Technical Papers
Dec 23, 2023

Effect of Sisal Fibers on the Rheology of Cement Paste Plasticized by Polycarboxylate Superplasticizer

Publication: Journal of Materials in Civil Engineering
Volume 36, Issue 3

Abstract

Sisal fibers (SF) and polycarboxylate superplasticizers (PCE) contribute to the sustainable development of cementitious materials by improving and optimizing their hardening properties. In this study, the impact of SF and PCE on the workability of cement pastes was investigated. The workability was evaluated through spreading diameter, yield stress, and plastic viscosity measurements, and the adsorption behavior of PCE was analyzed. The results showed that the introduction of SF had a negative effect on the workability of PCE plasticized cement pastes, reducing flowability and increasing yield stress and plastic viscosity, regardless of aspect ratio or dosage. A contact angle tester and a scanning electron microscope (SEM) were employed to examine the surface properties of SF. The mechanism behind this interaction of cement-PCE-SF was explored and found to be due to the rough surface of SF, which increased the consumption of PCE, and the formation of hydrogen bonds between PCE and SF. Additionally, PCE modified the interfacial structure between SF and the cement matrix, strengthening the relationship between the different phases. These findings provide new insights into the modification of fiber-reinforced cementitious materials.

Practical Applications

This paper presents a comprehensive study on the workability and rheology behavior of cementitious material that coupled PCE superplasticizer and SF. The interaction between PCE and SF was experimentally studied by suitable tests, and the results and mechanism behind were well explained. The fresh properties were evaluated through a mini slump test, rheological properties, and the adsorption behavior of PCE on the surface of cement and SF was analyzed. The results showed that the introduction of SF decreases the spread diameter and increases the yield stress and plastic viscosity, regardless of aspect ratio and dosage, which indicate that a negative effect on the workability of PCE plasticized cement pastes. The mechanism behind the cement-PCE-SF interaction was explored in depth by the surface properties of SF, which revealed that the rough surface of SF increased the consumption of PCE. In addition, the formation of hydrogen bonds between PCE and SF provides an additional explanation. The significance of this study provides valuable guidance in using fibers and PCE together in cementitious materials.

Get full access to this article

View all available purchase options and get full access to this article.

Data Availability Statement

All data, models, and code generated or used during the study appear in the published article.

Acknowledgments

This work is grateful for the financial support from the National Science Foundation of China (22268017), the Hainan Province Science and Technology Special Fund (ZDYF2021GXJS024), and the National Science Foundation of China (52268041).
Author contributions: Kun Zhang: data curation, investigation, formal analysis, writing–original draft. Chang Lin: review and editing. Lisha Pan: supervision, review and editing.

