Technical Papers
Apr 16, 2024

Corrosion Resistance of Cr10Mo1 Alloy Corrosion-Resistant Steel in Seawater–Sea Sand Concrete Pore Solution

Publication: Journal of Materials in Civil Engineering
Volume 36, Issue 7

Abstract

This paper is aimed to study the corrosion resistance of Cr10Mo1 alloy corrosion-resistant steel (CR) in the seawater–sea sand concrete pore solution (SWSSCPS), compared with low-carbon steel (LC) and stainless steel (SS). X-ray photoelectron spectroscopy (XPS), SEM, atomic force microscope, and Mott–Schottky curve tests are applied to obtain information on the composition, structure, and morphology of the corrosion-resistant (CR) passive film. Finally, the difference between CR passive film and the other two kinds of steels under chloride attack is investigated, and the apparent morphology, microstructure, and chemical composition of the CR passive film during the attack are analyzed. With the exposure time increased, the passive film and interfacial integrity of CR are approximately equivalent to that of SS in terms of phase angle in the midband and low-frequency band modulus, indicating the anticorrosion performance of CR has a much better effect than that of LC and close to that of SS. The results reveal that the FeO in the passive film outer layer and a high amount of Cr2O3/Cr(OH)3 in the inner layer prevent CR from further corrosion by chloride ions.

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Data Availability Statement

All data, models, and code generated or used during the study appear in the published article.

Acknowledgments

The authors greatly acknowledge the National Science Fund for Distinguished Young Scholars of China (51925903), National Natural Science Foundation Youth Fund Project (52108196), National Natural Science Foundation of China Joint Fund for Regional Innovation and Development (U2106221), General Program of the National Natural Science Foundation of China (52350004), National Key R & D Program of China (2021YFF0500803), State Key Laboratory of High Performance Civil Engineering Materials (2020CEM001), and Science and Technology Research Project of China Railway (2020YY240610 and K2020G033).
Author contributions: Zhongyi Xin: methodology, investigation, data curation, and writing–original draft. Fengjuan Wang: methodology, writing–review and editing, and funding acquisition. Le Guo: investigation, data curation, and writing–original draft. Huande Chen: resources and investigation. Zhongyong Liu: conceptualization and supervision. Jinyang Jiang: conceptualization, writing–review and editing, funding acquisition, and supervision.

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Go to Journal of Materials in Civil Engineering
Journal of Materials in Civil Engineering
Volume 36Issue 7July 2024

History

Received: Mar 30, 2023
Accepted: Nov 16, 2023
Published online: Apr 16, 2024
Published in print: Jul 1, 2024
Discussion open until: Sep 16, 2024

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Zhongyi Xin
Graduate Student, Jiangsu Key Laboratory of Construction Materials, School of Materials Science and Engineering, Southeast Univ., Nanjing 211189, China.
Fengjuan Wang, Ph.D.
Professor, Jiangsu Key Laboratory of Construction Materials, School of Materials Science and Engineering, Southeast Univ., Nanjing 211189, China.
Le Guo
Graduate Student, Jiangsu Key Laboratory of Construction Materials, School of Materials Science and Engineering, Southeast Univ., Nanjing 211189, China.
Huande Chen, Ph.D.
Graduate Student, Jiangsu Key Laboratory of Construction Materials, School of Materials Science and Engineering, Southeast Univ., Nanjing 211189, China.
Zhiyong Liu
Professor, Jiangsu Key Laboratory of Construction Materials, School of Materials Science and Engineering, Southeast Univ., Nanjing 211189, China.
Jinyang Jiang [email protected]
Professor, Jiangsu Key Laboratory of Construction Materials, School of Materials Science and Engineering, Southeast Univ., Nanjing 211189, China (corresponding author). Email: [email protected]

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