improves the application of red mud in concrete.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

Some or all data or models that support the findings of this study are available from the corresponding author upon reasonable request.

Acknowledgments

This work was supported by the Taishan Scholar Project of Shandong Province (No. TSHW20130956).

References

Angelin, A. F., R. C. Cecche Lintz, W. R. Osório, and L. A. Gachet. 2020. “Evaluation of efficiency factor of a self-compacting lightweight concrete with rubber and expanded clay contents.” Constr. Build. Mater. 257 (Oct): 119873. https://doi.org/10.1016/j.conbuildmat.2020.119573.
Chen, J. J., W. W. S. Fung, and A. K. H. Kwan. 2012. “Effects of CSF on strength, rheology and cohesiveness of cement paste.” Constr. Build. Mater. 35 (Oct): 979979–987987. https://doi.org/10.1016/j.conbuildmat.2012.04.037.
Chen, J. J., P. L. Ng, A. K. H. Kwan, and L. G. Li. 2019a. “Lowering cement content in mortar by adding superfine zeolite as cement replacement and optimizing mixture proportions.” J. Cleaner Prod. 210 (Feb): 66–76. https://doi.org/10.1016/j.jclepro.2018.11.007.
Chen, X., Y. Guo, S. Ding, H. Zhang, F. Xia, J. Wang, and M. Zhou. 2019b. “Utilization of red mud in geopolymer-based pervious concrete with function of adsorption of heavy metal ions.” J. Cleaner Prod. 207 (Jan): 789–800. https://doi.org/10.1016/j.jclepro.2018.09.263.
Chen, X., G. Wang, Q. Dong, X. Zhao, and Y. Wang. 2020. “Microscopic characterizations of pervious concrete using recycled steel slag aggregate.” J. Cleaner Prod. 254 (May): 120149. https://doi.org/10.1016/j.jclepro.2020.120149.
Cheng, X., D. Long, C. Zhang, X. Gao, Y. Yu, K. Mei, C. Zhang, X. Guo, and Z. Chen. 2019. “Utilization of red mud, slag and waste drilling fluid for the synthesis of slag-red mud cementitious material.” J. Cleaner Prod. 238 (Nov): 117902. https://doi.org/10.1016/j.jclepro.2019.117902.
Cusack, P. B., M. G. Healy, P. C. Ryan, I. T. Burke, L. M. T. O’ Donoghue, É. Ujaczki, and R. Courtney. 2018. “Enhancement of bauxite residue as a low-cost adsorbent for phosphorus in aqueous solution, using seawater and gypsum treatments.” J. Cleaner Prod. 179 (Apr): 217–224. https://doi.org/10.1016/j.jclepro.2018.01.092.
Geng, J., M. Zhou, T. Zhang, W. Wang, T. Wang, X. Zhou, X. Wang, and H. Hou. 2016. “Preparation of blended geopolymer from red mud and coal gangue with mechanical co-grinding preactivation.” Mater. Struct. 50 (Apr): 1–11. https://doi.org/10.1617/s11527-016-0967-5.
Ghalehnovi, M., N. Roshan, E. Hakak, E. A. Shamsabadi, and J. de Brito. 2019. “Effect of red mud (bauxite residue) as cement replacement on the properties of self-compacting concrete incorporating various fillers.” J. Cleaner Prod. 240 (Dec): 118213. https://doi.org/10.1016/j.jclepro.2019.118213.
Hao, X., X. Liu, Z. Zhang, W. Zhang, Y. Lu, Y. Wang, and T. Yang. 2022. “In-depth insight into the cementitious synergistic effect of steel slag and red mud on the properties of composite cementitious materials.” J. Build. Eng. 52 (Jul): 104449. https://doi.org/10.1016/j.jobe.2022.104449.
Hou, D., D. Wu, X. Wang, S. Gao, R. Yu, M. Li, P. Wang, and Y. Wang. 2021. “Sustainable use of red mud in ultra-high performance concrete (UHPC): Design and performance evaluation.” Cem. Concr. Compos. 115 (Jan): 103862. https://doi.org/10.1016/j.cemconcomp.2020.103862.
Jimma, B. E., and P. R. Rangaraju. 2014. “Film-forming ability of flowable cement pastes and its application in mixture proportioning of pervious concrete.” Constr. Build. Mater. 71 (Nov): 273–282. https://doi.org/10.1016/j.conbuildmat.2014.08.018.
Kaya-Özkiper, K., A. Uzun, and S. Soyer-Uzun. 2021. “Red mud- and metakaolin-based geopolymers for adsorption and photocatalytic degradation of methylene blue: Towards self-cleaning construction materials.” J. Cleaner Prod. 288 (Mar): 125120. https://doi.org/10.1016/j.jclepro.2020.125120.
Khairul, M. A., J. Zanganeh, and B. Moghtaderi. 2019. “The composition, recycling and utilisation of Bayer red mud.” Resour. Conserv. Recycl. 141 (Feb): 483–498. https://doi.org/10.1016/j.resconrec.2018.11.006.