References

Amjad, H., R. A. Khushnood, and F. Ahmad. 2023. “Enhanced fracture and durability resilience using bio-intriggered sisal fibers in concrete.” J. Build. Eng. 76 (Oct): 107008. https://doi.org/10.1016/j.jobe.2023.107008.
As’ad, S., P. Gunawan, and M. S. Alaydrus. 2011. “Fresh state behavior of self compacting concrete containing waste material fibres.” Procedia Eng. 14 (Mar): 797–804. https://doi.org/10.1016/j.proeng.2011.07.101.
Banfill, P. F. G. 2003. “The rheology of fresh cement and concrete—A review.” In Proc., 11th Int. Cement Chemistry Congress. Buchbach, Germany: Schleibinger.
Banthia, N., and J.-F. Trottier. 1995. “Concrete reinforced with deformed steel fibers, Part II: Toughness characterization.” ACI Mater. J. 92 (2): 146–154. https://doi.org/10.14359/9765.
Berge, B. 2007. Ecology of building materials. New York: Routledge.
Boghossian, E., and L. D. Wegner. 2008. “Use of flax fibres to reduce plastic shrinkage cracking in concrete.” Cem. Concr. Compos. 30 (10): 929–937. https://doi.org/10.1016/j.cemconcomp.2008.09.003.
Cao, M., L. Xu, and C. Zhang. 2016. “Rheology, fiber distribution and mechanical properties of calcium carbonate (CaCO3) whisker reinforced cement mortar.” Composites, Part A 90 (Mar): 662–669. https://doi.org/10.1016/j.compositesa.2016.08.033.
Centonze, G., M. Leone, F. Micelli, D. Colonna, and M. A. Aiello. 2016. “Concrete reinforced with recycled steel fibers from end of life tires: Mix-design and application.” Key Eng. Mater. 711 (Sep): 224–231. https://doi.org/10.4028/www.scientific.net/KEM.711.224.
Chandrasekar, M., M. R. Ishak, S. M. Sapuan, Z. Leman, and M. Jawaid. 2017. “A review on the characterisation of natural fibres and their composites after alkali treatment and water absorption.” Plast. Rubber Compos. 46 (3): 119–136. https://doi.org/10.1080/14658011.2017.1298550.
de Almeida Melo Filho, J., F. de Andrade Silva, and R. D. Toledo Filho. 2013. “Degradation kinetics and aging mechanisms on sisal fiber cement composite systems.” Cem. Concr. Compos. 40 (Jun): 30–39. https://doi.org/10.1016/j.cemconcomp.2013.04.003.
de Andrade Silva, F., R. D. Toledo Filho, J. de Almeida Melo Filho, and E. D. M. R. Fairbairn. 2010. “Physical and mechanical properties of durable sisal fiber–cement composites.” Constr. Build. Mater. 24 (5): 777–785. https://doi.org/10.1016/j.conbuildmat.2009.10.030.
de Souza Castoldi, R., L. M. S. de Souza, F. Souto, M. Liebscher, V. Mechtcherine, and F. de Andrade Silva. 2022. “Effect of alkali treatment on physical–chemical properties of sisal fibers and adhesion towards cement-based matrices.” Constr. Build. Mater. 345 (Aug): 128363. https://doi.org/10.1016/j.conbuildmat.2022.128363.
dos Santos, G. Z. B., L. R. Caldas, J. de Almeida Melo Filho, N. B. R. Monteiro, S. I. M. Rafael, and N. M. da Silva. 2022. “Circular alternatives in the construction industry: An environmental performance assessment of sisal fiber-reinforced composites.” J. Build. Eng. 54 (Aug): 104603. https://doi.org/10.1016/j.jobe.2022.104603.
El-Dieb, A., and M. R. Taha. 2012. “Flow characteristics and acceptance criteria of fiber-reinforced self-compacted concrete (FR-SCC).” Constr. Build. Mater. 27 (1): 585–596. https://doi.org/10.1016/j.conbuildmat.2011.07.004.
Feng, H., L. Pan, Q. Zheng, J. Li, N. Xu, and S. Pang. 2018. “Effects of molecular structure of polycarboxylate superplasticizers on their dispersion and adsorption behavior in cement paste with two kinds of stone powder.” Constr. Build. Mater. 170 (Feb): 182–192. https://doi.org/10.1016/j.conbuildmat.2018.02.195.
Ferrandez-García, M. T., C. E. Ferrandez-Garcia, T. Garcia-Ortuño, A. Ferrandez-Garcia, and M. Ferrandez-Villena. 2020. “Study of waste jute fibre panels (Corchorus capsularis L.) agglomerated with Portland cement and starch.” Polymers 12 (3): 599. https://doi.org/10.3390/polym12030599.
Figueiredo, A. D. D., and M. R. Ceccato. 2015. “Workability analysis of steel fiber reinforced concrete using slump and Ve-Be test.” Mater. Res. 18 (6): 1284–1290. https://doi.org/10.1590/1516-1439.022915.
Flatt, R. J., and Y. F. Houst. 2001. “A simplified view on chemical effects perturbing the action of superplasticizers.” Cem. Concr. Res. 31 (8): 1169–1176. https://doi.org/10.1016/S0008-8846(01)00534-8.
Glasser, F. P., J. Marchand, and E. Samson. 2008. “Durability of concrete—Degradation phenomena involving detrimental chemical reactions.” Cem. Concr. Res. 38 (2): 226–246. https://doi.org/10.1016/j.cemconres.2007.09.015.
