Pore Structure Characters and Oxygen Permeability Interpreted by Katz–Thompson Model of Fly Ash Concrete
Publication: Journal of Materials in Civil Engineering
Volume 36, Issue 5
Abstract
The relationship between the characteristics of concrete pore structures and intrinsic permeability was investigated. The concrete pore structure incorporating fly ash was characterized by parameters including total porosity, pore size distribution (PSD), tortuosity, and characteristic pore sizes. The results indicate that: (1) there is a weak correlation between total porosity and critical pore size concerning oxygen permeability as interpreted by the Katz–Thompson model; (2) pores with diameters exceeding 100 nm serve as the primary tunnel for oxygen percolation in fly ash concrete; and (3) the porosity of pores larger than 100 nm and the average pore diameter exhibit the strongest correlation with oxygen permeability in fly ash concrete, as interpreted by the Katz–Thompson model.
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Data Availability Statement
Some or all data, models, or code that support the findings of this study are available from the corresponding author upon reasonable request.
Acknowledgments
The work described in this paper was supported by the grant from the National Natural Science Foundation of China (Project Nos. 52078148 and 52108125), Special Research Projects in Key Areas for Colleges and Universities in Guangdong Province (Science and Technology Plan for Rural Revitalization, Project No. 2021ZDZX4009), Natural Science Foundation of Guangdong Province, China (Project No. 2022A1515010038), Basic Research Program (Municipality-University joint fund) of Science and Technology Bureau of Guangzhou (Project No. SL2023A03J00880), Tertiary Education Scientific research project of Guangzhou Municipal Education Bureau (Project No. 202235263), and Zhuhai Municipal Science and Technology Planning Project in the Field of Social Development (Project No. ZH22036201210032PWC). The authors are very grateful to Prof. Zhou Chunsheng for the supplication of the CemBureau device.
References
Androutsopoulos, G. P., and C. E. Salmas. 2000. “Tomography of macro-meso-pore structure based on mercury porosimetry hysteresis loop scanning—Part I: MP hysteresis loop scanning along the overall penetration line.” Chem. Eng. Commun. 181 (1): 179–202. https://doi.org/10.1080/00986440008912820.
Bonavetti, V., H. Donza, G. Menéndez, O. Cabrera, and E. F. Irassar. 2003. “Limestone filler cement in low w/c concrete: A rational use of energy.” Cem. Concr. Res. 33 (6): 865–871. https://doi.org/10.1016/S0008-8846(02)01087-6.
Care, S., and F. Derkx. 2011. “Determination of relevant parameters influencing gas permeability of mortars.” Constr. Build. Mater. 25 (3): 1248–1256. https://doi.org/10.1016/j.conbuildmat.2010.09.028.
Christensen, B. J., T. O. Mason, and H. M. Jennings. 1996. “Comparison of measured and calculated permeabilities for hardened cement pastes.” Cem. Concr. Res. 26 (9): 1325–1334. https://doi.org/10.1016/0008-8846(96)00130-5.
Chung, S.-Y., T.-S. Han, and S.-Y. Kim. 2015. “Reconstruction and evaluation of the air permeability of a cement paste specimen with a void distribution gradient using CT images and numerical methods.” Constr. Build. Mater. 87 (May): 45–53. https://doi.org/10.1016/j.conbuildmat.2015.03.103.
Da Silva, P. R., and J. De Brito. 2015. “Experimental study of the porosity and microstructure of self-compacting concrete (SCC) with binary and ternary mixes of fly ash and limestone filler.” Constr. Build. Mater. 86 (Jul): 101–112. https://doi.org/10.1016/j.conbuildmat.2015.03.110.
Garboczi, E. J. 1990. “Permeability, diffusivity, and microstructural parameters: A critical review.” Cem. Concr. Res. 20 (4): 591–601. https://doi.org/10.1016/0008-8846(90)90101-3.