Lawrence, P., M. Cyr, and E. Ringot. 2003. “Mineral admixtures in mortars.” Cem. Concr. Res. 33 (12): 1939–1947. https://doi.org/10.1016/S0008-8846(03)00183-2.
Li, X., Q. Zhang, and S. Mao. 2021a. “Investigation of the bond strength and microstructure of the interfacial transition zone between cement paste and aggregate modified by Bayer red mud.” J. Hazard. Mater. 403 (Feb): 123482. https://doi.org/10.1016/j.jhazmat.2020.123482.
Li, Y., X. Liu, Z. Li, Y. Ren, Y. Wang, and W. Zhang. 2021b. “Preparation, characterization and application of red mud, fly ash and desulfurized gypsum based eco-friendly road base materials.” J. Cleaner Prod. 284 (Feb): 124777. https://doi.org/10.1016/j.jclepro.2020.124777.
Li, Y., X. Min, Y. Ke, D. Liu, and C. Tang. 2019. “Preparation of red mud-based geopolymer materials from MSWI fly ash and red mud by mechanical activation.” Waste Manage. 83 (Jan): 202–208. https://doi.org/10.1016/j.wasman.2018.11.019.
Liu, R.-X., and C.-S. Poon. 2016. “Utilization of red mud derived from bauxite in self-compacting concrete.” J. Cleaner Prod. 112 (Jan): 384–391. https://doi.org/10.1016/j.jclepro.2015.09.049.
Malachanne, E., M. Jebli, F. Jamin, E. Garcia-Diaz, and M.-S. El Youssoufi. 2018. “A cohesive zone model for the characterization of adhesion between cement paste and aggregates.” Constr. Build. Mater. 193 (Dec): 64–71. https://doi.org/10.1016/j.conbuildmat.2018.10.188.
Mao, J., Q. Wang, L. Lei, and Y. Li. 2021. “Effects of wettability on the film-forming property of modified cement paste.” Constr. Build. Mater. 300 (Sep): 124068. https://doi.org/10.1016/j.conbuildmat.2021.124068.
Mao, J., Q. Wang, L. Qu, H. Zhang, Z. Shi, S. Xu, and X. Li. 2022a. “Study of mortar layer property of superhydrophobic metakaolin based cement mortar.” J. Build. Eng. 45 (Jan): 103578. https://doi.org/10.1016/j.jobe.2021.103578.
Mao, J., Q. Wang, M. Wang, X. Li, S. Xu, and Z. Shi. 2022b. “Study on properties of metakaolin-based cement paste coating and its application of adsorbing methylene blue in water.” Constr. Build. Mater. 327 (Apr): 126771. https://doi.org/10.1016/j.conbuildmat.2022.126771.
Nikbin, I. M., M. Aliaghazadeh, C. Sh, and A. Fathollahpour. 2018. “Environmental impacts and mechanical properties of lightweight concrete containing bauxite residue (red mud).” J. Cleaner Prod. 172 (Jan): 2683–2694. https://doi.org/10.1016/j.jclepro.2017.11.143.
Putrevu, M., J. S. Thiyagarajan, D. Pasla, K. I. S. A. Kabeer, and K. Bisht. 2021. “Valorization of red mud waste for cleaner production of construction materials.” J. Hazard. Toxic Radioact. Waste 25 (4): 03121002. https://doi.org/10.1061/(ASCE)HZ.2153-5515.0000629.
Romano, R. C. O., H. M. Bernardo, M. H. Maciel, R. G. Pileggi, and M. A. Cincotto. 2017. “Hydration of portland cement with red mud as mineral addition.” J. Therm. Anal. Calorim. 131 (3): 2477–2490. https://doi.org/10.1007/s10973-017-6794-2.
Sevgili, I., O. F. Dilmaç, and B. Simsek. 2021. “An environmentally sustainable way for effective water purification by adsorptive red mud cementitious composite cubes modified with bentonite and activated carbon.” Sep. Purif. Technol. 274 (Nov): 119115. https://doi.org/10.1016/j.seppur.2021.119115.
Song, Q., Q. Wang, S. Xu, J. Mao, X. Li, and Y. Zhao. 2022. “Properties of water-repellent concrete mortar containing superhydrophobic oyster shell powder.” Constr. Build. Mater. 337 (Jun): 127423. https://doi.org/10.1016/j.conbuildmat.2022.127423.
Su, Z., and X. Li. 2021. “Study on preparation and interfacial transition zone microstructure of red mud-yellow phosphorus slag-cement concrete.” Materials 14 (11): 2768. https://doi.org/10.3390/ma14112768.
Taneez, M., and C. Hurel. 2019. “A review on the potential uses of red mud as amendment for pollution control in environmental media.” Environ. Sci. Pollut. Res. Int. 26 (22): 22106–22125. https://doi.org/10.1007/s11356-019-05576-2.
Tang, W. C., Z. Wang, S. W. Donne, M. Forghani, and Y. Liu. 2019. “Influence of red mud on mechanical and durability performance of self-compacting concrete.” J. Hazard. Mater. 379 (Nov): 120802. https://doi.org/10.1016/j.jhazmat.2019.120802.