Güneyisi, E., Y. R. Atewi, and M. F. Hasan. 2019. “Fresh and rheological properties of glass fiber reinforced self-compacting concrete with nanosilica and fly ash blended.” Constr. Build. Mater. 211 (Jun): 349–362. https://doi.org/10.1016/j.conbuildmat.2019.03.087.
Hannawi, K., H. Bian, W. Prince-Agbodjan, and B. Raghavan. 2016. “Effect of different types of fibers on the microstructure and the mechanical behavior of ultra-high performance fiber-reinforced concretes.” Composites, Part B 86 (May): 214–220. https://doi.org/10.1016/j.compositesb.2015.09.059.
IPCC (Intergovernmental Panel on Climate Change). 2013. Intergovernmental panel on climate change climate change fifth assessment report (AR5). Geneva: IPCC.
Izaguirre, A., J. Lanas, and J. I. Alvarez. 2011. “Effect of a polypropylene fibre on the behaviour of aerial lime-based mortars.” Constr. Build. Mater. 25 (2): 992–1000. https://doi.org/10.1016/j.conbuildmat.2010.06.080.
Jabbar, A. M., M. J. Hamood, and D. H. Mohammed. 2021. “The effect of using basalt fibers compared to steel fibers on the shear behavior of ultra-high performance concrete T-beam.” Case Stud. Constr. Mater. 15 (Dec): e00702. https://doi.org/10.1016/j.cscm.2021.e00702.
Kabir, M. M., H. Wang, K. T. Lau, and F. Cardona. 2012. “Chemical treatments on plant-based natural fibre reinforced polymer composites: An overview.” Composites, Part B 43 (7): 2883–2892. https://doi.org/10.1016/j.compositesb.2012.04.053.
Kamal, M. M., M. A. Safan, Z. A. Etman, and M. A. Abd-elbaki. 2013. “Effect of polypropylene fibers on development of fresh and hardened properties of recycled self-compacting concrete.” Int. J. Eng. Adv. Technol. 2 (Jun): 86–94.
Kang, Z., H. Zhiwei, Y. Yajing, Y. Xiang, S. Yufeng, and Y. Jian. 2022. “Microscopic failure mechanism of fiber reinforced ultra-fine tailings backfill.” Supplement, Chin. J. Rock Mech. Eng. 41 (S1): 3010–3020.
Kicińska-Jakubowska, A., E. Bogacz, and M. Zimniewska. 2012. “Review of natural fibers. Part I—Vegetable fibers.” J. Nat. Fibers 9 (3): 150–167. https://doi.org/10.1080/15440478.2012.703370.
Kong, F.-R., L.-S. Pan, C.-M. Wang, D.-L. Zhang, and N. Xu. 2016. “Effects of polycarboxylate superplasticizers with different molecular structure on the hydration behavior of cement paste.” Constr. Build. Mater. 105 (May): 545–553. https://doi.org/10.1016/j.conbuildmat.2015.12.178.
Kuder, K. G., N. Ozyurt, E. B. Mu, and S. P. Shah. 2007. “Rheology of fiber-reinforced cementitious materials.” Cem. Concr. Res. 37 (2): 191–199. https://doi.org/10.1016/j.cemconres.2006.10.015.
Lao, J.-C., B.-T. Huang, Y. Fang, L.-Y. Xu, J.-G. Dai, and S. P. Shah. 2023. “Strain-hardening alkali-activated fly ash/slag composites with ultra-high compressive strength and ultra-high tensile ductility.” Cem. Concr. Res. 165 (Mar): 107075. https://doi.org/10.1016/j.cemconres.2022.107075.
Lepech, M., and V. C. Li. 2005. “Durability and long term performance of engineered cementitious composites.” In Proc., Int. Workshop on HPFRCC in Structural Applications. Paris: RILEM.
Liu, H., Q. Zhang, V. Li, H. Su, and C. Gu. 2017. “Durability study on engineered cementitious composites (ECC) under sulfate and chloride environment.” Constr. Build. Mater. 133 (Mar): 171–181. https://doi.org/10.1016/j.conbuildmat.2016.12.074.
Mármol, G., S. Santos, H. Savastano Jr., M. Borrachero, J. Monzó, and J. Payá. 2013. “Mechanical and physical performance of low alkalinity cementitious composites reinforced with recycled cellulosic fibres pulp from cement kraft bags.” Ind. Crops Prod. 49 (Jan): 422–427. https://doi.org/10.1016/j.indcrop.2013.04.051.
Medina, N. F., G. Barluenga, and F. Hernández-Olivares. 2014. “Enhancement of durability of concrete composites containing natural pozzolans blended cement through the use of polypropylene fibers.” Composites, Part B 61 (May): 214–221. https://doi.org/10.1016/j.compositesb.2014.01.052.
Pacheco-Torgal, F., and S. Jalali. 2011. “Cementitious building materials reinforced with vegetable fibres: A review.” Constr. Build. Mater. 25 (2): 575–581. https://doi.org/10.1016/j.conbuildmat.2010.07.024.
Ramesh, M., C. Deepa, L. R. Kumar, M. Sanjay, and S. Siengchin. 2020. “Life-cycle and environmental impact assessments on processing of plant fibres and its bio-composites: A critical review.” Supplement, J. Ind. Text. 51 (S4): 5518S–5542S. https://doi.org/10.1177/1528083720924730.