Gui, Q., M. Qin, and K. Li. 2016. “Gas permeability and electrical conductivity of structural concretes: Impact of pore structure and pore saturation.” Cem. Concr. Res. 89 (May): 109–119. https://doi.org/10.1016/j.cemconres.2016.08.009.
Halamickova, P., R. J. Detwiler, D. P. Bentz, and E. J. Garboczi. 1995. “Water permeability and chloride ion diffusion in portland cement mortars: Relationship to sand content and critical pore diameter.” Cem. Concr. Res. 25 (4): 790–802. https://doi.org/10.1016/0008-8846(95)00069-O.
Hamami, A. A., P. Turcry, and A. Aït-Mokhtar. 2012. “Influence of mix proportions on microstructure and gas permeability of cement pastes and mortars.” Cem. Concr. Res. 42 (2): 490–498. https://doi.org/10.1016/j.cemconres.2011.11.019.
Houst, Y. F., and F. H. Wittmann. 1994. “Influence of porosity and water content on the diffusivity of and through hydrated cement paste.” Cem. Concr. Res. 24 (6): 1165–1176. https://doi.org/10.1016/0008-8846(94)90040-X.
Katz, A. J., and A. H. Thompson. 1986. “Quantitative prediction of permeability in porous rock.” Phys. Rev. B 34 (11): 8179–8181. https://doi.org/10.1103/PhysRevB.34.8179.
Klinkenberg, L. J. 2012. “The permeability of porous media to liquids and gases.” In Proc., SOCAR, 57–73. Azerbaijan, Baku: Oil Gas Scientific Research Project Institute. https://doi.org/10.5510/OGP20120200114.
Koltermann, C. E., and S. M. Gorelick. 1995. “Fractional packing model for hydraulic conductivity derived from sediment mixtures.” Water Resour. Res. 31 (12): 3283–3297. https://doi.org/10.1029/95WR02020.
Krumbein, W., and G. Monk. 1943. “Permeability as a function of the size parameters of unconsolidated sand.” Trans. AIME 151 (1): 153–163. https://doi.org/10.2118/943153-G.
Lam, L., Y. L. Wong, and C. S. Poon. 2000. “Degree of hydration and gel/space ratio of high-volume fly ash/cement systems.” Cem. Concr. Res. 30 (5): 747–756. https://doi.org/10.1016/S0008-8846(00)00213-1.
Lammertijn, S., and N. D. Belie. 2008. “Porosity, gas permeability, carbonation and their interaction in high-volume fly ash concrete.” Mag. Concr. Res. 60 (7): 535–545. https://doi.org/10.1680/macr.2008.60.7.535.
Maxwell, J. C. 1860. “V. Illustrations of the dynamical theory of gases.—Part I. On the motions and collisions of perfectly elastic spheres.” Philos. Mag. 19 (124): 19–32. https://doi.org/10.1080/14786446008642818.
Metha, P. K., and P. J. M. Monteiro. 2006. Concrete microstructure properties and materials. London: McGraw-Hill.
Montes, J. M., F. G. Cuevas, and J. Cintas. 2007. “Electrical and thermal tortuosity in powder compacts.” Granular Matter 9 (6): 401–406. https://doi.org/10.1007/s10035-007-0061-3.
Muckenfuss, C. 1962. “Mean-free-path concept in gas dynamics.” Phys. Fluids 5 (2): 165–168. https://doi.org/10.1063/1.1706591.
Palou, M. T., L. U. Bágel’, V. Živica, M. Kuliffayová, and J. Kozánková. 2013. “Influence of hydrothermal curing regimes on the hydration of fiber-reinforced cement composites.” J. Therm. Anal. Calorim. 113 (1): 219–229. https://doi.org/10.1007/s10973-013-2943-4.
Poon, C. S., L. Lam, and Y. L. Wong. 1999. “Effects of fly ash and silica fume on interfacial porosity of concrete.” J. Mater. Civ. Eng. 11 (3): 197–205. https://doi.org/10.1061/(ASCE)0899-1561(1999)11:3(197).