Tang, W. C., Z. Wang, Y. Liu, and H. Z. Cui. 2018. “Influence of red mud on fresh and hardened properties of self-compacting concrete.” Constr. Build. Mater. 178 (Jul): 288–300. https://doi.org/10.1016/j.conbuildmat.2018.05.171.
Wang, L., L. Chen, D. C. W. Tsang, Y. Zhou, J. Rinklebe, H. Song, E. E. Kwon, K. Baek, and Y. Sik Ok. 2019a. “Mechanistic insights into red mud, blast furnace slag, or metakaolin-assisted stabilization/solidification of arsenic-contaminated sediment.” Environ. Int. 133 (Dec): 105247. https://doi.org/10.1016/j.envint.2019.105247.
Wang, L., N. Sun, H. Tang, and W. Sun. 2019b. “A review on comprehensive utilization of red mud and prospect analysis.” Minerals 9 (6): 362. https://doi.org/10.3390/min9060362.
Wang, L., K. M. Yu, D. C. Tsang, S. Li, J.-S. Li, C. S. Poon, Y.-S. Wang, and J.-G. Dai. 2017. “Transforming wood waste into water-resistant magnesia-phosphate cement particleboard modified by alumina and red mud.” J. Cleaner Prod. 168 (Dec): 452–462. https://doi.org/10.1016/j.jclepro.2017.09.038.
Wang, S., H. Jin, Y. Deng, and Y. Xiao. 2021a. “Comprehensive utilization status of red mud in China: A critical review.” J. Cleaner Prod. 289 (Mar): 125136. https://doi.org/10.1016/j.jclepro.2020.125136.
Wang, Y., X. Liu, Y. Li, D. Li, W. Zhang, and Y. Xue. 2021b. “Tailings after iron extraction in Bayer red mud by biomass reduction: Pozzolanic activity and hydration characteristics.” Materials 14 (14): 3955. https://doi.org/10.3390/ma14143955.
Wang, Y., X. Liu, Z. Xie, H. Wang, W. Zhang, and Y. Xue. 2021c. “Rapid evaluation of the pozzolanic activity of Bayer red mud by a polymerization degree method: Correlations with alkali dissolution of (Si+Al) and strength.” Materials 14 (19): 5546. https://doi.org/10.3390/ma14195546.
Ye, N., J. Yang, S. Liang, Y. Hu, J. Hu, B. Xiao, and Q. Huang. 2016. “Synthesis and strength optimization of one-part geopolymer based on red mud.” Constr. Build. Mater. 111 (May): 317–325. https://doi.org/10.1016/j.conbuildmat.2016.02.099.
Zhang, J., C. Sun, P. Li, M. Liang, H. Jiang, and Z. Yao. 2019. “Experimental study on rheological properties and moisture susceptibility of asphalt mastic containing red mud waste as a filler substitute.” Constr. Build. Mater. 211 (Jun): 159–166. https://doi.org/10.1016/j.conbuildmat.2019.03.252.
Zhang, M., M. Zhao, G. Zhang, D. Mann, K. Lumsden, and M. Tao. 2016. “Durability of red mud-fly ash based geopolymer and leaching behavior of heavy metals in sulfuric acid solutions and deionized water.” Constr. Build. Mater. 124 (Oct): 373–382. https://doi.org/10.1016/j.conbuildmat.2016.07.108.
Zhu, Z., and H. Chen. 2017. “Overestimation of ITZ thickness around regular polygon and ellipse aggregate.” Comput. Struct. 182 (Apr): 205–218. https://doi.org/10.1016/j.compstruc.2016.11.015.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 36Issue 6June 2024

History

Received: May 16, 2023
Accepted: Nov 7, 2023
Published online: Mar 19, 2024
Published in print: Jun 1, 2024
Discussion open until: Aug 19, 2024

Permissions

Request permissions for this article.

Authors

Affiliations

Master’s Student, College of Civil Engineering and Architecture, Shandong Univ. of Science and Technology, Shandong 266590, China. Email: [email protected]
Professor, College of Mechanical and Architectural Engineering, Taishan Univ., Shandong 271000, China (corresponding author). ORCID: https://orcid.org/0000-0001-7228-6472. Email: [email protected]
Qingnan Song [email protected]
Master’s Student, College of Civil Engineering and Architecture, Shandong Univ. of Science and Technology, Shandong 266590, China. Email: [email protected]
Ph.D. Candidate, College of Civil Engineering and Architecture, Shandong Univ. of Science and Technology, Shandong 266590, China. Email: [email protected]
Lecturer, College of Civil Engineering and Architecture, Shandong Univ. of Science and Technology, Shandong 266590, China. Email: [email protected]
Lecturer, College of Mechanical and Architectural Engineering, Taishan Univ., Shandong 271000, China. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share