Roma, L. C., Jr., L. S. Martello, and H. Savastano Jr. 2008. “Evaluation of mechanical, physical and thermal performance of cement-based tiles reinforced with vegetable fibers.” Constr. Build. Mater. 22 (4): 668–674. https://doi.org/10.1016/j.conbuildmat.2006.10.001.
Sakai, E., T. Kasuga, T. Sugiyama, K. Asaga, and M. Daimon. 2006. “Influence of superplasticizers on the hydration of cement and the pore structure of hardened cement.” Cem. Concr. Res. 36 (11): 2049–2053. https://doi.org/10.1016/j.cemconres.2006.08.003.
Shin, H.-O., K. Kim, T. Oh, and D.-Y. Yoo. 2021. “Effects of fiber type and specimen thickness on flexural behavior of ultra-high-performance fiber-reinforced concrete subjected to uniaxial and biaxial stresses.” Case Stud. Constr. Mater. 15 (May): e00726. https://doi.org/10.1016/j.cscm.2021.e00726.
Soleimani, T., A. A. Merati, M. Latifi, and A. A. Ramezanianpor. 2013. “Inhibition of cracks on the surface of cement mortar using estabragh fibers.” Adv. Mater. Sci. Eng. 2013 (Sep): 1. https://doi.org/10.1155/2013/656109.
Stancato, A., A. Burke, and A. Beraldo. 2005. “Mechanism of a vegetable waste composite with polymer-modified cement (VWCPMC).” Cem. Concr. Compos. 27 (5): 599–603. https://doi.org/10.1016/j.cemconcomp.2004.09.011.
Toledo Filho, R. D., F. de Andrade Silva, E. Fairbairn, and J. de Almeida Melo Filho. 2009. “Durability of compression molded sisal fiber reinforced mortar laminates.” Constr. Build. Mater. 23 (6): 2409–2420. https://doi.org/10.1016/j.conbuildmat.2008.10.012.
Tregger, N., L. Ferrara, and S. P. Shah. 2008. “Identifying viscosity of cement paste from mini-slump-flow test.” ACI Mater. J. 105 (6): 558. https://doi.org/10.14359/20197.
Voigt, T., V. K. Bui, and S. P. Shah. 2004. “Drying shrinkage of concrete reinforced with fibers and welded-wire fabric.” Mater. J. 101 (3): 233–241. https://doi.org/10.14359/13119.
Wallevik, O. H., D. Feys, J. E. Wallevik, and K. H. Khayat. 2015. “Avoiding inaccurate interpretations of rheological measurements for cement-based materials.” Cem. Concr. Res. 78 (Jun): 100–109. https://doi.org/10.1016/j.cemconres.2015.05.003.
Wang, C., F. Kong, and L. Pan. 2021a. “Effects of polycarboxylate superplasticizers with different side-chain lengths on the resistance of concrete to chloride penetration and sulfate attack.” J. Build. Eng. 43 (Nov): 102817. https://doi.org/10.1016/j.jobe.2021.102817.
Wang, W., A. Shen, Z. Lyu, Z. He, and K. T. Q. Nguyen. 2021b. “Fresh and rheological characteristics of fiber reinforced concrete: A review.” Constr. Build. Mater. 296 (Jun): 123734. https://doi.org/10.1016/j.conbuildmat.2021.123734.
Xu, L.-Y., B.-T. Huang, J.-C. Lao, J. Yao, V. C. Li, and J.-G. Dai. 2023. “Tensile over-saturated cracking of ultra-high-strength engineered cementitious composites (UHS-ECC) with artificial geopolymer aggregates.” Cem. Concr. Compos. 136 (Feb): 104896. https://doi.org/10.1016/j.cemconcomp.2022.104896.
Yamada, K. 2011. “Basics of analytical methods used for the investigation of interaction mechanism between cements and superplasticizers.” Cem. Concr. Res. 41 (7): 793–798. https://doi.org/10.1016/j.cemconres.2011.03.007.
Yoo, D.-Y., and N. Banthia. 2019. “Impact resistance of fiber-reinforced concrete—A review.” Cem. Concr. Compos. 104 (Nov): 103389. https://doi.org/10.1016/j.cemconcomp.2019.103389.
Yoo, D.-Y., S. Kim, J.-J. Kim, and B. Chun. 2019. “An experimental study on pullout and tensile behavior of ultra-high-performance concrete reinforced with various steel fibers.” Constr. Build. Mater. 206 (Aug): 46–61. https://doi.org/10.1016/j.conbuildmat.2019.02.058.
Yu, R., P. Spiesz, and H. J. H. Brouwers. 2014. “Mix design and properties assessment of ultra-high performance fibre reinforced concrete (UHPFRC).” Cem. Concr. Res. 56 (Feb): 29–39. https://doi.org/10.1016/j.cemconres.2013.11.002.
Zhang, K., L. Pan, J. Li, and C. Lin. 2021. “What is the mechanism of the fiber effect on the rheological behavior of cement paste with polycarboxylate superplasticizer?” Constr. Build. Mater. 281 (Apr): 122542. https://doi.org/10.1016/j.conbuildmat.2021.122542.
Zhang, K., L. Pan, J. Li, C. Lin, Y. Cao, N. Xu, and S. Pang. 2019. “How does adsorption behavior of polycarboxylate superplasticizer effect rheology and flowability of cement paste with polypropylene fiber?” Cem. Concr. Compos. 95 (Jan): 228–236. https://doi.org/10.1016/j.cemconcomp.2018.11.003.