Powers, T. C., and T. L. Brownyard. 1946. “Studies of the physical properties of hardened portland cement paste.” ACI Mater. J. 43 (9): 469–504. https://doi.org/10.14359/15301.
RILEM. 1999. “Permeability of concrete as a criterion of its durability, tests for gas permeability of concrete.” Mater. Struct. 32 (217): 174–179.
Sakai, Y. 2019. “Correlations between air permeability coefficients and pore structure indicators of cementitious materials.” Constr. Build. Mater. 209 (11): 541–547. https://doi.org/10.1016/j.conbuildmat.2019.03.068.
Sakai, Y. 2020. “Relationship between water permeability and pore structure of cementitious materials.” Mag. Concr. Res 72 (23): 1235–1242. https://doi.org/10.1680/jmacr.19.00135.
Salmas, C. E., and G. P. Androutsopoulos. 2001. “A novel pore structure tortuosity concept based on nitrogen sorption hysteresis data.” Ind. Eng. Chem. Res. 40 (2): 721–730. https://doi.org/10.1021/ie000626y.
Shanti, N. O., V. W. L. Chan, S. R. Stock, F. De Carlo, K. Thornton, and K. T. Faber. 2014. “X-ray micro-computed tomography and tortuosity calculations of percolating pore networks.” Acta Mater. 71 (Mar): 126–135. https://doi.org/10.1016/j.actamat.2014.03.003.
Sinsiri, T., P. Chindaprasirt, and C. Jaturapitakkul. 2010. “Influence of fly ash fineness and shape on the porosity and permeability of blended cement pastes.” Int. J. Miner. Metall. Mater. 17 (6): 683–690. https://doi.org/10.1007/s12613-010-0374-9.
Song, Y., G. Dai, L. Zhao, Z. Bian, P. Li, and L. Song. 2020. “Permeability prediction of hydrated cement paste based on its 3D image analysis.” Constr. Build. Mater. 247 (May): 118527. https://doi.org/10.1016/j.conbuildmat.2020.118527.
Thomas, M. D., J. Matthews, and C. Haynes. 1989. “Effect of curing on the strength and permeability of PFA concrete.” ACI Spec. Publ. 114 (May): 191–218. https://doi.org/10.14359/1788.
Tibbetts, C. M., C. Tao, J. M. Paris, and C. C. Ferraro. 2020. “Mercury intrusion porosimetry parameters for use in concrete penetrability qualification using the Katz-Thompson relationship.” Constr. Build. Mater. 263 (May): 119834. https://doi.org/10.1016/j.conbuildmat.2020.119834.
Washburn, E. W. 1921. “Note on a method of determining the distribution of pore sizes in a porous material.” Proc. Natl. Acad. Sci. 7 (4): 115–116. https://doi.org/10.1073/pnas.7.4.115.
Zelenka, T. 2016. “Adsorption and desorption of nitrogen at 77K on micro- and meso-porous materials: Study of transport kinetics.” Microporous Mesoporous Mater. 227 (Jun): 202–209. https://doi.org/10.1016/j.micromeso.2016.03.009.
Zeng, Q., K. Li, T. Fen-chong, and P. Dangla. 2012b. “Pore structure characterization of cement pastes blended with high-volume fly-ash.” Cem. Concr. Res. 42 (1): 194–204. https://doi.org/10.1016/j.cemconres.2011.09.012.
Zeng, Q., K. Li, T. Fen-Chong, and P. Dangla. 2012a. “Analysis of pore structure, contact angle and pore entrapment of blended cement pastes from mercury porosimetry data.” Cem. Concr. Compos. 34 (9): 1053–1060. https://doi.org/10.1016/j.cemconcomp.2012.06.005.
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Received: May 2, 2023
Accepted: Nov 1, 2023
Published online: Feb 24, 2024
Published in print: May 1, 2024
Discussion open until: Jul 24, 2024
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