Information & Authors

Information

Published In

Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 36Issue 3March 2024

History

Received: Apr 13, 2023
Accepted: Aug 10, 2023
Published online: Dec 23, 2023
Published in print: Mar 1, 2024
Discussion open until: May 23, 2024

Permissions

Request permissions for this article.

Authors

Affiliations

Kun Zhang
School of Chemical Engineering and Technology, Hainan Univ., 58 Renmin Rd., Haikou, Hainan 570228, China; Bundesanstalt für Materialforschung und -prüfung, Unter den Eichen 87, Berlin 12205, Germany.
Chang Lin, Ph.D.
Associate Professor, School of Chemical Engineering and Technology, Hainan Univ., 58 Renmin Rd., Haikou, Hainan 570228, China.
Professor, School of Chemical Engineering and Technology, Hainan Univ., 58 Renmin Rd., Haikou, Hainan 570228, China (corresponding author). ORCID: https://orcid.org/0000-0002-7974-0807. Email: [email protected]

Metrics & Citations

Metrics

Citations

Download citation

If you have the appropriate software installed, you can download article citation data to the citation manager of your choice. Simply select your manager software from the list below and click Download.

View Options

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Get Access

Access content

Please select your options to get access

Log in/Register Log in via your institution (Shibboleth)
ASCE Members: Please log in to see member pricing

Purchase

Save for later Information on ASCE Library Cards
ASCE Library Cards let you download journal articles, proceedings papers, and available book chapters across the entire ASCE Library platform. ASCE Library Cards remain active for 24 months or until all downloads are used. Note: This content will be debited as one download at time of checkout.

Terms of Use: ASCE Library Cards are for individual, personal use only. Reselling, republishing, or forwarding the materials to libraries or reading rooms is prohibited.
ASCE Library Card (5 downloads)
$105.00
Add to cart
ASCE Library Card (20 downloads)
$280.00
Add to cart
Buy Single Article
$35.00
Add to cart

Media

Figures

Other

Tables

Share

Share

Copy the content Link

Share with email

Email a colleague

Share